Comparison of thermodynamic and kinetic aspects of oxidative addition of PhE-EPh (E = S, Se, Te) to Mo(CO)3(PR3)2, W(CO)3(PR3)2, and Mo(N[tBu]Ar) 3 complexes. The role of oxidation state and ancillary ligands in metal complex induced chalcogenyl radical generation

Journal of the American Chemical Society

Volumn 128, Issue 31, 2006, Pages 10295-10303

  McDonough, James E ^a   Weir, John J ^a   Sukcharoenphon, Kengkaj ^a   Hoff, Carl D ^a   Kryatova, Olga P ^a   Rybak Akimova, Elena V ^a   Scott, Brian L ^a   Kubas, Gregory J ^a   Mendiratta, Arjun ^a   Cummins, Christopher C ^a  

^a NONE

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; CARRIER CONCENTRATION; COMPLEXATION; CRYSTAL STRUCTURE; ENTHALPY; PARAMAGNETIC RESONANCE;

ANCILLARY LIGANDS; CHALCOGENYL RADICAL GENERATION; METAL COMPLEX; OXIDATIVE ADDITION;

MOLYBDENUM COMPOUNDS;

CHALCOGEN; FREE RADICAL; LIGAND; METAL COMPLEX; MOLYBDENUM COMPLEX; SELENIUM DERIVATIVE; SULFUR DERIVATIVE; TELLURIUM DERIVATIVE; TUNGSTEN DERIVATIVE;

ARTICLE; CALORIMETRY; CHEMICAL REACTION KINETICS; CRYSTAL STRUCTURE; ELECTRON SPIN RESONANCE; FOURIER TRANSFORMATION; INFRARED SPECTROSCOPY; LIGAND BINDING; OXIDATION; THERMODYNAMICS;

CRYSTALLOGRAPHY, X-RAY; ELECTRON SPIN RESONANCE SPECTROSCOPY; KINETICS; LIGANDS; METALS; MODELS, MOLECULAR; OXIDATION-REDUCTION; THERMODYNAMICS;

EID: 33746889433     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja063250+     Document Type: Article

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