Iron partitioning between basaltic melts and clinopyroxene as a function of oxygen fugacity

American Mineralogist

Volumn 89, Issue 11-12, 2004, Pages 1685-1693

  McCanta, Molly C ^a,b   Dyar, M Darby ^c   Rutherford, Malcolm J ^a   Delaney, Jeremy S ^d  

^a BROWN UNIVERSITY   (United States)

^b LUNAR AND PLANETARY INSTITUTE   (United States)

^c MOUNT HOLYOKE COLLEGE   (United States)

^d RUTGERS UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BINARY ALLOYS; IRON ALLOYS; OXYGEN; SILICATE MINERALS; TITANIUM ALLOYS; TITANIUM OXIDES; VOLCANIC ROCKS;

ANALYTICAL METHOD; BASALTIC MELTS; BULK COMPOSITIONS; EXPERIMENTAL CONDITIONS; IN COMPOSITIONS; MARTIAN METEORITES; OXYGEN FUGACITY; SILICATE MELTS;

IRON OXIDES;

CLINOPYROXENE; FUGACITY; IRON; MELT; MINERALOGY; OXYGEN; PARTITIONING;

EID: 11144312464     PISSN: 0003004X     EISSN: None     Source Type: Journal    
DOI: 10.2138/am-2004-11-1214     Document Type: Article

References (58)

1. Ague, J.J. (1998) Simple models of coupled fluid infiltration and redox reactions in the crust. Contributions to Mineralogy and Petrology, 132, 180-197.
2. Bajt, S., Sutton, S.R., and Delaney, J.S. (1994) Microanalysis of iron oxidation states in silicates and oxides using X-ray absorption near edge structure (XANES). Geochimica et Cosmochimica Acta, 58, 5209-5214.
3. Barrat, J.A., Gillet, P., Lesourd, M., Blichert-Toft, J., and Poupeau, G.R. (1999) The Tatahouine diogenite: mineralogical chemical effects of sixty-three years of terrestrial residence. Earth and Planetary Science Letters, 34, 91-97.
4. Berry, A.J., O'Neill, H.S., Jayasuriya, K.D., Campbell, S.J., and Foran, G.J. (2003) XANES calibrations for the oxidation state of iron in a silicate glass. American Mineralogist, 88, 967-977.
5. Borisov, A. and Jones, J.H. (1999) An evaluation of Re, as an alternative to Pt, for the 1 bar loop technique; an experimental study at 1400 °C. American Mineralogist, 84, 1528-1534.
6. Brandon, A.D. and Draper, D.S. (1996) Constraints on the origin of the oxidation state of mantle overlying subduction zones: an example from Simcoe, Washington, USA. Geochimica et Cosmochimica Acta, 60, 1739-1749.
7. Buddington, A.F. and Lindsley, D.H. (1964) Iron-titanium oxide minerals and synthetic equivalents. Journal of Petrology, 5, 310-357.
8. Calas, G. and Petiau, J. (1983) Coordination of iron in oxide glasses through high-resolution K-edge spectra: information from the pre-edge. Solid State Communications, 48, 625-629.
9. Canil, D., O'Neill, H.St.C., Pearson, D.G., Rudnick, R.L., McDonough, W.F., and Carswell, D.A. (1994) Ferric iron in peridotites and mantle oxidation states. Earth and Planetary Science Letters, 123, 205-220.
10. Carmichael, I.S.E. and Ghiorso, M.S. (1990) The effect of oxygen fugacity on the redox state of natural liquids and their crystallizing phases. In J. Nicholls and J.K. Russell, Eds., Modern methods of igneous petrology; understanding magmatic processes, 24, 191-212. Reviews in Mineralogy, Mineralogical Society of America, Washington, D.C.
11. Deer, W.A., Howie, R.A., and Zussman, J. (1978) Rock-forming minerals, volume 2A. Longman Scientific and Technical, New York.
12. 3+/ΣFe in amphibole by X-ray absorption near edge structure (XANES) spectroscopy. In M.D. Dyar, C. McCammon, and M.W. Schaefer, Eds., Mineral Spectroscopy: A Tribute to Roger G Burns, 5, 165-172. Geochemical Society Special Publication, Elsevier, New York.
13. Delaney, J.S., Sutton, S.R., Dyar, M.D., Bajt, S., Moore, G., Carmichael, I.S.E., and Roeder, P. (1996b) In situ microanalysis of ferric/ferrous in geologically significant glasses. Abstract to G.S.A. Annual Meeting, Denver, A419.
14. Delaney, J.S., Bajt, S., Newville, M., Sutton, S.R., and Dyar, M.D. (1996c) Measurement of Fe oxidation state and coordination in geological glasses by synchrotron microXANES spectroscopy. Abstract to AGU Fall Meeting, San Francisco, Eos, 77, 835.
15. 2+) results for amphibole and silicate glass with independent measurements. Lunar and Planetary Science XXVII, p. 299-300 (extended abstract) Lunar and Planetary Institute, Houston, Texas.
16. Delaney, J.S., Sutton, S.R., Dyar, M.D., Bajt, S., Moore, G., Carmichael, I.S.E., and Roeder, P. (1996e) In situ microanalysis of ferric/ferrous in geologically significant glasses. Abstract to G.S.A. Annual Meeting, Denver, A419.
17. Delaney, J.S., Dyar, M.D., Sutton, S.R., and Bajt, S. (1998) Redox ratios with relevant resolution: Solving an old problem using the Synchrotron microXANES probe. Geology, 26, 139-142.
18. Delaney, J.S. and Dyar, M.D. (2000) Correction of the calibration of ferric/ferrous determinations in pyroxene from Martian samples and achondritic meteorites by synchrotron microXANES spectroscopy. 31st Annual Lunar and Planetary Science Conference, no. 1981, Lunar and Planetary Institute, Houston.
19. Delaney, J.S. and Dyar, M.D. (2002) Compositional and oxidation state zoning in martian pyroxene: Paradox or process indicator. 33rd Annual Lunar and Planetary Science Conference, no. 1659, Lunar and Planetary Institute, Houston.
20. +, and D/H in mantle-derived augite from Dish Hill: Implications for alteration during transport. In M.D. Dyar, C.A. McCammon, and M. Schaefer, Eds., Mineral Spectroscopy: A Tribute to Roger G. Burns, Special Publication 5, 273-289. The Geochemical Society, St. Louis.
21. Dyar, M.D., Delaney, J.S., and Tegner, C. (2001a) Ferric iron in feldspar as an indicator of evolution of planetary oxygen fugacity. 32nd Annual Lunar and Planetary Science Conference, no. 1065, Lunar and Planetary Institute, Houston.
22. Dyar, M.D., Delaney, J.S., and Sutton, S.R. (2001b) Fe XANES spectra of iron-rich micas. European Journal of Mineralogy, 13, 1079-1098.
23. Dyar, M.D., Gunter, M.E., Delaney, J.S., Lanzarotti, A., and Sutton, S.R. (2002) Systematics in the structure, optical properties, and XANES spectra of pyroxenes, amphiboles, and micas. Canadian Mineralogist, 40, 1347-1365.
24. Frost, B.R. (1991) Introduction to oxygen fugacity and its petrologic importance. In L. Donald, Ed., Oxide Minerals, 25, 1-9. Reviews in Mineralogy, Mineralogical Society of America, Washington, D.C.
25. Frost, B.R. and Ballhaus, C. (1998) Comment on "Constraints on the origin of the oxidation state of mantle overlying subduction zones: an example from Simcoe, Washington, USA". Geochimica et Cosmochimica Acta, 62, 329-331.
26. Frost, B.R. and Lindsley, D.H. (1991) Occurrence of iron-titanium oxides in igneous rocks. In L. Donald, Ed., Oxide Minerals, 25, 433-468. Reviews in Mineralogy, Mineralogical Society of America, Washington, D.C.
27. Galoisy, L., Calas, G., and Arrio, M.A. (2001) High-resolution XANES spectra of iron in minerals and glasses: structural information from the pre-edge region. Chemical Geology, 174, 307-319.
28. Ghiorso, M.S. and Sack, R.O. (1991) Fe-Ti oxide geothermometry; thermodynamic formulation and the estimation of intensive variables in silicic magmas. Contributions to Mineralogy and Petrology, 108, 485-510.
29. Ghosal, S., Sack, R.O., Ghiorso, M.S., and Lipschutz, M.E. (1998) Evidence for a reduced, Fe-depleted Martian mantle source region of shergottites. Contributions to Mineralogy and Petrology, 130, 346-357.
30. Hale, V.P.S., McSween, H.Y. Jr., and McKay, G.A. (1999) Re-evaluation of intercumulus liquid composition and oxidation state for the Shergotty meteorite. Geochimica et Cosmochimica Acta, 63, 1459-1470.
31. Herd, C.D.K., Papike, J.J., and Brearley, A.J. (2001) Oxygen fugacity of martian basalts from electron microprobe oxygen and TEM-EELS analyses of Fe-Ti oxides. American Mineralogist, 86, 1015-1024.
32. Herd, C.D.K., Borg, L.E., Jones, J.H., and Papike, J.J. (2002) Oxygen fugacity and geochemical variations in the martian basalts: implications for martian basalt petrogenesis and the oxidation state of the upper mantle of Mars. Geochimica et Cosmochimica Acta, 66, 2025-2036.
33. 2 controlled-atmosphere furnaces. NASA Technical Memorandum 104774, United States Government Printing Office, Washington, D.C.
34. total between amphibole and basanitic melt as a function of oxygen fugacity. Earth and Planetary Science Letters, 178, 97-112.
35. 3 and the effect of composition, temperature, oxygen fugacity, and pressure on their redox states. Contributions to Mineralogy and Petrology, 108, 82-92.
36. Lindsley, D.H., Frost, B.R, Ghiorso, M.S., and Sack, R.O. (1991) Oxides lie; the Bishop Tuff did not erupt from a thermally zoned magma body (abstr.). EOS 72, 312.
37. Long, G.J., Cranshaw, T.E., and Longworth, G. (1983) The ideal Mössbauer effect absorber thickness. Mössbauer Effect Reference and Data Journal, 6, 42-49.
38. Luth, R.W. and Canil, D. (1993) Ferric iron in mantle-derived pyroxenes and a new oxybarometer for the mantle. Contributions to Mineralogy and Petrology, 113, 236-248.
39. McCanta, M.C. and Rutherford, M.J. (2001) SNC oxygen fugacity as recorded in pyroxenes: an experimental study (abstr.). 32nd Lunar and Planetary Science Conference 32, no. 1348, Lunar and Planetary Institute, Houston.
40. O2: implications for the martian interior (abstr.). Meteoritics and Planetary Science, 37, A97.
41. McCanta, M.C., Rutherford, M.J., and Jones, J.H. (2004) An experimental study of rare earth element partitioning between a shergottite melt and pigeonite: implications for the oxygen fugacity of the martian interior. Geochimica et Cosmochimica Acta 68, 1943-1952.
42. McGuire, A.V., Dyar, M.D., and Nielson, J.E. (1991) Metasomatic oxidation of upper mantle peridotite. Contributions to Mineralogy and Petrology, 109, 252-264.
43. McSween, H.Y. Jr., Eisenhour, D.D., Taylor, L.A., Wadhwa, M., and Crozaz, G. (1996) QUE94201 shergottite: crystallization of a martian basaltic magma. Geochimica et Cosmochimica Acta 60, 4563-4569.
44. Minitti, M.E. and Rutherford, M.J. (2000) Genesis of the Mars Pathfinder "sulfur-free" rock from SNC parental liquids. Geochimica et Cosmochimica Acta 64, 2535-2547.
45. Musselwhite, D.M., Jones, J.H., and Wadhwa, M. (2004) Variations in experimentally determined augite/melt partition coefficients for samarium, europium, and gadolinium, with oxygen fugacity: implications for the oxidation state of the martian mantle. Meteoritics and Planetary Science, in press.
46. Nakamura, A., and Schmalzried, H. (1983) On the nonstoichiometry and point defects of olivine. Physics and Chemistry of Minerals, 10, 27-37.
47. 3+ content. American Mineralogist, 78, 456-460.
48. Osborn, E.F. (1959) Role of oxygen pressure in the crystallization and differentiation of basaltic magma. American Journal of Science, 257, 609-647.
49. Parkinson, I.J. and Arculus, R.J. (1999) The redox state of subduction zones: insights from arc peridotites. Chemical Geology, 160, 409-423.
50. Petit, P.-E., Farges, F., Wilke, M., and Solé, V.A. (2001) Determination of the iron oxidation state in Earth materials using XANES pre-edge information. Journal of Synchrotron Radiation, 8, 952-954.
51. Presnall, D.C. (1966) The join forsterite-diopside-iron oxide and its bearing on the crystallization of basaltic and ultramafic magmas. American Journal of Science, 264, 753-809.
52. Rancourt, D.G. and Ping, J.Y. (1991) Voigt-based methods for arbitrary-shape static hyperfine parameter distributions in Mö ssbauer spectroscopy. Nuclear Instruments and Methods in Physics Research, B58, 85-97.
53. Rutherford, M.J. and Devine J.D. (1988) The May 18, 1980, eruption of Mount St. Helens 3. Stability and chemistry of amphibole in the magma chamber. Journal of Geophysical Research, 93, 11,949-11,959.
54. Sack, R.O., Carmichael, I.S.E., Rivers, M., and Ghiorso, M.S. (1980) Ferric-ferrous equilibria in natural silicate liquids at 1 bar. Contributions to Mineralogy and Petrology, 75, 369-376.
55. Solberg, T.C. and Burns, R.G. (1989) Mössbauer spectral study of weathered Antarctic and SNC meteorites. Proceedings of the Lunar and Planetary Science Conference 19, 313-322.
56. Thornber, C.R., Roedder, P.L., and Foster, J.R. (1980) The effect of composition on the ferric ferrous ratio in basaltic liquids at atmospheric pressure. Geochimica et Cosmochimica, Acta, 44, 525-532.
57. Wadhwa, M. (2001) Redox state of Mars' upper mantle and crust from Eu anomalies in shergottite pyroxenes. Science, 291, 1527-1530.
58. Wilke, M., Behrens, H., Burkhard, D.J.M., and Rossano S. (2002) The oxidation state of iron in silicic melt at 500 MPa water pressure. Chemical Geology, 189, 55-67.