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1
-
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0542393666
-
-
note
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3+ (6).
-
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2
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85088543223
-
-
note
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2O, this signal disappeared upon heating the sample. In addition, the signal at 2.85 ppm now appeared as a sharp triplet (J = 3.8 Hz).
-
-
-
-
38
-
-
85088543596
-
-
note
-
3. Shorter or longer reaction times resulted in a significantly diminished yield.
-
-
-
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39
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44
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48
-
-
85088543579
-
-
note
-
o) = esd based on counting statistics.
-
-
-
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49
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37049073570
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51
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85088542125
-
-
note
-
13C).
-
-
-
-
52
-
-
85088542231
-
-
note
-
w = 6.43% for 813 observed reflections [I > 2ω(I)] and 227 refined parameters. The mean Co-N distance is 1.96(1) Å.
-
-
-
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53
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0002811362
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3+ (en = ethane1,2-diamine), formaldehyde, and nitromethane rapidly produced the bicapped complex whereas for the corresponding analogue with the more rigid trans-cyclohexane-1,2-diamine ligand, the reaction proceeded more slowly and in equivalent conditions only the monocapped species was formed: Geue, R. J.; McCarthy, M. G.; Sargeson, A. M. J. Am. Chem. Soc. 1984, 106, 8282.
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