A route to 1,2-diols by enantioselective organocatalytic α-oxidation with molecular oxygen

Tetrahedron Letters

Volumn 47, Issue 27, 2006, Pages 4659-4663

  Ibrahem, Ismail ^a   Zhao, Gui Ling ^a   Sundén, Henrik ^a   Córdova, Armando ^a  

^a STOCKHOLM UNIVERSITY   (Sweden)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL DERIVATIVE; ALDEHYDE; OXYGEN; PYRROLIDINE DERIVATIVE;

ARTICLE; CATALYSIS; CHIRALITY; ENANTIOSELECTIVITY; OXIDATION;

EID: 33744506603     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2006.04.133     Document Type: Article

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43. 4 at 0 °C to afford the corresponding optically active crude diol 4. The pure diol 4 was obtained by silica-gel column chromatoghraphy (toluene/EtOAc mixtures). Next, the diol 4 was converted to the corresponding diacetylated product and the enantiomeric excess was determined by chiral-phase GC analyses
44. R = 46.1 min.