Very high rate enhancement of benzyl alcohol oxidation by an artificial enzyme

Angewandte Chemie - International Edition

Volumn 45, Issue 28, 2006, Pages 4590-4593

  Marinescu, Lavinia G ^a   Bols, Mikael ^a  

^a AARHUS UNIVERSITY   (Denmark)

Author keywords

Biomimetics; Cyclodextrins; Michaelis Menten kinetics; Supramolecular chemistry

Indexed keywords

ARTIFICIAL ENZYME; BENZYL ALCOHOLS; CYCLODEXTRINS; MICHAELIS MENTEN KINETICS;

ALCOHOLS; BIOMIMETIC MATERIALS; HYDROGEN PEROXIDE; KETONES; REACTION KINETICS; SUPRAMOLECULAR CHEMISTRY;

AROMATIC COMPOUNDS;

BENZYL ALCOHOL; ENZYME; HYDROGEN PEROXIDE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; METABOLISM; OXIDATION REDUCTION REACTION;

BENZYL ALCOHOL; ENZYMES; HYDROGEN PEROXIDE; MOLECULAR STRUCTURE; OXIDATION-REDUCTION;

EID: 33746281446     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200600812     Document Type: Article

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25. -1] (25°C, pH 7) and wavelengths λ [nm] of the products were determined and used: benzaldehyde (1.23, 285), acetophenone (0.32, 300), benzophenone (4.03, 280), 2-hydroxybenzaldehyde (2.92, 325), 2-methoxybenzaldehyde (2.75, 323), 2-chlorobenzaldehyde (1.24, 300), 2-bromobenzaldehyde (0.47, 292), 3-methoxybenzaldehyde (2.48, 313), 4-methoxybenzaldehyde (7.53, 300), 4-hydroxybenzaldehyde (6.1, 329), 4-fluorobenzaldehyde (0.88, 292), 4-chlorobenzaldehyde (1.09, 286), 4-bromobenzaldehyde (1.59, 295), 4-methylbenzaldehyde (3.37, 285), 2,6-dimethoxybenzaldehyde (3.63, 323), 2,6-dichlorobenzaldehyde (1.03, 309), acetylferrocene (1.68, 345 nm).