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Volumn 35, Issue 3, 2006, Pages 288-289

Activation of a cyclobutanone carbon-carbon bond over an aldehyde carbon-hydrogen bond in the rhodium-catalyzed decarbonylation

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EID: 33744548526     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2006.288     Document Type: Article
Times cited : (36)

References (36)
  • 27
  • 30
    • 33744530110 scopus 로고    scopus 로고
    • note
    • Abbreviations: cod = cycloocta-1,5-diene, DPPP = 1,3- bis(diphenylphosphino)propane.
  • 33
    • 33744528857 scopus 로고    scopus 로고
    • note
    • Decarbonylation of 3a with [RhCl(cod)(1,3-dimethylimidazol-2-ylidene)] under otherwise identical conditions gave 4a in 82% yield.
  • 34
    • 33744535493 scopus 로고    scopus 로고
    • note
    • Catalyst with 1/2 ratio of Rh/DPPP exhibited a higher activity than that with 1/1 ratio.
  • 35
    • 33744534510 scopus 로고    scopus 로고
    • note
    • 3], which failed to occur at rt, proceeded in refluxing m-xylene (4 days) to afford a mixture of 4a (7%), 8 (25%), and 11 (23%, E/Z = 90/10).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.