Amphiphilic polymer supported N-heterocyclic carbene palladium complex for Suzuki cross-coupling reaction in water

Tetrahedron Letters

Volumn 47, Issue 27, 2006, Pages 4745-4748

  Kim, Jung Woo ^a   Kim, Jong Ho ^a   Lee, Dong Ho ^a   Lee, Yoon Sik ^a  

^a Seoul National University   (South Korea)

Author keywords

Aqueous phase reaction; Heterogeneous catalyst; N Heterocyclic carbene (NHC); Palladium; Suzuki reaction

Indexed keywords

CARBENE; HETEROCYCLIC COMPOUND; IMIDAZOLE DERIVATIVE; MACROGOL; PALLADIUM COMPLEX; POLYMER; WATER;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION; CROSS COUPLING REACTION; MOLECULAR STABILITY; POLYMER PRODUCTION; SUZUKI REACTION; SYNTHESIS;

EID: 33744528105     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2006.04.105     Document Type: Article

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36. 3 (820 mg, 2.5 mmol) in distilled water (4 mL), and then aryl halide (0.5 mmol) was added to the mixture. The resulting dispersion was stirred for 12 h at 50 °C. The catalyst was filtered and washed with distilled water and diethyl ether. The product was extracted with diethyl ether and purified by column chromatography. The yield was calculated from the mass value of the product after isolation with column chromatography.