Solid-phase microextraction as a novel air sampling technology for improved, GC-olfactometry-based assessment of livestock odors

Journal of Chromatographic Science

Volumn 44, Issue 7, 2006, Pages 451-457

  Koziel, Jacek A ^a   Cai, Lingshuang ^a   Wright, Donald W ^b   Hoff, Steven J ^a  

^a Iowa State University   (United States)

^b Microanalytics A MOCON Company   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BOS TAURUS; SUS SCROFA;

EID: 33746900837     PISSN: 00219665     EISSN: 00219665     Source Type: Journal    
DOI: 10.1093/chromsci/44.7.451     Document Type: Article

References (36)

1. National Research Council, National Academy of Sciences. Air Emissions from Animal Feeding Operations: Current Knowledge and Future Needs. The National Academies Press, Washington, D.C., 2003.
2. D.H. O'Neal and V.R. Phillips. A review of the control of odour and nuisance from livestock buildings: Part 3, properties of the odorous substances which have been identified in livestock wastes or in the air around them. J. Agric. Eng. Res. 53: 23-50 (1992).
3. S.F. Spoelstra. Origin of objectionable odorous components in piggery wastes and the possibility of applying indicator components for studying odour development. Agric. Environ. 5: 241-60 (1980).
4. A.R. Mosier, C.E. Andre, and F.G. Viets, Jr. Identification of aliphatic amines volatilized from cattle feedyard. Environ. Sci. Technol. 7: 624-44 (1973).
5. G.L. Hutchinson, A.R. Mosier, and C.E. Andre. Ammonia and amine emissions from a large cattle feedlot. J. Environ. Qual. 11: 288-93 (1982).
6. S.M. McGinn, H.H. Jantzen, and T. Coates. Atmospheric ammonia, volatile fatty acids and other odorants near beef feedlots. J. Environ. Qual. 32: 1173-82 (2003).
7. S. Willig, M. Lacorn, and R. Claus. Development of a rapid and accurate method for the determination of key compounds of pig odor. J. Chromatogr. A 1038: 11-18 (2004).
8. J. Schaeffer. Sampling, characterization and analysis of malodors. Agric. Environ. 3: 121-27 (1997).
9. A. Yasuhara, K. Fuwa, and M. Jimbu. Identification of odorous compounds in fresh and rotten swine manure. Agric. Biol. Chem. 48: 3001-10 (1984).
10. P. Kai and A. Schafer. Identification of key components in pig house air using hyphenated gas chromatography olfactometry. Agric. Eng. Int. CIGR J. Sci. Res. Dev. VI: Manuscript BC 04 006 1-11 (2004).
11. S.S. Schiffman, J.L. Bennett, and J.H. Raymer. Quantification of odors and odorants from swine operations in North Carolina. Agric. Forest Meteorol. 108: 213-240 (2001).
12. J.A. Zahn, J.L. Hatfield, Y.S. Do, A.A. DiSpirito, D.A. Laird, and R.L. Pfeiffer. Characterization of volatile organic emissions and wastes from a swine production facility. J. Environ. Qual. 26: 1687-96 (1997).
13. J.A. Zahn, J.L. Hatfield, D.A. Laird, T.T. Hart, Y.S. Do, and A.A. DiSpirito. Correlation of olfactory responses to airborne concentrations of malodorous volatile organic compounds emitted from swine effluent. J. Environ. Qual. 30: 624-34 (2001).
14. W.E. Burnett. Air pollution from animal wastes; determination of malodors by gas chromatographic and organoleptic techniques. Environ. Sci. Technol. 3: 744-49 (1969).
15. N.E. Rabaud, S.E. Ebeler, L.L. Ashbaugh, and R.G. Flocchini. The application of thermal desorption GC-MS with simultaneous olfactory evaluation for the characterization and quantification of odor compounds from dairy. J. Agric. Food Chem. 50: 5139-45 (2002).
16. K.M. Keener, J. Zhang, R.W. Bottcher, and R.D. Munilla. Evaluation of thermal desorption for the measurement of artificial swine odorants in the vapor phase. Trans. ASAE. 45: 1579-84 (2002).
17. C.J. Clanton and D.R. Schmidt. Sulfur compounds in gases emitted from stored manure. Trans. ASAE. 43: 1229-39 (2000).
18. F. Begnaud, C. Peres, and J.L. Berdague. Characterization of volatile effluents of livestock buildings by solid-phase microextraction. Int. J. Environ. Anal. Chem. 83: 837-49 (2003).
19. S.P. Yo. Analysis of volatile fatty acids in wastewater collected from a pig farm by a solid-phase microextraction method. Chemosphere. 38: 823-34 (1999).
20. D.W. Wright, D.K. Eaton, L.T. Nielsen, F.W. Kuhrt, J.A. Koziel, J.P. Spinhirne, and D.B. Parker. Multidimensional gas chromatography-olfactometry for identification and prioritization of malodors from confined animal feeding operations. J. Agric. Food Chem. 53: 8663-72 (2005).
21. D.W. Wright. "Application of multidimensional gas chromatography techniques to aroma analysis". In Techniques for Analyzing Food Aroma. Ray Marsili, Ed. Marcel Dekker, Inc., New York, NY, 1997, pp. 113-41.
22. D.W. Wright, K.O. Mahler, and L.B. Ballard. The application of an expanded multidimensional GC system to complex fragrance evaluations. J. Chromatgr. Sci. 24: 60-65 (1986).
23. P. Pollien, A. Ott, F. Montigon, M. Baumgartner, R. Munoz-Box, and A. Chaintreau. Hyphenated headspace-gas chromatography-sniffing technique: screening of impact odorants and quantitative aromagram comparisons. J. Agric. Food Chem. 45: 2630-37 (1997).
24. J.A. Koziel, J.P. Spinhirne, J.D. Lloyd, D.B. Parker, D.W. Wright, and F.W. Kuhrt. Evaluation of sample recovery of malodorous gases from air sampling bags, SPME and sampling canisters. J. Air Waste Manage. Assoc. 55: 1147-57 (2005).
25. P.A. Martos. "Air sampling with SPME". In Applications of Solid Phase Microextraction, 1st ed., J. Pawliszyn, Ed. The Royal Society of Chemistry, Hertfordshire, U.K., 1999 pp. 159-68.
26. L. Tuduri, V. Desauziers, and J.L. Fanlo. Potential of solid phase microextraction fibers for the analysis of volatile organic compounds in air. J. Chromatgr. Sci. 39: 521-29 (2001).
27. J.A. Koziel, M. Jia, A. Khaled, J. Noah, and J. Pawliszyn. Field air analysis with SPME device. Anal. Chim. Acta. 400: 153-62 (1999).
28. M. Jia, J.A. Koziel, and J. Pawliszyn. Fast field sampling/sample preparation and quantification of volatile organic compounds in indoor air by solid phase microextraction and portable GC. Field Anal. Chem. Technol. 4: 73-84 (2000).
29. J.A. Koziel, M. Jia, and J. Pawliszyn. Air sampling with porous solid-phase microextraction fibers. Anal. Chem. 72: 5178-86 (2000).
30. F. Augusto, J.A. Koziel, and J. Pawliszyn. Design and validation of portable SPME devices for rapid field air sampling and diffusion based calibration. Anal. Chem. 73: 481-86 (2001).
31. J.A. Koziel, J. Noah, and J. Pawliszyn. Field sampling and determination of formaldehyde in indoor air with solid phase microextraction and on-fiber derivatization. Environ. Sci. Technol. 35: 1481-86 (2001).
32. J.A. Koziel and J. Pawliszyn. Air sampling and analysis of VOCs with solid phase microextraction. J. Air Waste Manag. Assoc. 51: 173-84 (2001).
33. J.A. Koziel and I. Novak. Sampling and sample preparation strategies based on solid phase microextraction for analysis of indoor air. Trends Anal. Chem. 21: 840-50 (2002).
34. S. Lin, D. Hawley, D.D. Schulte, and D.P. Billesbach. Use of solid phase microextraction (SPME) fibers for detecting odorous compounds in ambient air. Paper #024161. In the Proceedings of the 2002 ASAE Annual International Meeting, CIGR XVth World Congress, Chicago, IL, 2002.
35. Y. Chen, J.A. Koziel, and J. Pawliszyn. Calibration for rapid on-site analysis of organic compounds and aqueous and gaseous samples using solid phase microextraction. Anal. Chem. 75: 6485-93 (2003).
36. J. Pawliszyn. Solid-Phase Microextraction: Theory and Practice. Wiley-VCH, New York, NY, 1997.