Pd/C-catalyzed chemoselective hydrogenation in the presence of diphenylsulfide

Organic Letters

Volumn 8, Issue 15, 2006, Pages 3279-3281

  Mori, Akinori ^a   Miyakawa, Yumi ^a   Ohashi, Eri ^a   Haga, Tomoko ^a   Maegawa, Tomohiro ^a   Sajiki, Hironao ^a  

^a GIFU PHARMACEUTICAL UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ACETYLENE; ALKENE; PALLADIUM; SULFIDE;

ARTICLE; CATALYSIS; CHEMISTRY; COMBINATORIAL CHEMISTRY; HYDROGENATION; OXIDATION REDUCTION REACTION;

ACETYLENE; ALKENES; CATALYSIS; COMBINATORIAL CHEMISTRY TECHNIQUES; HYDROGENATION; OXIDATION-REDUCTION; PALLADIUM; SULFIDES;

EID: 33746901223     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol061147j     Document Type: Article

References (34)

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26. 2 cycles to replace air inside the reaction tube with hydrogen, the mixture of the substrate (0.500 mmol), 10% Pd/C (10 wt % of the substrate), and diphenylsulfide (0.84 μL, 5.00 μmol) in MeOH (2 mL) was vigorously stirred at room temperature (ca. 20 °C) under 1 atm of hydrogen for 24 h. The reaction mixture was filtered using a membrane filter (Millipore, Millex-LH, 0.45 μm), and the filtrate was concentrated to provide the product.
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