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Volumn 7, Issue 6, 2006, Pages 1372-1381

Femtosecond dynamics on 2-(2′-hydroxy-4′-diethylaminophenyl) benzothiazole: Solvent polarity in the excited-state proton transfer

Author keywords

Charge transfer; Proton transfer solvatochromism; Solvent relaxation; Tautomerism

Indexed keywords

CHARGE TRANSFER; DYNAMICS; GROUND STATE; PROTON TRANSFER; RELAXATION PROCESSES; SOLVENTS;

EID: 33745352064     PISSN: 14394235     EISSN: 14397641     Source Type: Journal    
DOI: 10.1002/cphc.200600017     Document Type: Article
Times cited : (57)

References (45)
  • 1
    • 33745331265 scopus 로고    scopus 로고
    • note
    • In general, it is difficult to distinguish the mechanism between proton transfer and hydrogen atom transfer reactions. Herein, we simply adopted the conventional term, namely "proton transfer", throughout the text, as it is particularly more suitable in describing the solvent polarity coupled proton transfer tautomerism.
  • 13
    • 33745387573 scopus 로고    scopus 로고
    • note
    • In some ESIPT molecules, the lowest excited singlet state is in an nπ* configuration, in which the rate of ESIPT is very slow in comparison to that of the ππ* configuration.
  • 14
    • 0037077666 scopus 로고    scopus 로고
    • ESIPT incorporating phenol O-H to a β-carbon atom is not included in this category, see: M. Lukeman, P. Wan, J. Am. Chem. Soc. 2002, 124, 9458-9464.
    • (2002) J. Am. Chem. Soc. , vol.124 , pp. 9458-9464
    • Lukeman, M.1    Wan, P.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.