메뉴 건너뛰기




Volumn 87, Issue 1, 2006, Pages 41-55

Driving multi-electron reactions with photons: Dinuclear ruthenium complexes capable of stepwise and concerted multi-electron reduction

Author keywords

Acceptor ligands; Multi electron; Photochemistry; Proton coupled electron transfer; Ruthenium polypyridyl

Indexed keywords

RUTHENIUM;

EID: 33646544073     PISSN: 01668595     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11120-005-6398-8     Document Type: Review
Times cited : (30)

References (59)
  • 1
    • 0038085138 scopus 로고
    • Photochemical model system for hydrogen production from water: The efficiency of colloidal platinum catalyst associated with viologen electron relay
    • Amouyal E, Grand D, Moradpour A and Keller P (1982) Photochemical model system for hydrogen production from water: The efficiency of colloidal platinum catalyst associated with viologen electron relay. New J Chem 6(5): 241-244
    • (1982) New J Chem , vol.6 , Issue.5 , pp. 241-244
    • Amouyal, E.1    Grand, D.2    Moradpour, A.3    Keller, P.4
  • 2
    • 37049076733 scopus 로고
    • Synthesis study of a mixed-ligand ruthenium(II) complex in its ground and excited states: Bis(2,2′-bipyridine)(dipyrido[3,2-a:2′,3′-c] phenazine-n4n5)ruthenium(II)
    • Amouyal E, Homsi A, Chambron J-C and Sauvage J-P (1990) Synthesis study of a mixed-ligand ruthenium(II) complex in its ground and excited states: Bis(2,2′-bipyridine)(dipyrido[3,2-a:2′,3′-c]phenazine-n4n5) ruthenium(II). J Chem Soc, Dalt Trans: 1841-1845
    • (1990) J Chem Soc, Dalt Trans , pp. 1841-1845
    • Amouyal, E.1    Homsi, A.2    Chambron, J.-C.3    Sauvage, J.-P.4
  • 3
    • 37049100630 scopus 로고
    • Light-induced hydrogen generation from water catalyzed by ruthenium dioxide
    • Amouyal E, Keller P and Moradpour A (1980) Light-induced hydrogen generation from water catalyzed by ruthenium dioxide. J Chem Soc, Chem Commun: 1019-1020
    • (1980) J Chem Soc, Chem Commun , pp. 1019-1020
    • Amouyal, E.1    Keller, P.2    Moradpour, A.3
  • 4
    • 0142098107 scopus 로고    scopus 로고
    • From metal complexes to fullerene arrays: Exploring the exciting world of supramolecular photochemistry fifteen years after its birth
    • Armaroli N (2003) From metal complexes to fullerene arrays: exploring the exciting world of supramolecular photochemistry fifteen years after its birth. Photochem Photobiol Sci 2(2): 73-87
    • (2003) Photochem Photobiol Sci , vol.2 , Issue.2 , pp. 73-87
    • Armaroli, N.1
  • 5
    • 0040257744 scopus 로고    scopus 로고
    • Luminescent and redox-active polynuclear transition metal complexes
    • Balzani V, Juris A, Venturi M, Campagna S and Serroni S (1996) Luminescent and redox-active polynuclear transition metal complexes. Chem Rev 96: 759-833
    • (1996) Chem Rev , vol.96 , pp. 759-833
    • Balzani, V.1    Juris, A.2    Venturi, M.3    Campagna, S.4    Serroni, S.5
  • 6
    • 2342649581 scopus 로고    scopus 로고
    • From ruthenium(II) to iridium (III): 15 Years of triads based on bis-terpyrdine complexes
    • Baranoff E, Collin J-P, Flamigni L and Sauvage J-P (2004) From ruthenium(II) to iridium (III): 15 years of triads based on bis-terpyrdine complexes. Chem Soc Rev 33(3): 147-155
    • (2004) Chem Soc Rev , vol.33 , Issue.3 , pp. 147-155
    • Baranoff, E.1    Collin, J.-P.2    Flamigni, L.3    Sauvage, J.-P.4
  • 7
    • 0000574755 scopus 로고
    • Artificial photosynthesis: Solar splitting of water to hydrogen and oxygen
    • Bard AJ and Fox MA (1995) Artificial photosynthesis: Solar splitting of water to hydrogen and oxygen. Acc Chem Res 28: 141-145
    • (1995) Acc Chem Res , vol.28 , pp. 141-145
    • Bard, A.J.1    Fox, M.A.2
  • 8
    • 0000919034 scopus 로고    scopus 로고
    • Mononuclear and binuclear tetrapyrido [3,2-a:2′,3′-c: 3″,3″-h:2‴,3‴-j]phenazine (tpphz)- ruthenium and osmium complexes
    • Bolger J, Gourdon A, Ishow E and Launay J-P (1996) Mononuclear and binuclear tetrapyrido [3,2-a:2′,3′-c:3″,3″-h:2‴, 3‴-j]phenazine (tpphz)- ruthenium and osmium complexes. Inorg Chem 35: 2937-2944
    • (1996) Inorg Chem , vol.35 , pp. 2937-2944
    • Bolger, J.1    Gourdon, A.2    Ishow, E.3    Launay, J.-P.4
  • 9
    • 0033275055 scopus 로고    scopus 로고
    • Tridentate-bridged polyazine complexes of ruthenium(II) and osmium(II) and their applications to the development of photochemical molecular devices
    • Brewer KJ (1999) Tridentate-bridged polyazine complexes of ruthenium(II) and osmium(II) and their applications to the development of photochemical molecular devices. Comm Inorg Chem 21: 201-224
    • (1999) Comm Inorg Chem , vol.21 , pp. 201-224
    • Brewer, K.J.1
  • 10
    • 0000783424 scopus 로고    scopus 로고
    • Absorption spectra, photophysical properties, and redox behavior of stereochemically pure dendritic ruthenium(II) tetramers and related dinuclear and mononuclear complexes
    • Campagna S, Serroni S, Bodige S and MacDonnell FM (1999) Absorption spectra, photophysical properties, and redox behavior of stereochemically pure dendritic ruthenium(II) tetramers and related dinuclear and mononuclear complexes. Inorg Chem 38: 692-701
    • (1999) Inorg Chem , vol.38 , pp. 692-701
    • Campagna, S.1    Serroni, S.2    Bodige, S.3    MacDonnell, F.M.4
  • 11
    • 0037020287 scopus 로고    scopus 로고
    • Coupling of metal-based light-harvesting antennas and electron-donor subunits: Trinuclear ruthenium(II) complexes containing tetrathiafulvalene- substituted polypyridine ligands
    • Campagna S, Serroni S, Puntoriero F, Loiseau F, De Cola L, Kleverlaan CJ, Becher J, Sorensen AP, Hascoat P and Thorup N (2002) Coupling of metal-based light-harvesting antennas and electron-donor subunits: Trinuclear ruthenium(II) complexes containing tetrathiafulvalene-substituted polypyridine ligands. Chem Bur J 8(19): 4461-4469
    • (2002) Chem Bur J , vol.8 , Issue.19 , pp. 4461-4469
    • Campagna, S.1    Serroni, S.2    Puntoriero, F.3    Loiseau, F.4    De Cola, L.5    Kleverlaan, C.J.6    Becher, J.7    Sorensen, A.P.8    Hascoat, P.9    Thorup, N.10
  • 13
    • 0001396221 scopus 로고    scopus 로고
    • Photophysics of dinuclear Ru(II) and Os(II) complexes based on the tpphz bridging ligand
    • Chiorboli C, Bignozzi C-A, Scandola F, Ishow E, Gourdon A and Launay J-P (1999) Photophysics of dinuclear Ru(II) and Os(II) complexes based on the tpphz bridging ligand. Inorg Chem 38: 2402-2410
    • (1999) Inorg Chem , vol.38 , pp. 2402-2410
    • Chiorboli, C.1    Bignozzi, C.-A.2    Scandola, F.3    Ishow, E.4    Gourdon, A.5    Launay, J.-P.6
  • 14
    • 0037625449 scopus 로고    scopus 로고
    • Primary processes in photoinduced multielectron storage systems. A dinuclear ruthenium(II) species featuring a charge-separated state with a lifetime of 1.3 μs
    • Chiorboli C, Fracasso S, Scandola F, Campagna S, Serroni S, Konduri R and MacDonnell FM (2003) Primary processes in photoinduced multielectron storage systems. A dinuclear ruthenium(II) species featuring a charge-separated state with a lifetime of 1.3 μs. Chem Comm: 1658-1659
    • (2003) Chem Comm , pp. 1658-1659
    • Chiorboli, C.1    Fracasso, S.2    Scandola, F.3    Campagna, S.4    Serroni, S.5    Konduri, R.6    MacDonnell, F.M.7
  • 16
    • 0032234424 scopus 로고    scopus 로고
    • Proton-coupled electron transfer
    • Cukier RI and Nocera DG (1998) Proton-coupled electron transfer. Ann Rev Phys Chem 49: 337-369
    • (1998) Ann Rev Phys Chem , vol.49 , pp. 337-369
    • Cukier, R.I.1    Nocera, D.G.2
  • 18
    • 0032178384 scopus 로고    scopus 로고
    • Photoinduced energy- and electron transfer processes in rigidly bridged dinuclear Ru/Os complexes
    • De Cola L and Belser P (1998) Photoinduced energy- and electron transfer processes in rigidly bridged dinuclear Ru/Os complexes. Coord Chem Rev 177: 301-346
    • (1998) Coord Chem Rev , vol.177 , pp. 301-346
    • De Cola, L.1    Belser, P.2
  • 20
    • 0344477411 scopus 로고
    • Applications of light-induced electron-transfer reactions. Coupling of hydrogen generation with photoreduction of ruthenium(II) complexes by triethylamine
    • DeLaive PJ, Sullivan BP, Meyer TJ and Whitten DG (1979) Applications of light-induced electron-transfer reactions. Coupling of hydrogen generation with photoreduction of ruthenium(II) complexes by triethylamine. J Am Chem Soc 101(14): 4007-4008
    • (1979) J Am Chem Soc , vol.101 , Issue.14 , pp. 4007-4008
    • DeLaive, P.J.1    Sullivan, B.P.2    Meyer, T.J.3    Whitten, D.G.4
  • 22
    • 4243362146 scopus 로고
    • Electronic structure of the 'molecular light switch' bis(bipyrdine) dipyrido[3,2-a:2′,3′-c]phenazineruthenium(2+). Cyclic voltammetric, uv/visible and epr/endor study of multiply reduced complexes and ligands
    • Fees J, Kaim W, Moscherosch M, Matheis W, Klima J, Krejcik M and Zalis S (1993) Electronic structure of the 'molecular light switch' bis(bipyrdine) dipyrido[3,2-a:2′,3′-c]phenazineruthenium(2+). Cyclic voltammetric, uv/visible and epr/endor study of multiply reduced complexes and ligands. Inorg Chem 32(2): 166-174
    • (1993) Inorg Chem , vol.32 , Issue.2 , pp. 166-174
    • Fees, J.1    Kaim, W.2    Moscherosch, M.3    Matheis, W.4    Klima, J.5    Krejcik, M.6    Zalis, S.7
  • 23
    • 0034617159 scopus 로고    scopus 로고
    • Excited-state interconversion between emissive MLCT levels in a dinuclear Ru(II) complex containing a bridging ligand with an extended π system
    • Flamigni L, Encinas S, Barigelletti F, MacDonnell FM, Kim M-J, Puntoriero F and Campagna S (2000) Excited-state interconversion between emissive MLCT levels in a dinuclear Ru(II) complex containing a bridging ligand with an extended π system. Chem Comm: 1185-1186
    • (2000) Chem Comm , pp. 1185-1186
    • Flamigni, L.1    Encinas, S.2    Barigelletti, F.3    MacDonnell, F.M.4    Kim, M.-J.5    Puntoriero, F.6    Campagna, S.7
  • 24
    • 33845558157 scopus 로고
    • Artificial photosynthesis: Water cleavage into hydrogen and oxygen by visible light
    • Grätzel M (1981) Artificial photosynthesis: Water cleavage into hydrogen and oxygen by visible light. Acc Chem Res 14: 376
    • (1981) Acc Chem Res , vol.14 , pp. 376
    • Grätzel, M.1
  • 27
    • 0000690482 scopus 로고
    • Optimization of the rate of hydrogen production from the tris(2,2′-bipyridyl)ruthenium(II) photosensitized reduction of methyl viologen
    • Harriman A and Mills A (1981) Optimization of the rate of hydrogen production from the tris(2,2′-bipyridyl)ruthenium(II) photosensitized reduction of methyl viologen. J Chem Soc, Faraday Trans: 2111-2124
    • (1981) J Chem Soc, Faraday Trans , pp. 2111-2124
    • Harriman, A.1    Mills, A.2
  • 28
    • 0033516306 scopus 로고    scopus 로고
    • Four-electron photochemistry of dirhodium fluorophosphine compounds
    • Heyduk AF, Macintosh AM and Nocera DG (1999) Four-electron photochemistry of dirhodium fluorophosphine compounds. J Am Chem Soc 121(21): 5023-5032
    • (1999) J Am Chem Soc , vol.121 , Issue.21 , pp. 5023-5032
    • Heyduk, A.F.1    Macintosh, A.M.2    Nocera, D.G.3
  • 29
    • 0035979748 scopus 로고    scopus 로고
    • Hydrogen produced from hydrohalic acid solutions by a two-electron mixed-valence photocatalyst
    • Heyduk AF and Nocera DG (2001) Hydrogen produced from hydrohalic acid solutions by a two-electron mixed-valence photocatalyst. Science 293: 1639-1641
    • (2001) Science , vol.293 , pp. 1639-1641
    • Heyduk, A.F.1    Nocera, D.G.2
  • 30
    • 0032746980 scopus 로고    scopus 로고
    • Intramolecular triplet energy transfer in pyrene-metal polypyridine dyads: A strategy for extending the triplet lifetime of the metal complex
    • Hissler M, Harriman A, Khatyr A and Ziessel R (1999) Intramolecular triplet energy transfer in pyrene-metal polypyridine dyads: a strategy for extending the triplet lifetime of the metal complex. Chem Eur J 5(11): 3366-3381
    • (1999) Chem Eur J , vol.5 , Issue.11 , pp. 3366-3381
    • Hissler, M.1    Harriman, A.2    Khatyr, A.3    Ziessel, R.4
  • 31
    • 0000591916 scopus 로고    scopus 로고
    • Synthesis, mass spectrometry, and spectroscopic properties of a dinuclear ruthenium complex comprising a 20 a long fully aromatic bridging ligand
    • Ishow E, Gourdon A, Launay J-P, Chiorboli C and Scandola F (1999) Synthesis, mass spectrometry, and spectroscopic properties of a dinuclear ruthenium complex comprising a 20 a long fully aromatic bridging ligand. Inorg Chem 38: 1504-1510
    • (1999) Inorg Chem , vol.38 , pp. 1504-1510
    • Ishow, E.1    Gourdon, A.2    Launay, J.-P.3    Chiorboli, C.4    Scandola, F.5
  • 32
    • 0001196411 scopus 로고    scopus 로고
    • Tetranuclear tetrapyrido[3,2-a:2′,3′-c3″,2″-h: 2‴,3‴-j]phenazineruthenium complex: Synthesis, wide angle scattering, and photophysical studies
    • Ishow E, Gourdon A, Launay J-P, Lecante P, Verelst M, Chiorboli C, Scandola F and Bignozzi C-A (1998) Tetranuclear tetrapyrido[3,2-a:2′, 3′-c3″,2″-h:2‴,3‴-j]phenazineruthenium complex: synthesis, wide angle scattering, and photophysical studies. Inorg Chem 37: 3603-3609
    • (1998) Inorg Chem , vol.37 , pp. 3603-3609
    • Ishow, E.1    Gourdon, A.2    Launay, J.-P.3    Lecante, P.4    Verelst, M.5    Chiorboli, C.6    Scandola, F.7    Bignozzi, C.-A.8
  • 33
    • 0026418480 scopus 로고
    • Electroactive ladder polyquinoxalines. 1. Properties of the model compound 5,12-dihydro-5,7,12, 14-tetraazapentacene and its complexes
    • Jenekhe SA (1991) Electroactive ladder polyquinoxalines. 1. Properties of the model compound 5,12-dihydro-5,7,12, 14-tetraazapentacene and its complexes. Macromolecules 24(1): 1-10
    • (1991) Macromolecules , vol.24 , Issue.1 , pp. 1-10
    • Jenekhe, S.A.1
  • 34
  • 36
    • 0032540476 scopus 로고    scopus 로고
    • A monolithic photovoltaic-photoelectrochemical device for hydrogen production via water splitting
    • Khaselev O and Turner JA (1998) A monolithic photovoltaic- photoelectrochemical device for hydrogen production via water splitting. Science 280(5362): 425-427
    • (1998) Science , vol.280 , Issue.5362 , pp. 425-427
    • Khaselev, O.1    Turner, J.A.2
  • 37
    • 0037029894 scopus 로고    scopus 로고
    • Dinuclear Ru(II) polypyridyl complexes containing large, redox-active aromatic bridging ligands. Synthesis, characterization and intramolecular quenching of MLCT excited states
    • Kim M-J, Konduri R, Ye H, MacDonnell FM, Puntoriero F, Serroni S, Campagna S, Holder T, Kinsel G and Rajeshwar R (2002) Dinuclear Ru(II) polypyridyl complexes containing large, redox-active aromatic bridging ligands. Synthesis, characterization and intramolecular quenching of MLCT excited states. Inorg Chem 41(9): 2471-2476
    • (2002) Inorg Chem , vol.41 , Issue.9 , pp. 2471-2476
    • Kim, M.-J.1    Konduri, R.2    Ye, H.3    MacDonnell, F.M.4    Puntoriero, F.5    Serroni, S.6    Campagna, S.7    Holder, T.8    Kinsel, G.9    Rajeshwar, R.10
  • 39
    • 0018544417 scopus 로고
    • Projection, size factors, and reaction dynamics of colloidal redox catalysts mediating light induced hydrogen evolution from water
    • Kiwi J and Graetzel M (1979) Projection, size factors, and reaction dynamics of colloidal redox catalysts mediating light induced hydrogen evolution from water. J Am Chem Soc 101(24): 7214-7217
    • (1979) J Am Chem Soc , vol.101 , Issue.24 , pp. 7214-7217
    • Kiwi, J.1    Graetzel, M.2
  • 40
    • 4544284235 scopus 로고    scopus 로고
    • 4: Aqueous reactivity and chemical and spectroelectrochemical identification of the photoproducts
    • 4: aqueous reactivity and chemical and spectroelectrochemical identification of the photoproducts. J Am Chem Soc 126(37): 11621-11629
    • (2004) J Am Chem Soc , vol.126 , Issue.37 , pp. 11621-11629
    • Konduri, R.1    De Tacconi, N.R.2    Rajeshwar, K.3    MacDonnell, F.M.4
  • 41
    • 0037008977 scopus 로고    scopus 로고
    • New ruthenium photocatalysts capable of reversibly storing up to four electrons in a single acceptor ligand: A step closer to artificial photosynthesis
    • Konduri R, Ye H, MacDonnell FM, Serroni S, Campagna S and Rajeshwar K (2002) New ruthenium photocatalysts capable of reversibly storing up to four electrons in a single acceptor ligand: a step closer to artificial photosynthesis. Angew Chem Int Ed 41(17): 3185-3187
    • (2002) Angew Chem Int Ed , vol.41 , Issue.17 , pp. 3185-3187
    • Konduri, R.1    Ye, H.2    MacDonnell, F.M.3    Serroni, S.4    Campagna, S.5    Rajeshwar, K.6
  • 42
    • 0038969702 scopus 로고
    • Photochemical hydrogen production: Development of efficient heterogeneous redox catalysts
    • Lehn J-M, Sauvage J-P and Ziessel R (1981) Photochemical hydrogen production: development of efficient heterogeneous redox catalysts. Nov J Chim 5: 291
    • (1981) Nov J Chim , vol.5 , pp. 291
    • Lehn, J.-M.1    Sauvage, J.-P.2    Ziessel, R.3
  • 43
    • 0021840853 scopus 로고
    • Photo-induced hydrogen evolution from water in the presence of EDTA and a platinum/titanium dioxide supported catalyst
    • Loy L and Wolf EE (1985) Photo-induced hydrogen evolution from water in the presence of EDTA and a platinum/titanium dioxide supported catalyst. Solar Energy 34(6): 455-461
    • (1985) Solar Energy , vol.34 , Issue.6 , pp. 455-461
    • Loy, L.1    Wolf, E.E.2
  • 44
    • 0029468278 scopus 로고
    • High-valent oxomanganese clusters: Structural and mechanistic work relevant to the oxygen-evolving center in photosystem II
    • Manchanda R, Brudvig GW and Crabtree RH (1995) High-valent oxomanganese clusters: structural and mechanistic work relevant to the oxygen-evolving center in photosystem II. Coord Chem Rev 144: 1-38
    • (1995) Coord Chem Rev , vol.144 , pp. 1-38
    • Manchanda, R.1    Brudvig, G.W.2    Crabtree, R.H.3
  • 46
    • 0343148642 scopus 로고
    • Chemical approaches to artificial photosynthesis
    • Meyer TJ (1989) Chemical approaches to artificial photosynthesis. Acc Chem Res 22: 163
    • (1989) Acc Chem Res , vol.22 , pp. 163
    • Meyer, T.J.1
  • 48
    • 0037121875 scopus 로고    scopus 로고
    • Interplay of light antenna and excitation 'energy reservoir' effects in a bichromophoric system based on ruthenium-polypyridine and pyrene units linked by a long and flexible poly(ethylene glycol) chain
    • Morales AF, Accorsi G, Armaroli N, Barigelletti F, Pope SJA and Ward MD (2002) Interplay of light antenna and excitation 'energy reservoir' effects in a bichromophoric system based on ruthenium-polypyridine and pyrene units linked by a long and flexible poly(ethylene glycol) chain. Inorg Chem 41(25): 6711-6719
    • (2002) Inorg Chem , vol.41 , Issue.25 , pp. 6711-6719
    • Morales, A.F.1    Accorsi, G.2    Armaroli, N.3    Barigelletti, F.4    Pope, S.J.A.5    Ward, M.D.6
  • 50
    • 0005381370 scopus 로고    scopus 로고
    • Electrochemical and spectroelectrochemical studies of dihydro-tetra-azapentacene as a model of polyazaacene
    • Sawtschenko L, Jobst K, Neudeck A and Dunsch L (1996) Electrochemical and spectroelectrochemical studies of dihydro-tetra-azapentacene as a model of polyazaacene. Electrochimica Acta 41: 123-131
    • (1996) Electrochimica Acta , vol.41 , pp. 123-131
    • Sawtschenko, L.1    Jobst, K.2    Neudeck, A.3    Dunsch, L.4
  • 55
    • 0031286917 scopus 로고    scopus 로고
    • Photo-induced generation of dihydrogen and reduction of carbon dioxide using transition metal complexes
    • Sutin N, Creutz C and Fujita E (1997) Photo-induced generation of dihydrogen and reduction of carbon dioxide using transition metal complexes. Comm Inorg Chem 19(2): 67-92
    • (1997) Comm Inorg Chem , vol.19 , Issue.2 , pp. 67-92
    • Sutin, N.1    Creutz, C.2    Fujita, E.3
  • 56
    • 0002891361 scopus 로고    scopus 로고
    • Oxygen production in nature: A light-driven metalloradical enzyme process
    • Tommos C and Babcock GT (1998) Oxygen production in nature: a light-driven metalloradical enzyme process. Acc Chem Res 31: 18-25
    • (1998) Acc Chem Res , vol.31 , pp. 18-25
    • Tommos, C.1    Babcock, G.T.2
  • 58
  • 59
    • 0005385542 scopus 로고
    • Photogeneration of strong one- and two-electron redox agents from transition metal complexes
    • Watts RJ (1991) Photogeneration of strong one- and two-electron redox agents from transition metal complexes. Comm Inorg Chem 11: 303-337
    • (1991) Comm Inorg Chem , vol.11 , pp. 303-337
    • Watts, R.J.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.