Reactions of the complexes M(Pr3)2(CO)3(M = Cr, Mo, W; R = iPr, Cy) with thiols, hydrogen sulfide, disulfides, hydrogen iodide and iodine. The role of heteroatoms in determining the metal-hydrogen bond strength at a sterically crowded metal center

Inorganica Chimica Acta

Volumn 259, Issue 1-2, 1997, Pages 317-327

  Lang, Russel F ^a   Ju, Telvin D ^a   Kiss, Gabor ^a   Hoff, Carl D ^a   Bryan, Jeffrey C ^b   Kubas, Gregory J ^b  

^a Department of Biology   (United States)

^b LOS ALAMOS NATIONAL LABORATORY   (United States)

Author keywords

Chromium complexes; Hydrogen sulfide complexes; Molybdenum complexes; Thiol complexes; Tungsten complexes

Indexed keywords

BOND STRENGTH (CHEMICAL); BOND STRENGTH (MATERIALS); CRYSTAL STRUCTURE; FREE RADICAL REACTIONS; HYDROGEN BONDS; HYDROGEN SULFIDE; IODINE; MOLYBDENUM COMPOUNDS; PRASEODYMIUM COMPOUNDS; SULFUR COMPOUNDS; SULFUR DETERMINATION; TUNGSTEN COMPOUNDS;

CHROMIUM COMPLEXES; HYDROGEN IODIDE; METAL HYDROGEN BONDS; MOLECULAR HYDROGEN; MOLYBDENUM COMPLEX; RADICAL COMPLEXES; THIOL COMPLEXES; TUNGSTEN COMPLEX;

CHROMIUM COMPOUNDS;

EID: 0001188967     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/s0020-1693(97)05510-2     Document Type: Article

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