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45
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33746543551
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note
-
In the case of cross-coupling derivative 3d both (E) and (Z) isomers have been characterized, and the stereochemistry has been deduced on the basis of NOESY experiments (see Experimental Section).
-
-
-
-
46
-
-
33746481552
-
-
note
-
II, has also to be considered. At this moment we have no explanation for the results regarding cross-coupling product 3c and 3f.
-
-
-
-
48
-
-
33746516698
-
-
note
-
3 can be likely considered a weak proton scavenger.
-
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49
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0032552047
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53
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33746572660
-
-
note
-
The reaction reported in Scheme 6 has also been carried out using 3a in the presence of 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ), and no significant increase in reaction rate and yield has been observed.
-
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54
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55
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[18b]
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[18b]
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