A high-frequency EPR study of frozen solutions of GdIII complexes: Straightforward determination of the zero-field splitting parameters and simulation of the NMRD profiles

Journal of the American Chemical Society

Volumn 128, Issue 24, 2006, Pages 7807-7816

  Benmelouka, Meriem ^a   Van Tol, Johan ^b   Borel, Alain ^a   Port, Marc ^c   Helm, Lothar ^a   Brunel, Louis Claude ^b   Merbach, André E ^a  

^a EPFL   (Switzerland)

^b FLORIDA STATE UNIVERSITY   (United States)

^c Research Department   (France)

Author keywords

[No Author keywords available]

Indexed keywords

COMPUTER SIMULATION; MAGNETIC PROPERTIES; MAGNETIC RESONANCE IMAGING; NUCLEAR MAGNETIC RESONANCE; PARAMAGNETIC RESONANCE;

HIGH-FREQUENCY-HIGH-FIELD ELECTRON PARAMAGNETIC RESONANCE (HF-EPR); MACROCYCLIC COMPLEXES; ZERO-FIELD SPLITTING (ZFS);

GADOLINIUM COMPOUNDS;

1,4,7,10 TETRAAZACYCLODODECANE 1,4,7,10 TETRAACETIC ACID; 1,4,7,10 TETRAAZACYCLODODECANE 1,4,7,10 TETRAACETIC ACID DERIVATIVE; GADOLINIUM CHELATE; MACROCYCLIC COMPOUND; PENTETIC ACID DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; ELECTRON SPIN RESONANCE; FREEZING; FROZEN SOLUTION; HIGH FREQUENCY ELECTRON SPIN RESONANCE; LIQUID; NUCLEAR MAGNETIC RESONANCE; PARAMETER; RHOMBICITY; SIMULATION; TEMPERATURE; ZERO FIELD SPLITTING;

CHELATING AGENTS; CONTRAST MEDIA; ELECTRON SPIN RESONANCE SPECTROSCOPY; FREEZING; GADOLINIUM; GADOLINIUM DTPA; HETEROCYCLIC COMPOUNDS, 1-RING; LIGANDS; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, CHEMICAL; ORGANOMETALLIC COMPOUNDS; SOLUTIONS;

EID: 33745371698     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0583261     Document Type: Article

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