Selective Blocking of Coordination Modes in 1,3,5-Triamino-1,3,5-trideoxy-cis-inositol: Enforced Formation of a Low-Spin Iron(III) Hexaamine Complex

Inorganic Chemistry

Volumn 36, Issue 18, 1997, Pages 4121-4127

  Hegetschweiler, Kaspar ^a   Weber, Michael ^a   Huch, Volker ^a   Veith, Michael ^a   Schmalle, Helmut W ^b   Linden, Anthony ^b   Geue, Rodney J ^c,d   Osvath, Peter ^c   Sargeson, Alan M ^c,d   Willis, Anthony C ^c   Angst, Werner ^e  

^a SAARLAND UNIVERSITY   (Germany)

^b UNIVERSITY OF ZURICH   (Switzerland)

^c AUSTRALIAN NATIONAL UNIVERSITY   (Australia)

^d SWISS FEDERAL INSTITUTE OF AQUATIC SCIENCE AND TECHNOLOGY   (Switzerland)

^e CSIRO   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000286242     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic970291l     Document Type: Article

References (37)

1. Hegetschweiler, K.; Ghisletta, M.; Hausherr-Primo L.; Kradolfer, T.; Schmalle, H. W.; Gramlich, V. Inorg. Chem. 1995, 34, 1950.
2. Hegetschweiler, K.; Hancock, R. D., Ghisletta, M.; Kradolfer, T.; Grmlich, V., Schmalie, H. W. Inorg. Chem. 1993, 32, 5273.
3. Kradolfer, T. Thesis, Diss. No. 10935, ETH-Zürich, Switzerland, 1995.
4. Hegetschweiter, K.; Ghisletta. M.: Fässler, T. F.; Nesper, R.; Schmalle, H. W.: Rihs, G. Inorg. Chem. 1993, 32, 2032.
5. Ghisletta, M. Thesis,. Diss. No. 10891. ETH-Zürich, Switzerland, 1994.
6. Heeetschweiler. K.; Grämlich, V.; Ghisletta. M.; Samaras, H. Inorg. Chem. 1992, 31, 2341.
7. Schmalle. H. W.; Hesetschweiler, K.; Ghisletta. M. Actu Cryxtallogr. 1991, C47, 2047.
8. Hegetschweiler, K.; Kradolfer.T.: Grämlich, V.: Hancock. R. D. Chem. Eur. J. 1995. 1, 74.
9. Kradolfer, T.; Hegetschweiler. K. Helv. Chim. Acta 1992, 75, 2243.
10. Ghisletta, M.; Jalett, H.-P.: Gerfin, T.; Gramlich, V.; Hegetschweiler, K. Helv Chim. Ada 1992, 75, 2233.
11. Weber, M. Thesis. Diss. No. 12071. ETH-Zürich, Switzerland. 1997.
12. 2 = 28.4% for all 11 979 data and 663 refined parameters).
13. II (see refs 9 and 10).
14. 1H NMR spectrum of 3 showed only one slightly broadened singleet with a line width of about 5 Hz which was assigned to the six metrum groups. The protons of the two cyclohexane rings, winch are much closer to the paramagnetic center, could not be observed in the range 0-14 ppm. In l M DC1, liberation of free Hiimca' was indicated by increasing signals at 4.05 ppm (t. 3H). 3.77 (I. 3H), and 3.55 (s, 9H)
15. 2 = 25.5% (for all 5008 data) and 441 refined parameters (Siemens Stoe AED 2 four-circle diffractometer. graphite-monochromated Mo Ka radiation).
16. ( 17) teXsan. Crystal Structure Analysis Package, Molecular Structure Corp., 1992.
17. Sheldrick. G. M. SHELXL-9X a program for the refinement of X-ray structures. University of Gottin2en. 1993.
18. Sheldrick. G. M. SHELXS-86. ~Acta Ciystallogr. 1990. A46. 467.
19. Renoviieh, G. A.: Baker, W. A., Jr. J. Am. Own. Soc. 1968, 90, 3585. Wieghardt, K.; Tolksdorf. I., Herrmann, W. Inorg. Chem. 1985, 24, 1230. See also rets 23 and 25d.
20. Renoviieh, G. A.: Baker, W. A., Jr. J. Am. Own. Soc. 1968, 90, 3585. Wieghardt, K.; Tolksdorf. I., Herrmann, W. Inorg. Chem. 1985, 24, 1230. See also rets 23 and 25d.
21. Pohl, K.: Wieghardl, K.; Kaim. W.: Steenken, S. Inorg. Chem. 1988. 27, 440.
22. Tobe. M. L. Adv. Inurg. Bivinorg. Meek. 1983. 2, 1 and references therein.
23. 3+2; see: Wieghardt, K.: Schmidt. W.; Hermann. W.: Küppers, H.-J. Inorg. Chem. 1983, 22, 2953.
24. 6 coordination,
25. Only a few crystal structures of low-spin Fe1" hexaamine complexes have been reported. The Fe-N bond distances fall in the range 1.97 -2.02 A. See: (a) Marsh, R. E. Acta Crystallogr. 1987, B4, 3174. (b) Geilenkirchen. A.; Wieghardt, K.; Nuber. B.; Weiss. J. Z. Naturforsch. 1989, 44b, 1333. Comba, P.; Sargeson, A. M.: Engelhardt. L. M.: Harrowfield, J. M.: White, A. H.. Horn, E.; Snow, M. R. Intirg. Chem. 1985, 24, 2325. Bernhardt. P. V.; Comba, P.; Hambley, T. W.; Lawrence, G. A. Inorg. Chem. 1991, 30, 942.
26. Only a few crystal structures of low-spin Fe1" hexaamine complexes have been reported. The Fe-N bond distances fall in the range 1.97 -2.02 A. See: (a) Marsh, R. E. Acta Crystallogr. 1987, B4, 3174. (b) Geilenkirchen. A.; Wieghardt, K.; Nuber. B.; Weiss. J. Z. Naturforsch. 1989, 44b, 1333. Comba, P.; Sargeson, A. M.: Engelhardt. L. M.: Harrowfield, J. M.: White, A. H.. Horn, E.; Snow, M. R. Intirg. Chem. 1985, 24, 2325. Bernhardt. P. V.; Comba, P.; Hambley, T. W.; Lawrence, G. A. Inorg. Chem. 1991, 30, 942.
27. Only a few crystal structures of low-spin Fe1" hexaamine complexes have been reported. The Fe-N bond distances fall in the range 1.97 -2.02 A. See: (a) Marsh, R. E. Acta Crystallogr. 1987, B4, 3174. (b) Geilenkirchen. A.; Wieghardt, K.; Nuber. B.; Weiss. J. Z. Naturforsch. 1989, 44b, 1333. Comba, P.; Sargeson, A. M.: Engelhardt. L. M.: Harrowfield, J. M.: White, A. H.. Horn, E.; Snow, M. R. Intirg. Chem. 1985, 24, 2325. Bernhardt. P. V.; Comba, P.; Hambley, T. W.; Lawrence, G. A. Inorg. Chem. 1991, 30, 942.
28. Only a few crystal structures of low-spin Fe1" hexaamine complexes have been reported. The Fe-N bond distances fall in the range 1.97 -2.02 A. See: (a) Marsh, R. E. Acta Crystallogr. 1987, B4, 3174. (b) Geilenkirchen. A.; Wieghardt, K.; Nuber. B.; Weiss. J. Z. Naturforsch. 1989, 44b, 1333. Comba, P.; Sargeson, A. M.: Engelhardt. L. M.: Harrowfield, J. M.: White, A. H.. Horn, E.; Snow, M. R. Intirg. Chem. 1985, 24, 2325. Bernhardt. P. V.; Comba, P.; Hambley, T. W.; Lawrence, G. A. Inorg. Chem. 1991, 30, 942.
29. IIIreported by: Shannon. R. D. Acta Crystallogr. 1976, A32, 751.
30. Orpen, A. G.: Brammer, L.; Allen, F. H.: Kennard, O.; Watson, D. G.; Taylor, R. J. Chem. Soc. Dalton Trans. 1989, S1.
31. Peterson. S. W.: Levy, H. A. Acta Crystallogr. 1957, 10, 70.
32. (a) Arulsamy. N.; Glerup. J.: Hodgson. D. J. Inorg. Chem. 1994, 33. 3043.
33. (b) wieshardt. K.; Sehöffmann, E.; Nuber. B,: Weiss, J. Inorg. Chem. 1986, 25, 4877.
34. Comba, P. Inorg. Chem. 1994, 33, 4577.
35. Schwarzenbaeh, G.: Bürei. H.-B.: Jensen, W. P.: Lawrance, G. A.; Monsted, L.: Sargeson. A. M. lnorg. Chem. 1983, 22, 4029.
36. (a) Read. R. A.; Margerum, D. W. Inorg. Chem. 1981, 20, 3143.
37. (b.) Shamsuddin Ahmed, A. K.; Wilkins, R. G. J. Chem. Sac. 1960. 2901.