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accepted
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The synthesis of PBI-2 will be published elsewhere: Beckers, E. H. A.; Chen, Z.; Meskers, S. C. J.; Jonkheijm, P.; Schenning, A. P. H. J.; Qing, X.; Osswald, P.; Würthner, F.; Janssen, R. A. J. J. Phys. Chem. A., accepted.
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em = 570 and 650 nm for films spun from heptane (chloroform) are τ = 0.30 ns (τ = 65 ns) and τ = 1.1 ns (τ = 1.7 ns), respectively (see Supporting Information). These differences indicate that the excitations reach trap sites earlier when heptane is used showing that the molecules are more in close contact. Similar observations has been found earlier for self-assembled oligo(p-phenylenevinylene) in solution, see: Herz, L. M.; Daniel, C.; Silva, C.; Hoeben, F. J. M.; Schenning, A. P. H. J.; Meijer, E. W.; Friend, R. H.; Phillips, R. T. Phys. Rev. B. 2003, 68, 045203/1-/7.
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33746457908
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note
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See Supporting Information.
-
-
-
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41
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33745736801
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4T:PBI-2) (see Supporting Information). Jonkheijm, P.; Miura, A.; Zdanowska, M.; Hoeben, F. J. M.; De Feyter, S.; Schenning, A. P. H. J.; De Schryver, F. C.; Meijer, E. W. Angew. Chem. Int. Ed. 2004, 43, 74-78.
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Jonkheijm, P.1
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Schenning, A.P.H.J.6
De Schryver, F.C.7
Meijer, E.W.8
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42
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33746433136
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note
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-4 M gave an interconnected network (see Supporting Information).
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