Application of a new vanadium valence oxybarometer to basaltic glasses from the Earth, Moon, and Mars

American Mineralogist

Volumn 91, Issue 2-3, 2006, Pages 270-277

  Karner, Jim M ^a   Sutton, Steven R ^b,c   Papike, James J ^a   Shearer, Charles K ^a   Jones, John H ^d   Newville, Matt ^c  

^a UNIVERSITY OF NEW MEXICO   (United States)

^b UNIVERSITY OF CHICAGO   (United States)

^c UNIVERSITY OF CHICAGO   (United States)

^d NASA JOHNSON SPACE CENTER   (United States)

Author keywords

Mars; Oxidation state; Oxygen fugacity; Planetary basalts; Vanadium; XANES

Indexed keywords

BASALT; GLASS; VANADIUM; X RAY ABSORPTION; X RAY ABSORPTION NEAR EDGE STRUCTURE SPECTROSCOPY;

EXTRATERRESTRIAL BODIES; IN-SITU MEASUREMENT; MARS; ORDERS OF MAGNITUDE; OXIDATION STATE; OXYGEN FUGACITY; SPATIAL RESOLUTION; XANES;

MOON;

BASALT; EARTH; IMPACT STRUCTURE; MARS; MOON; OXIDATION; VANADIUM; X-RAY SPECTROSCOPY;

EID: 33745459549     PISSN: 0003004X     EISSN: None     Source Type: Journal    
DOI: 10.2138/am.2006.1830     Document Type: Article

References (64)

1. Bajt, S., Sutton, S.R., and Delaney, J.S. (1994) X-ray microprobe analysis of iron oxidation states in silicates and oxides using X-ray absorption near edge structure (XANES). Geochimica et Cosmochimica Acta, 58, 5209-5214.
2. Ballhaus, C. (1993) Redox states of lithospheric and asthenospheric upper-mantle. Contribributions to Mineralogy and Petrology, 114, 331-348.
3. 4-bearing upper mantle sources. Geochimica et Cosmochimica Acta, 58, 4931-4940.
4. Ballhaus, C., Berry, R.F., and Green, D.H. (1990) Oxygen fugacity controls on the Earth's upper mantle. Nature, 348, 437-440.
5. Berry, A.J. and O'Neill, H.St.C. (2004) XANES determination of the oxidation state of chromium in silicate glasses. American Mineralogist, 89, 790-798.
6. Berry, A.J., O'Neill, H.St.C., Jayasuriya, K.D., Campbell, S.J., and Foran, G.J. (2003) XANES calibrations for the oxidation state of iron in a silicate glass. American Mineralogist, 88, 967-977.
7. 3+/∑ Fe ratios of MORB glasses and their implications for mantle melting. Geochimica et Cosmochimica Acta, 69, 711-725.
8. Canil, D. (1997) Vanadium partitioning and the oxidation state of Archaean komatiite magmas. Nature, 389, 842-845.
9. Canil, D. (1999) Vanadium partitioning between orthopyroxene, spinel and silicate melt and the redox states of mantle source regions for primary magmas. Geochimica et Cosmochimica Acta, 63, 557-572.
10. Canil, D. (2002) Vanadium in peridotites, mantle redox and tectonic environments: Archean to present. Earth and Planetary Science Letters, 195, 75-90.
11. Canil, D. and Fedortchouk, Y. (2001) Olivine-liquid partitioning of vanadium and other trace elements, with applications to modern and ancient picrites. The Canadian Mineralogist, 39, 319-330.
12. Carmichael, I.S.E. and Ghiorso, M.S. (1986) Oxidation-reduction relations in basic magma: a case for homogenous equilibria. Earth and Planetary Science Letters, 78, 200-210.
13. Carmichael, I.S.E. and Ghiorso, M.S. (1990) The effect of oxygen fugacity on the redox states of natural liquids and their crystallizing phases. In J. Nicholls and J.K. Russell, Eds., Modern methods of igneous petrology: understanding magmatic processes, 24, p. 190-212. Reviews in Mineralogy, Mineralogical Society of America, Chantilly, Virginia.
14. Christie, D.M., Carmichael, I.S.E., and Langmuir, C.H. (1986) Oxidation-states of mid-ocean ridge basalt glasses. Earth and Planetary Science Letters, 79, 397-411.
15. Connolly, H.C., Jr., and Burnett, D.S. (1999) A study of the minor element concentrations of spinels from two type B calcium-aluminum-rich inclusions; an investigation into potential formation conditions of calcium-aluminum-rich inclusions. Meteoritics and Planetary Science, 34, 829-848.
16. 3+/∑Fe ratios in arnphibole by X-ray absorption near edge structure (XANES) spectroscopy. Mineral Spectroscopy, Roger Burns Memorial, 5, 165-171.
17. Delaney, J.S., Dyar, M.D., Sutton, S.R., and Bajt, S. (1998) Redox ratios with relevant resolution: solving an old problem using the synchrotron microXANES probe. Geology, 26, 139-142.
18. Delaney, J. S., Jones, J.H., Sutton, S.R., Simon, S., and Grossman, L. (1999) In situ microanalysis of vanadium, chromium, and iron oxidation states in extraterrestrial samples by synchrotron microXANES (SmX) spectroscopy (abstract). Meteoritics and Planetary Science, 34, A32.
19. Delano, J.W. (1990) Experimental constraints on the oxidation state of the lunar mantle (abstract). Lunar and Planetary Science Conference XXI, 278-279. Lunar and Planetary Institute, Houston.
20. 3+ distribution in oxidized olivine: A synchrotron micro-XANES study. American Mineralogist, 83, 1361-1365.
21. 2+ partitioning among silicates in metapelites: a synchrotron micro-XANES study. American Mineralogist, 87, 514-522.
22. El Ghoresy, A. (1976) Oxide minerals in lunar rocks. In D. Rumble, Ed., Oxide minerals, 3, p. EG1-EG43. Reviews in Mineralogy, Mineralogical Society of America, Chantilly, Virginia.
23. Fogel, R.A. and Rutherford, M.J. (1995) Magmatic volatiles in primitive lunar glasses. 1. FTIR and EPMA analyses of Apollo 15 green and yellow glasses and revision of the volatile-assisted fire-fountain theory. Geochimica et Cosmochimica Acta, 59, 201-215.
24. Gessmann, C.K. and Rubie, D.C. (1998) The effect of temperature on the partitioning of nickel, cobalt, manganese, chromium, and vanadium at 9 GPa and constraints on formation of the Earth's core. Geochimica et Cosmochimica Acta, 62, 867-882.
25. Gessmann, C.K., Rabic, D.C., and McCammon, C.A. (1999) Oxygen fugacity dependence of Ni, Co, Mn, Cr, V, and Si partitioning between liquid metal and magnesiowuestite at 9-18 GPa and 2200 degrees C. Geochimica et Cosmochimica Acta, 63, 1853-1863.
26. Ghiorso, M.S. and Sack, R.O. (1995) Chemical Mass-Transfer in Magmatic Processes. ed. 4. A Revised and Internally Consistent Thermodynamic Model for the Interpolation and Extrapolation of Liquid-Solid Equilibria in Magmatic Systems at Elevated-Temperatures and Pressures. Contribributions to Mineralogy and Petrology, 119, 197-212.
27. Goodrich, C.A. (2002) Olivine-phyric martian basafts: a new type of shergottites. Meteoritics and Planetary Science, 37, B31-B34.
28. Guili, G., Paris, E., Mungall, J., Romano, C., and Dingwell, D. (2004) V oxidation state and coordination number in synthetic silicate glasses by XAS. American Mineralogist, 89, 1640-1646.
29. Haggerty, S.E. and Meyer, H.O.A. (1970) Apollo 12: opaque oxides. Earth and Planetary Science Letters, 9, 379-387.
30. Hanson, B. and Jones, J. H. (1997) The contrasting partitioning behavior of V and Cr into olivine. Eos, 78, 17, Supplemental pages 335.
31. Herd, C.D.K., Papike, J.J., and Brearley, A.J. (2001) Oxygen fugacity of martian basalts from electron microprobe oxygen and TEM-EELS analyses of Fe-Ti oxides. American Mineralogist, 86, 1015-1024.
32. Hess, P.C. (1989) Origins of Igneous Rocks, 336 p. Harvard University Press, Cambridge, Massachusetts.
33. Jones, J. (2004) Redox conditions among the terrestrial planets (abstract). Lunar and Planetary Science Conference XXXV, no. 1264. Lunar and Planetary Institute, Houston, Texas (CD-ROM).
34. Karner, J.M., Papike, J.J., and Shearer, C.K. (2003) Olivine from planetary basalts: chemical signatures that indicate planetary parentage and those that record igneous setting and process. American Mineralogist, 88, 806-816.
35. O2 estimates for basalts from Vesta (abstract). Oxygen in Asteroids and Meteorites Workshop, 7010, Lunar and Planetary Institute, Houston, Texas.
36. Kallithrakas, K.N. and Moshohoritou, R. (1998) Vanadium speciation by EDXRF. X-Ray Spectrometry, 27, 173-176.
37. Kilburn, M.R. and Wood, B.J. (1998) The effect of oxygen fugacity and silicate melt composition of the partitioning of titanium, vanadium, chromium, and manganese between liquid metal and silicate melt. In Origin of the Earth and Moon, LPI Contribution 957, p. 18-19. Lunar and Planetary Institute, Houston, Texas.
38. Koizumi, E., Mikouchi, T., McKay, G., Monkawa, A., Chokai, J., and Miyamoto, M. (2004) Yamato 980459: crystallization of martian magnesian magma (abstract). Lunar and Planetary Science Conference XXXV, 1494. Lunar and Planetary Institute, Houston, Texas (CD-ROM).
39. Lindstrom, D.J. (1976) Experimental study of partitioning of the transition metals between clinopyroxene and coexisting silicate liquids. Ph.D. thesis, University of Oregon.
40. Longhi, J. (1992) Experimental petrology and petrogenesis of mare volcanics. Geochimica et Cosmochimica Acta, 56, 2235-2252.
41. McCanta, M.C., Rutherford, M.J., and Jones, J.H. (2004a) An experimental study of rare earth element partitioning between a shergottite melt and pigeonite: implications for the oxygen fugacity of the martian interior. Geochimica et Cosmochimica Acta, 68, 1943-1952.
42. McCanta, M.C., Rutherford, M.J., Dyar, M.D., and Delaney, J.S. (2004b) Iron partitioning between basaltic melts and clinopyroxene as a function of oxygen fugacity. American Mineralogist, 89, 1685-1693.
43. Papike, J.J., Karner, J.M., and Shearer, C.K. (2004) Comparative planetary mineralogy: V/(Cr+Al) systematics in chromite as an indicator of relative oxygen fugacity. American Mineralogist, 89, 1557-1560.
44. Papike, J.J., Karner, J.M., and Shearer, C.K. (2005) Comparative planetary mineralogy: Valence-state partitioning of Cr, Fe, Ti, and V among crystallographic sites in olivine, pyroxene, and spinel from planetary basalts. American Mineralogist, 90, 277-290.
45. Rao, M.N., Borg, L.E., McKay, D.S., and Wentworth, S.J. (1999) Martian soil component in impact glasses in a Martian meteorite. Geophysical Research Letters, 26, 3265.
46. Righter, K., Sutton, S.R., and Newville, M. (2004) MicroXANES measurements on experimental spinels and the oxidation state of vanadium in spinel-melt pairs (abstract). Oxygen in the Terrestrial Planets workshop, LPI contribution, 1203. Lunar and Planetary Institute, Houston, Texas.
47. Sato, M. (1976) Oxygen fugacity and other thermochemical parameters of Apollo 17 high-Ti basalts and their implications on the reduction mechanism. Proceedings of the 7th Lunar Science Conference, 1323-1344.
48. Sato, M. (1979) The driving mechanism of lunar pyroclastic eruptions inferred from the oxygen fugacity behavior of Apollo 17 orange glasses. Proceedings of the 10th Lunar Science Conference, 311-325.
49. Sato, M. and Wright, T.L. (1966) Oxygen fugacities directly measured in magmatic gases. Science, 153, 1103-1105.
50. Sato, M., Hickling, N.L., and McLane, J.E. (1973) Oxygen fagacity values of Apollo 12, 14, and 15 lunar samples and reduced state of lunar magmas. Proceedings of the 4th Lunar Science Conference, 1061-1079.
51. Schreiber, H.D. (1977) Redox states of Ti, Zr, Hf, Cr, and Eu in basaltic magmas: an experimental study. Proceedings of 8th Lunar Science Conference, 1785-1807.
52. Shearer, C.K. and Papike, J.J. (1993) Basaltic magmatism on the Moon: a perspective from the volcanic picritic glass beads. Geochimica et Cosmochimica Acta, 57, 4785-4812.
53. Stolper, E.M. (1977) Experimental petrology of eucritic meteorites. Geochimica et Cosmochimica Acta, 41, 587-611.
54. Sutton, S.R. and Newville, M. (2005) Vanadium K XANES of synthetic olivine: valence determinations and crystal orientation effects (abstract). Lunar and Planetary Science Conference XXXVI, 2133. Lunar and Planetary Institute, Houston, Texas (CD-ROM).
55. Sutton, S.R., Jones, K.W., Gordon, B., Rivers, M.L., and Smith, J.V. (1993) Reduced chromium in olivine grains from lunar basalt 15555: X-ray absorption near edge structure (XANES). Geochimica et Cosmochimica Acta, 57, 461-468.
56. Sutton, S.R., Simon, S., Grossman, L., Delaney, J.S., Beckett, J., Newville, M., Eng, P., and Rivers, M. (2002) Evidence for divalent vanadium in Allende CAl fassaite and implications for formation conditions (abstract). Lunar and Planetary Science Conference XXXIII, 1907. Lunar and Planetary Institute, Houston, Texas (CD-ROM).
57. Sutton, S.R., Karner, J.M., Papike, J.J., Delaney, J.S., Shearer, C.K., Newville, M., Eng, P., Rivers, M., and Dyar, M.D. (2005) Vanadium K edge XANES of synthetic and natural basaltic glasses and application to microscale oxygen barometry. Geochimica et Cosmochimica Acta, 69, 2333-2348.
58. Taylor, G.J., Warren, P., Ryder, G., Delano, J., Pieters, C., and Lofgren, G. (1991) Lunar rocks. In G. Heiken, D. Vaniman, and B. French, Eds., Lunar Sourcebook, p. 183-284. Cambridge University Press, U.K.
59. Wadhwa, M. (2001) Redox state of Mars' upper mantle and crust from Eu anomalies in shergottite pyroxenes. Science, 291, 1527-1530.
60. Waychunas, G.A., Brown, G.E., Jr., and Apted, M.J. (1983) X-ray K-edge absorption spectra of Fe minerals and model compounds: Near-edge structure. Physical Chemistry of Minerals, 10, 1-9.
61. Wilke, M., Farges, F., Petit, P.E., Brown, G.E., Jr., and Martin, F. (200 1) Oxidation state and coordination of Fe in minerals: An Fe K-XANES spectroscopic study. American Mineralogist, 86, 714-730.
62. Wong, J., Lytle, F.W., Messmer, R.P., and Maylotte, D.H. (1984) K-edge absorption spectra of selected vanadium compounds. Physical Review B (Condensed Matter), 30, 5596-5610.
63. Wood, B.J., Bryndzia, L.T., and Johnson, K.E. (1990) Mantle oxidation state and its relationship to tectonic environment and fluid speciation. Science, 248, 337-345.
64. Wright, T.L. and Okamura, R.T. (1977) Cooling and Crystallization of Tholeiitic Basalt, 1965 Makaopuhi Lava Lake, Hawaii. Geological Survey Professional Paper 1004, U.S. Government Printing Office, Washington, 78 p.