Role of the metal oxidation state in the SNS-Cr catalyst for ethylene trimerization: Isolation of Di- and trivalent cationic intermediates

Journal of the American Chemical Society

Volumn 128, Issue 28, 2006, Pages 9238-9247

  Jabri, Amir ^a   Temple, Claire ^a   Crewdson, Patrick ^a   Gambarotta, Sandro ^a   Korobkov, Ilia ^a   Duchateau, Robbert ^b  

^a UNIVERSITY OF OTTAWA   (Canada)

^b EINDHOVEN UNIVERSITY OF TECHNOLOGY   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

CHROMIUM; CRYSTALLINE MATERIALS; ETHYLENE; METAL ANALYSIS; OLIGOMERS; OXIDATION; REACTION KINETICS;

ALUMINUM ACTIVATORS; CATIONIC INTERMEDIATES; DEPROTONATION; TRIMERIZATION;

CATALYSTS;

ALUMINUM DERIVATIVE; CATION; CHROMIUM; ETHYLENE; OLIGOMER;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION KINETICS; COMPLEX FORMATION; CRYSTALLIZATION; ELECTRON SPIN RESONANCE; LIGAND BINDING; METAL BINDING; OLIGOMERIZATION; OXIDATION; REDUCTION KINETICS;

EID: 33746068258     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0623717     Document Type: Article

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