Four-electron photochemistry of dirhodium fluorophosphine compounds

Journal of the American Chemical Society

Volumn 121, Issue 21, 1999, Pages 5023-5032

  Heyduk, Alan F ^a   Macintosh, Ann M ^a   Nocera, Daniel G ^a  

^a MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DIRHODIUM FLUOROPHOSPHINE; PHOSPHINE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL MODIFICATION; CHEMICAL STRUCTURE; COMPLEX FORMATION; ELECTRON; IRRADIATION; LIGHT; MATHEMATICAL ANALYSIS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOTOCHEMISTRY; PHOTOLYSIS; QUANTITATIVE ASSAY; SPECTRAL SENSITIVITY; SPECTROSCOPY; STRUCTURE ANALYSIS; SYNTHESIS; ULTRAVIOLET RADIATION;

EID: 0033516306     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9902017     Document Type: Article

References (87)

1. Photosensitization and Photocatalysis Using Inorganic and Organometallic Compounds; Kalyanasundaram, K., Grätzel, M., Eds.; Catalysis by Metal Complexes 14; Kluwer Academic: Dordrecht, 1993; pp 247-271.
2. Amouyal, E. In Homogeneous Photocatalysis; Chanon, M., Ed.; Wiley: New York, 1997; pp 263-307.
3. Bignozzi, C. A.; Schoonover, J. R.; Scandola, F. Prog. Inorg. Chem. 1997, 44, 1-95.
4. von Zelewsky, A. Chimia 1994, 48, 331-335.
5. Sutin, N.; Creutz, C.; Fujita, E. Comments Inorg. Chem. A 1997, 19, 67-92.
6. Roundhill, D. M. Photochemistry and Photophysics of Metal Complexes; Plenum Press: New York, 1994.
7. Schoonover, J. R.; Bignozzi, C. A.; Meyer, T. J. Coord. Chem. Rev. 1997, 165, 239-266.
8. Krausz, E.; Ferguson, J. Prog. Inorg. Chem. 1989, 37, 293-390.
9. Juris, A.; Balzani, V.; Barigelletti, F.; Campagna, S.; Belser, P.; von Zelewsky, A. Coord. Chem. Rev. 1988, 84, 85-277.
10. Kalyanasundaram, K. Photochemistry of Polypyridine and Porphyrin Complexes; Academic Press: London, 1982; Chapter 6.
11. Crosby, G. L. Acc. Chem. Res. 1975, 8, 231-238.
12. (a) Argazzi, R.; Bignozzi, C. A.; Hasselmann, G. M.; Meyer, G. J. Inorg. Chem. 1998, 37, 4533-4537.
13. (b) Garcia, C. G.; Iha, N. Y. M.; Argazzi, R.; Bignozzi, C. A. J. Photochem. Photobiol. A 1998, 115, 239-242.
14. Premkumar, J.; Ramaraj, R. J. Chem. Soc., Dalton Trans. 1998, 3667-3672.
15. Dutta, P. K.; Ledney, M. Prog. Inorg. Chem. 1997, 44, 209-271.
16. Levy, B. J. Electroceram. 1997, 1, 239-272.
17. Balzani, V.; Barigelletti, F.; Decola, L. Top. Curr. Chem. 1990, 158, 31-71.
18. (a) Vaida, V. In High Energy Processes in Organometallic Chemistry; Suslick, K. S., Ed.; ACS Symposium Series 333; American Chemical Society: Washington, DC, 1987; pp 70-80.
19. (b) Rothberg, L. J.; Cooper, N. J.; Peters, K. S.; Vaida, V. J. Am. Chem. Soc. 1982, 104, 3536-3537.
20. Zhang, J. Z.; Harris, C. B. J. Chem. Phys. 1991, 95, 4024-4032.
21. Owrutsky, J. C.; Baronavski, A. P. J. Chem. Phys. 1996, 105, 9864-9873.
22. Kim, S. K.; Pedersen, S.; Zewail, A. H. Chem. Phys. Lett. 1995, 233, 500-508.
23. Stufkens, D. J.; van der Graaf, T.; Stor, G. J.; Oskam, A. In Photoprocesses in Transition Metal Complexes, Biosystems and Other Molecules. Experiment and Theory; Kochanski, E., Ed.; NATO ASI Series C, Mathematical and Physical Sciences 376; Kluwer Academic; Dordrecht, 1992; pp 217-232.
24. Geoffrey, G. L.; Wrighton, M. S. Organometallic Photochemistry; Academic Press: New York, 1979.
25. (a) Che, C.-M.; Butler, L. G.; Gray, H. B.; Crooks, R. M.; Woodruff, W. H. J. Am. Chem. Soc. 1983, 105, 5492-5494.
26. (b) Rice, S. F.; Gray, H. B. J. Am. Chem. Soc. 1983, 105, 4571-4575.
27. (c) Che, C.-M.; Butler, L. G.; Gray, H. B. J. Am. Chem. Soc. 1981, 103, 7796-7797.
28. Fordyce, W. A.; Brummer, J. G.; Crosby, G. A. J. Am. Chem. Soc. 1981, 103, 7061-7064.
29. (a) Roundhill, D. M.; Gray, H. B.; Che, C.-M. Acc. Chem. Res. 1989, 22, 55-61.
30. (b) Smith, D. C.; Gray, H. B. Coord. Chem. Rev. 1990, 100, 169-181.
31. (a) Yam, V. W. W.; Lo, K. K. W.; Fung, W. K. M.; Wang, C. R. Coord. Chem. Rev. 1998, 171, 17-41.
32. (b) Yam, V. W. W.; Choi, S. W. K. J. Chem. Soc., Dalton Trans. 1996, 4227-4232.
33. Vogler, A.; Quett, C.; Kunkely, H. Ber. Bunsen. Ges. Phys. Chem. 1988, 92, 1486-1492.
34. Cameron, R. E.; Bocarsly, A. B. Inorg. Chem. 1986, 25, 2910-2913.
35. (a) Tokel-Takvoryan, N. E.; Hemingway, R. E.; Bard, A. J. J. Am. Chem. Soc. 1973, 95, 6582-6589.
36. (b) Garcia, E.; Kwak, J.; Bard, A. J. Inorg. Chem. 1988, 27, 4377-4382.
37. Ying, W.; Pfennig, B. W.; Sharp, S. L.; Ludvig, D. R.; Warren, C. J.; Vicenzi, E. P.; Bocarsly, A. B. Coord. Chem. Rev. 1997, 159, 245-255.
38. (a) Nocera, D. G. Acc. Chem. Res. 1995, 28, 209-217.
39. (b) Nocera, D. G. J. Cluster Sci. 1994, 5, 185-209.
40. Vogler, A.; Osman, A. H.; Kunkely, H. Coord. Chem. Rev. 1985, 64, 159-173.
41. Young, C. G. Coord. Chem. Rev. 1989, 96, 89-251.
42. Mixed Valency System: Applications in Chemistry, Physics and Biology; Prassides, K., Ed.; NATO ASI Series C, Mathematical and Physical Sciences 343; Kluwer Academic: Dordrecht, 1991.
43. Haines, R. J.; Meintjies, E.; Laing, M. Inorg. Chim. Acta 1979, 36, L403-404.
44. (a) Dulebohn, J. I.; Ward, D. L.; Nocera, D. G. J. Am. Chem. Soc. 1988, 110, 4054-4056.
45. (b) Dulebohn, J. I.; Ward, D. L.; Nocera, D. G. J. Am. Chem. Soc. 1990, 112, 2969-2977.
46. Kadis, J.; Shin, Y.-g. K.; Dulebohn, J. I.; Ward, D. L.; Nocera, D. G. Inorg. Chem. 1996, 35, 811-817.
47. Armarego, W. L. F.; Perrin, D. D. Purification of Laboratory Chemicals, 4th ed.; Butterworth-Heinmann: Oxford, 1996.
48. Nixon, J. F. J. Chem. Soc. A 1968, 2689-2692.
49. King, R. B.; Gimeno, J. Inorg. Chem. 1978, 17, 2390-2395.
50. Osborn, J. A.; Wilkinson, G. Inorg. Synth. 1990, 28, 77-79.
51. Giordano, G.; Crabtree, R. H. Inorg. Synth. 1990, 28, 88-90.
52. Murov, S. L.; Carmichael, I.; Hug, G. L. Handbook of Photochemistry, 2nd ed.; Marcel Dekker: New York, 1993.
53. Landrum, G. A. YAeHMOP: Yet Another extended Hückel Molecular Orbital Package. YAeHMOP is freely available on the World Wide Web at http://overlap.chera.cornell.edu:8080/yaehmop.html.
54. Kolb, C.; Bogart, R.; Rayshade, v. 4.0. Rayshade is available on the World Wide Web at http://aperture.stanford.edu/~cek/rayshade/rayshade.html.
55. Bennett, M. A.; Patimore, D. J. Inorg. Chem. 1971, 10, 2387-2395.
56. King, R. B.; Gimeno, J., Lotz, T. J. Inorg. Chem. 1978, 17, 2401-2405.
57. King, R. B. Acc. Chem. Res. 1980, 13, 243-248.
58. (a) Miskowski, V. M.; Gray, H. B. In Understanding Molecular Properties; Avery, J., Dahl, J. P., Hansen, A. E., Eds.; Reidel: Dordrecht, 1987; p 1.
59. (b) Miskowski, V. M.; Smith, T. P.; Loehr, T. M.; Gray, H. B. J. Am. Chem. Soc. 1985, 107, 7925-7934.
60. Reinking, M. K.; Kullburg, M. L.; Cutler, A. R.; Kubiak, C. P. J. Am. Chem. Soc. 1985, 107, 3517-3524.
61. Tolman, C. A. Chem. Rev. 1977, 77, 313-48.
62. Shin, Y.-g. K.; Miskowski, V. M.; Nocera, D. G. Inorg. Chem. 1990, 29, 2308-2313.
63. Kunkely, H.; Vogler, A. J. Organomet. Chem. 1997, 541, 177-179.
64. max = 352 nm).
65. Fossey, J.; Lefort, D. Free Radicals in Organic Chemistry; Wiley: New York, 1995.
66. Morse, J. G.; Cohn, K.; Rudolph, R. W.; Parry, R. W. Inorg. Synth. 1967, 10, 147-159.
67. 1H NMR spectrum at 16.3 ppm for the acid proton and at 2.96 ppm for the methyl groups.
68. Albright, T. A.; Burdett, J. K.; Whangbo, M.-H. Orbital Interactions in Chemistry; Wiley-Interscience: New York, 1985.
69. (a) Engebretson, D. S.; Zaleski, J. M.; Leroi, G. E.; Nocera, D. G. Science 1994, 265, 759-762.
70. (b) Engebretson, D. S.; Graj, E. M.; Leroi, G. E.; Nocera, D. G. J. Am. Chem. Soc. 1999, 121, 868-869.
71. (a) Hsu, T.-L. C.; Helvoigt, S. A.; Partigianoni, C. M.; Turró, C.; Nocera, D. G. Inorg. Chem. 1995, 34, 6186-6190.
72. (b) Hsu, T.-L. C.; Engebretson, D. S.; Nocera, D. G. Inorg. Chim. Acta 1995, 240, 551-557.
73. (c) Hsu, T.-L. C.; Chang, I.-J.; Ward, D. L.; Nocera, D. G. Inorg. Chem. 1994, 33, 2932-2937.
74. (d) Partigianoni, C. M.; Turró, C.; Hsu, T.-L. C.; Chang, I.-J.; Nocera, D. G. In Photosensitive Metal-Organic Systems; Kutal, C., Serpone, N., Eds.; ACS Advances in Chemistry Series 238; American Chemical Society: Washington, DC, 1993; pp 147-163.
75. (e) Partigianoni, C. M.; Nocera, D. G. Inorg. Chem. 1990, 29, 2033-2034.
76. Pistorio, B. J.; Nocera, D. G., submitted for publication.
77. (a) Halpern, J. Inorg. Chim. Acta 1982, 62, 31-37.
78. (b) Halpern, J.; Goodall, B. L.; Khare, G. P.; Lim, H. S.; Pluth, J. J. J. Am. Chem. Soc. 1975, 97, 2301-2303.
79. Halpern, J.; Wong, C. S. Chem. Commun. 1973, 629-630.
80. (a) Schenck, T. G.; Downes, J. M.; Milne, C. R. C.; Mackenzie, P. B.; Boucher, H.; Whelan, J.; Bosnich, B. Inorg. Chem. 1985, 24, 2334-2337.
81. (b) Schenck, T. G.; Milne, C. R. C.; Sawyer, J. F.; Bosnich, B. Inorg. Chem. 1985, 24, 2338-2344.
82. (c) Bosnich, B.; Boucher, H.; Marshall, C. Inorg. Chem. 1976, 16, 634-638.
83. Tolman, C. A.; Meakin, P. Z.; Lindner, D. L.; Jesson, J. P. J. Am. Chem. Soc. 1974, 96, 2762-2774.
84. McCollum, D. G.; Bosnich, B. Inorg. Chim. Acta 1998, 270, 13-19.
85. Mizoguchi, T. J.; Lippard, S. L. J. Am. Chem. Soc. 1998, 120, 11022-11023.
86. Marshall, J. L.; Steigman, A. E.; Gray, H. B. In Excited States and Reactive Intermediates; Lever, A. B. P., Ed.; ACS Symposium Series 307; American Chemical Society: Washington, DC, 1986; pp 166-176.
87. Gray, H. B.; Maverick, A. W. Science 1981, 214, 1201-1205.