Spontaneous formation of gold nanoparticles in poly(ethylene oxide)-poly(propylene oxide) solutions: Solvent quality and polymer structure effects

Langmuir

Volumn 21, Issue 17, 2005, Pages 8019-8025

  Sakai, Toshio ^a   Alexandridis, Paschalis ^a  

^a State University of New York ^*  (United States)

Author keywords

[No Author keywords available]

Indexed keywords

FORMAMIDE; HYDROGEN TETRACHLOROAURATE(III) HYDRATE; POLY(ETHYLENE OXIDE)-POLY(PROPYLENE OXIDE) SOLUTIONS;

BLOCK COPOLYMERS; IONS; MICELLES; NANOSTRUCTURED MATERIALS; PARTICLE SIZE ANALYSIS; POLYETHYLENE OXIDES;

GOLD;

CHLORIDE; FORMAMIDE; FORMAMIDE DERIVATIVE; GOLD; GOLD DERIVATIVE; GOLD TETRACHLORIDE, ACID; MACROGOL DERIVATIVE; NANOPARTICLE; POLYMER; POLYPROPYLENE GLYCOL; PROPANEDIOL DERIVATIVE; SOLVENT;

ARTICLE; CHEMISTRY; OXIDATION REDUCTION REACTION; PARTICLE SIZE; SOLUBILITY; SOLUTION AND SOLUBILITY; SURFACE PROPERTY; TEMPERATURE;

CHLORIDES; FORMAMIDES; GOLD; GOLD COMPOUNDS; NANOPARTICLES; OXIDATION-REDUCTION; PARTICLE SIZE; POLYETHYLENE GLYCOLS; POLYMERS; PROPYLENE GLYCOLS; SOLUBILITY; SOLUTIONS; SOLVENTS; SURFACE PROPERTIES; TEMPERATURE;

EID: 33646135525     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la050756h     Document Type: Article

References (41)

1. Pastoriza-Santos, I.; Liz-Marzan, L. M. Formation and Stabilization of Silver Nanoparticles through Reduction by N,N-Dimethylformamide. Langmuir 1999, 15 (4), 948-951.
2. Osakada, K.; Taniguchi, A.; Kubota, E.; Dev, S.; Tanaka, K.; Kubota, K.; Yamamoto, T. New Organosols of Copper(II) Sulfide, Cadmium Sulfide, Zinc Sulfide, Mercury(II) Sulfide, Nickel(II) Sulfide and Mixed Metal Sulfides in N,N-Dimethylformamide and Dimethyl Sulfoxide. Preparation, Characterization, and Physical Properties. Chem. Mater. 1992, 4 (3), 562-570.
3. Murakoshi, K.; Hosokawa, H.; Saitoh, M.; Wada, Y.; Sakata, T.; Mori, H.; Satoh, M.; Yanagida, S. Preparation of Size-Controlled Hexagonal CdS Nanocrystallites and the Characteristics of their Surface Structures. J. Chem. Soc., Faraday Trans. 1998, 94 (4), 579-586.
4. Chen, D. H.; Huang, Y. W. Spontaneous Formation of Ag Nanoparticles in Dimethylacetamide Solution of Poly(ethylene glycol). J. Colloid Interface Sci. 2002, 255 (2), 299-302.
5. Liz-Marzan, L. M.; Lado-Tourino, I. Reduction and Stabilization of Silver Nanoparticles in Ethanol by Nonionic Surfactants. Langmuir 1996, 12 (15), 3585-3589.
6. Linnert, T.; Mulvaney, P.; Henglein, A.; Weller, H. Long-Lived Nonmetallic Silver Clusters in Aqueous Solution: Preparation and Photolysis. J. Am. Chem. Soc. 1990, 112 (12), 4657-4664.
7. Yonezawa, Y.; Sato, T.; Kuroda, S.; Kuge, K. Photochemical Formation of Colloidal Silver-Peptizing Action of Acetone Ketyl Radical. J. Chem. Soc., Faraday Trans. 1991, 87 (12), 1905-1910.
8. Yeung, S. A.; Hobson, R.; Biggs, S.; Grieser, F. Formation of Gold Sols Using Ultrasound. J. Chem. Soc., Chem. Commun. 1993, No. 4, 378-379.
9. Hirai, H.; Nakao, Y.; Toshima, N. Preparation of Colloidal Transition-Metals in Polymers by Reduction with Alcohols or Ethers. J. Macromol. Sci., Chem. 1979, A13 (6), 727-750.
10. 2 with Enhanced Photocatalytic and Bactericidal Activities. Langmuir 2003, 19 (24), 10372-10380.
11. Hirai, H.; Nakao, Y.; Toshima, N. Preparation of Colloidal Rhodium in Poly(vinyl-alcohol) by Reduction with Methanol. J. Macromol. Sci., Chem. 1978, A12 (8), 1117-1141.
12. Huang, Z.-Y.; Mills, G.; Hajek, B. Spontaneous Formation of Silver Particles in Basic 2-Propanol. J. Phys. Chem. 1993, 97 (44), 11542-11550.
13. Esumi, K; Hosoya, T.; Suzuki, A.; Torigoe, K. Formation of Gold and Silver Nanoparticles in Aqueous Solution of Sugar-Persubstituted Poly(amidoamine) Dendrimers. J. Colloid Interface Sci. 2000, 226 (2), 346-352.
14. Esumi, K.; Hosoya, T.; Suzuki, A.; Torigoe, K. Spontaneous Formation of Gold Nanoparticles in Aqueous Solution of Sugar-Persubstituted Poly(amidoamine) Dendrimers. Langmuir 2000, 16 (6), 2978-2980.
15. Esumi, K.; Nakamura, R.; Suzuki, A.; Torigoe, K. Preparation of Platinum Nanoparticles in Ethyl Acetate in the Presence of Poly(amidoamine) Dendrimers with a Methyl Ester Terminal Group. Langmuir 2000, 16 (20), 7842-7846.
16. Esumi, K.; Kameo, A.; Suzuki, A.; Torigoe, K. Preparation of Gold Nanoparticles in Formamide and N,N-Dimethylformamide in the Presence of Poly(amidoamine) Dendrimers with Surface Methyl Ester Groups. Colloids Surf., A 2001, 189 (1-3), 155-161.
17. Yu, J. Y.; Schreiner, S.; Vaska, L. Homogeneous Catalytic Production of Hydrogen and Other Molecules from Water-DMF Solutions. Inorg. Chim. Acta 1990, 170 (2), 145-147.
18. Hugar, G. H.; Nandibewoor, S. T. Kinetics of Oxidation of Dimethylformamide (DMF) by Diperiodatonickelate(IV) (DPN) in Aqueous Alkaline Medium. Indian J. Chem. 1993, 32A (12), 1056-1059.
19. Andrews, M. P.; Ozin, G. A. Liquid-Phase Agglomeration of Silver Atoms in Olefinic and Ether Media: Electrocatalytic Application. 2. J. Phys. Chem. 1986, 90 (13), 2929-2938.
20. Nakao, Y.; Kaeriyama, K. Adsorption of Surfactant-Stabilized Colloidal Noble Metals by Ion-Exchange Resins and their Catalytic Activity for Hydrogenation. J. Colloid Interface Sci. 1989, 131 (1), 186-191.
21. Linnert, T.; Mulvaney, P.; Henglein, A. Photochemistry of Colloidal Silver Particles: The Effects of Nitrous Oxide and Adsorbed Cyanide Ion. Ber. Bunsen-Ges. Phys. Chem. 1991, 95 (7), 838-841.
22. Mulvaney, P.; Giersig, M.; Henglein, A. Surface Chemistry of Colloidal Gold: Deposition of Lead and Accompanying Optical Effects. J. Phys. Chem. 1992, 96 (25), 10419-10424.
23. Mulvaney, P. Surface Plasmon Spectroscopy of Nanosized Metal Particles. Langmuir 1996, 12 (3), 788-800.
24. Sakai, T.; Alexandridis, P. Single-Step Synthesis and Stabilization of Metal Nanoparticles in Aqueous Pluronic Block Copolymer Solutions at Ambient Temperature. Langmuir 2004, 20 (20), 8426-8430.
25. Sakai, T.; Alexandridis, P. Mechanism of Metal Ion Reduction, Nanoparticle Growth and Size Control in Aqueous Amphiphilic Block Copolymer Solutions at Ambient Conditions. J. Phys. Chem. B 2005, 109 (16), 7766-7777.
26. Longenberger, L.; Mills, G. Formation of Metal Particles in Aqueous Solutions by Reactions of Metal Complexes with Polymers. J. Phys. Chem. 1995, 99 (2), 475-478.
27. Liu, K.-J. Nuclear Magnetic Resonance Studies of Polymer Solutions. V. Cooperative Effects in the Ion-Dipole Interaction between Potassium Iodide and Poly(ethylene oxide). Macromolecules 1968, 1 (4), 308-311.
28. Yanagida, S.; Takahashi, K.; Okahara, M. Metal-Ion Complexation of Noncyclic Polyoxyethylene Derivatives. I. Solvent Extraction of Alkali and Alkaline Earth Metal Thiocyanates and Iodides. Bull. Chem. Soc. Jpn. 1977, 50 (6), 1386-1390.
29. Alexandridis, P.; Nivaggioli, T.; Hatton, T. A. Temperature Effects on Structural Properties of Pluronic P104 and F108 PEO-PPO-PEO Block Copolymer Solutions. Langmuir 1995, 11 (5), 1468-1476.
30. Lin, Y.; Alexandridis, P. Temperature-Dependent Adsorption of Pluronic F127 Block Copolymers onto Carbon Black Particles Dispersed in Aqueous Media. J. Phys. Chem. B 2002, 106 (42), 10834-10844.
31. Alexandridis, P.; Yang, L. Micellization of Polyoxyalkylene Block Copolymers in Formamide. Macromolecules 2000, 33 (9), 3382-3391.
32. Yang, L.; Alexandridis, P. Polyoxyalkylene Block Copolymers in Formamide-Water Mixed Solvents: Micelle Formation and Structure Studied by Small-Angle Neutron Scattering. Langmuir 2000, 16 (11), 4819-4829.
33. Samii, A. A.; Karlstrom, G.; Lindman, B. Phase Behavior of Poly(ethylene oxide)-Poly(propylene oxide) Block Copolymers in Non-aqueous Solution. Langmuir 1991, 7 (6), 1067-1071.
34. Alexandridis, P. Poly(ethylene oxide)/Poly(propylene oxide) Block Copolymer Surfactants. Curr. Opin. Colloid Interface Sci. 1997, 2, 478-489.
35. Link, S.; El-Sayed, M. A. Spectral Properties and Relaxation Dynamics of Surface Plasmon Electronic Oscillations in Gold and Silver Nanodots and Nanorods. J. Phys. Chem. B 1999, 103 (40), 8410-8426.
36. Elliott, B. J.; Willis, W. B.; Bowman, C. N. Polymerization Kinetics of Pseudocrown Ether Network Formation for Facilitated Transport Membranes. Macromolecules 1999, 32 (10), 3201-3208.
37. Wang, Z. L. Transmission Electron Microscopy of Shape-Controlled Nanocrystals and their Assemblies. J. Phys. Chem. B 2000, 104 (6), 1153-1175.
38. Allpress, J. G.; Sanders, J. V. The Structure and Orientation of Crystals in Deposits of Metals on Mica. Surf. Sci. 1967, 7 (1), 1-25.
39. Kirkland, A. I.; Jefferson, D. A.; Duff, D. G.; Edwards, P. P.; Gameson, I.; Johnson, B. F. G.; Smith, D. J. Structural Studies of Trigonal Lamellar Particles of Gold and Silver. Proc. R. Soc. London, Ser. A 1993, 440 (1910), 589-609.
40. Sun, Y. G.; Xia, Y. N. Shape-Controlled Synthesis of Gold and Silver Nanoparticles. Science 2002, 298, 2176-2179.
41. Sau, T. K.; Murphy, C. J. Room Temperature, High-Yield Synthesis of Multiple Shapes of Gold Nanoparticles in Aqueous Solution. J. Am. Chem. Soc. 2004, 126 (28), 8648-8649.