A XANES determination of the oxidation state of chromium in silicate glasses

American Mineralogist

Volumn 89, Issue 5-6, 2004, Pages 790-798

  Berry, Andrew J ^a   O'Neill, Hugh St C ^a  

^a AUSTRALIAN NATIONAL UNIVERSITY   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION SPECTROSCOPY; ALUMINA; ALUMINUM OXIDE; CALCIUM OXIDE; CHROMIUM COMPOUNDS; GLASS; IODINE COMPOUNDS; IRON COMPOUNDS; MAGNESIA; OXIDATION; OXIDE MINERALS; PHOSPHORUS COMPOUNDS; SILICATES; TITANIUM COMPOUNDS; X RAY ABSORPTION; X RAY ABSORPTION NEAR EDGE STRUCTURE SPECTROSCOPY;

ABSORPTION EDGES; COORDINATION GEOMETRY; DERIVATIVE SPECTRA; GLASS COMPOSITIONS; HIGH TEMPERATURE; IN-SITU EXPERIMENTS; OXYGEN FUGACITY; X-RAY ABSORPTION NEAR-EDGE STRUCTURE;

URANIUM COMPOUNDS;

CHROMIUM; GLASS; OXIDATION; SILICATE; XANES SPECTROSCOPY;

EID: 2942519133     PISSN: 0003004X     EISSN: None     Source Type: Journal    
DOI: 10.2138/am-2004-5-613     Document Type: Article

References (33)

1. Arcon, I., Mirtic, B., and Kodre, A. (1999) Determination of valence states of chromium in calcium chromates by using X-ray absorption near-edge structure (XANES) spectroscopy. Journal of the American Ceramic Society, 81, 222-224.
2. Bajt, S., Clark, S.B., Sutton, S.R., Rivers, M.L., and Smith, J.V. (1993) Synchrotron X-ray microprobe determination of chromate content using X-ray absorption near-edge structure. Analytical Chemistry, 65, 1800-1804.
3. Bajt, S., Sutton, S.R., and Delaney, J.S. (1994) X-ray microprobe analysis of iron oxidation states in silicates and oxides using X-ray absorption near edge structure (XANES). Geochimica et Cosmochimica Acta, 58, 5209-5214.
4. Barnes, S.J. (1986) The distribution of chromium among orthopyroxene, spinel and silicate liquid at atmospheric pressure Geochimica et Cosmochimica Acta, 50, 1889-1909.
5. Berry, A.J., O'Neill, H.St.C., Jayasuriya, K.D., Campbell, S.J., and Foran, G.J. (2003a) XANES calibrations for the oxidation state of iron in a silicate glass. American Mineralogist, 88, 967-977.
6. Berry, A.J., Shelley, J.M.G., Foran, G.J., O'Neill, H.St.C., and Scott, D.R. (2003b) A furnace design for XANES spectroscopy of silicate melts under controlled oxygen fugacities and temperatures to 1773K. Journal of Synchrotron Radiation, 10, 332-336.
7. Brigatti, M.F., Galli, E., Medici, L., Poppi, L., Cibin, G., Marcelli, A., and Mottana, A. (2001) Chromium-containing muscovite: crystal chemistry and XANES spectroscopy. European Journal of Mineralogy, 13, 377-389.
8. Burns, V.M. and Burns, R.G. (1975) Mineralogy of chromium. Geochimica et Cosmochimica Acta, 39, 903-910.
9. Farges, F., Brown Jr., G.E., and Rehi, J.J. (1996) Coordination chemistry of Ti (IV) in silicate glasses and melts: I. XAFS study of titanium coordination in oxide model compounds. Geochimica et Cosmochimica Acta, 60, 3023-3038.
10. Foran, G.J., Garrett, R.F., Gentle, I.R., Creagh, D.C., Peng, J.B., and Barnes, G. T. (1998) Focusing monochromator and imaging plate camera for grazing incidence diffraction studies of thin films. Journal of Synchrotron Radiation, 5, 500-502.
11. Haggerty, S.E., Boyd, F.R., Bell, P.M., Finger, L.W., and Bryan, W.B. (1970) Opaque minerals and olivine in lavas and breccias from Mare Tranquillitatis. Proceedings of the Apollo 11 Lunar Science Conference, 1, 513-538.
12. 2+ partitioning between olivine and liquid in the presence of spinel. American Mineralogist, 83, 669-684.
13. Holzheid, A., Palme, H., and Chakraborty, S. (1997) The activities of NiO, CoO and FeO to silicate melts. Chemical Geology, 139, 21-38.
14. Kilinc, A., Carmichael, I.S.E., Rivers, M.L., and Sack, R.O. (1983) The ferric-ferrous ratio of natural silicate liquids equilibrated in air. Contributions to Mineralogy and Petrology, 83, 136-140.
15. Krause, M.O. and Oliver, J.H. (1979) Natural widths of atomic K and L levels, Kα X-ray lines and several KLL Auger lines. Journal of Physical and Chemical Reference Data, 8, 329-338.
16. Lauer, H.V. and Morris, R.V. (1977) Redox equilibria of multivalent ions in silicate glasses. Journal of the American Ceramic Society, 60, 443-451.
17. Levina, A., Foran, G.J., and Lay, P.A. (1999) X-ray absorption spectroscopic studies of the Cr(IV) 2-ethyl-2-hydroxybutanoato(I-) complex. Chemical Communications, 2339-2340.
18. 2-Cr-O in equilibrium with metallic Cr, and their significance for the petrochemistry of chromium. Journal of Petrology, 36, 107-132.
19. Liang, Y. and Elthon, D. (1990) Evidence from chromium abundances in mantle rocks for extraction of pricrite and komatiite melts. Nature, 343, 551-553.
20. 3 in silicate melts. Chemical Geology, 186, 151-181.
21. O'Neill, H.S.C. and Mavrogenes, J.A. (2002) The sulfide capacity and the sulfur content at sulfide saturation of silicate melts at 1400 °C and 1 bar. Journal of Petrology, 43, 1049-1087.
22. Peterson, M.L., Brown Jr., G.E., Parks, G.A., and Stein, C.L. (1997) Differential redox and sorption of Cr(III/VI) on natural silicate and oxide minerals: EXAFS and XANES results. Geochimica et Cosmochimica Acta, 61, 3399-3412.
23. Poustovetov, A.A. and Roeder, P.L. (2000) The distribution of Cr between basaltic melt and chromium spinel as an oxygen geobarometer. Canadian Mineralogist, 39, 309-317.
24. Roeder, P.L. and Reynolds, I. (1991) Crystallization of chromite and chromium solubility in basaltic melts. Journal of Petrology, 32, 909-934.
25. Schreiber, H.D. (1987) An electrochemical series of redox couples in silicate melts: a review and applications to geochemistry. Journal of Geophysical Research, 92, 9225-9232.
26. Schreiber, H.D. and Haskin, L.A. (1976) Chromium in basalts: Experimental determination of redox states and partitioning among synthetic silicate phases. Proceedings of the 7th Lunar Science Conference, p. 1221-1259.
27. Schreiber, H.D., Merkel Jr., R.C., Schreiber, V.L., and Balazs, G.B. (1987) Mutual interactions of redox couples via electron exchange in silicate melts: models for geochemical melt systems. Journal of Geophysical Research, 92, 9233-9245.
28. Shulman, R.G., Yafet, Y., Eisenberger, P., and Blumberg, W.E. (1976) Observation and interpretation of X-ray absorption edges of iron compounds and proteins. Proceedings of the National Academy of Science, 73, 1384-1388.
29. Sutton, S.R., Jones, K.W., Gordon, B., Rivers, M.L., Bajt, S., and Smith, J.V. (1993) Reduced chromium in olivine grains from lunar basalt 15555: X-ray absorption near edge structure (XANES). Geochimica et Cosmochimica Acta, 57, 461-468.
30. Szulczewski, M.D., Helmke, P.A., and Bleam, W.F. (1997) Comparison of XANES analyses and extractions to determine chromium speciation in contaminated soils. Environmental Science and Technology, 31, 2954-2959.
31. Waychunas, G.A., Apted, M.J., and Brown Jr., G.E. (1983) X-ray K-edge absorption spectra of Fe minerals and model compounds: near edge-structure. Physics and Chemistry of Minerals, 10, 1-9.
32. Wilke, M., Farges, F., Petit, P-E., Brown Jr., G.E., and Martin, F. (2001) Oxidation state and coordination of Fe in minerals: an Fe K-XANES spectroscopic study. American Mineralogist, 86, 714-730.
33. Wong, J., Lytle, F.W., Messmer, R.P., and Maylotte, D.H. (1984) K-edge absorption spectra of selected vanadium compounds. Physical Review B, 30, 5596-5609.