Experimental and numerical study on the transient behavior of partial oxidation of methane in a catalytic monolith

Chemical Engineering Science

Volumn 58, Issue 3-6, 2003, Pages 633-642

  Schwiedernoch, Renate ^a   Tischer, Steffen ^a   Correa, Chrys ^a   Deutschmann, Olaf ^a  

^a UNIVERSITY OF HEIDELBERG   (Germany)

Author keywords

Kinetics; Multiphase reactions; Partial oxidation; Reaction Engineering; Simulation; Synthesis gas

Indexed keywords

ALUMINA; CATALYSTS; IGNITION; OXIDATION; RHODIUM; SYNTHESIS GAS;

PARTIAL OXIDATION;

METHANE;

KINETICS; MATHEMATICAL ANALYSIS; METHANE; MULTIPHASE FLOW; OXIDATION;

EID: 0037289613     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0009-2509(02)00589-4     Document Type: Article

References (23)

1. Baerns, M. (1993). Oxidative coupling of methane for utilization of natural gas. In H.I. de Lesa et al. (Eds.), Chemical reactor technology for environmental safe reactors and products (pp. 283-316). Dordrecht: Kluwer Academic Publishers.
2. Baulch, D. L., Cobos, C. J., Cox, R. A., Esser, C., Frank, P., Just, T., Kerr, J. A., Pilling, M. P., Troe, J., Walker, R. W., & Warnatz, J. (1992). Journal of Physical Chemical Reference Data. 21, 441.
3. Belgued, M., Amariglio, H., Pareja, P., Ameriglio, A., & Saint-Just, J. (1992). Low temperature catalytic homologation of methane on platinum, ruthenium and cobolt. Catalysis Today, 13, 337-445.
4. Bodke, A. S., Bharadwaj, S. S., & Schmidt, L. D. (1998). The effect of ceramic supports on partial oxidation of hydrocarbons over noble metal coated monoliths. Journal of Catalysis, 179, 138-149.
5. 2. Transient studies on its mechanism. Catalysis Letters, 29 249-260.
6. 3 Journal of Physical Chemistry, 96, 8686-8688.
7. Deuflhardt, P., Hairer, E., & Zugk, J. (1987). One-step and extrapolation methods for differential-algebraic systems. Numerische Mathematik, 51, 501-516.
8. Deutschmann, O., Correa, C., Tischer, S., Chatterjee, D., Kleditzsch, S. & Warnatz, J. (2001b). DETCHEM Version 1.4.2. http://rea2ow.iwr.uni-heidelberg.de/˜dmann/DETCHEM.html
9. Deutschmann, O., & Schmidt, L. D. (1998). Modeling the partial oxidation of methane in a short contact time reactor. A.I.Ch.E. Journal, 44, 2465-2476.
10. Deutschmann, O., Schwiedernoch, R., Maier, L., & Chatterjee, D. (2001a). Natural gas conversion in monolithic catalysts: Interaction of chemical reactions and transport phenomena. Studies in surface science and catalysis. In E. Iglesia., J. J. Spivey, T. H. Fleisch (Eds.), Natural gas conversion VI, vol. 136 (p. 215). Amsterdam: Elsevier.
11. Heitnes, K., Lindeberg, S., Rokstad, O. A., & Holmen, A. (1995). Catalytic partial oxidation of methane to synthesis gas. Catalysis Today, 24, 211-216.
12. 4 Oxidation on Pt and Rh surfaces: High temperature reactor simulation. A.I.Ch.E. Journal, 39(7), 1164-1177.
13. Hindmarsh, A. C. (1983). Scientific computing (pp. 55-64) Amsterdam.
14. Jahn, R., Snita, D., Kubicek, M., & Marek, M. (1997). 3D-modeling of monolith reactors. Catalysis Today, 38, 39-46.
15. Li, L., Borry, R., & Iglesia, E. (2001). Reaction-transport simulations of non oxidative methane conversion with continuous hydrogen removal-homogeneous-heterogeneous reaction pathways. Chemical Engineering Science, 56, 1869-1881.
16. Lide, D. R. (Ed.) (1994). CRC handbook of chemistry and physics (75th ed.). Boca Raton: CRC Press.
17. Mallens, E. P. J., Hoebink, J. H.B., & Marin, G. B. (1997). The reaction mechanism of the partial oxidation of methane to synthesis gas: A transient kinetic study over rhodium and a comparison with platinum. Journal of Catalysis, 167, 43-46.
18. Pery, T., Schweitzer, M. G., Volpp, H.-R., Wolfrum, J., Ciossu, L., Deutschmann, O., & Warnatz, J. (2002). Sum-frequency generation in situ study of CO adsorption and catalytic CO oxidation on rhodium at elevated pressures. Proceedings of Combustion Institute, 29, in press.
19. Raja, L. L., Kee, R. J., Deutschmann, O., Warnatz, J., & Schmidt, L. D. (2000). A critica evaluation of Navier-Stokes, boundary-layer, and plug-flow models for the simulation of flow and chemistry in a catalytic combustion honeycomb channel. Catalysis Today, 59, 47-60.
20. Schlichting, H., & Gersten, K. (1999). In Boundary-Layer Theory. Heidelberg: Springer.
21. Tischer, S., Correa, C., & Deutschmann, O. (2001). Transient three- dimensional simulation of a catalytic combustion monolith using detailed models or heterogeneous and homogeneous reactions and transport phenomena. Catalysis Today, 69, 57-62.
22. Veser, G., & Frauhammer, J. (2000). Modelling steady state and ignition during catalytic methane oxidation in a monolith reactor. Chemical Engineering Science, 55, 2271-2286.
23. Wolf, M., Deutschmann, O., Behrendt, F., & Warnatz, J. (1999). Kinetic model of an oxygen-free methane conversion on a platinum catalyst. Catalysis Letters, 61, 15-25.