Molecular imprinting of cyclodextrin on silica-gel support for the stationary phase of high-performance-liquid-chromatography

Journal of Inclusion Phenomena

Volumn 41, Issue 1-4, 2001, Pages 149-153

  Akiyama, Tomohiro ^a   Hishiya, Takayuki ^a   Asanuma, Hiroyuki ^a   Komiyama, Makoto ^a  

^a UNIVERSITY OF TOKYO   (Japan)

Author keywords

Cyclodextrin; HPLC; Molecular imprinting; Silica gel

Indexed keywords

EID: 0035624633     PISSN: 09230750     EISSN: None     Source Type: Journal    
DOI: 10.1023/A:1014446420222     Document Type: Article

References (25)

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21. 6. Non-specific binding is enhanced when an aromatic moiety is introduced into the crosslinking agent. Note that conventional imprinting requires much excess crosslinking agent compared with the functional monomer.
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23. 2 per one acryloyl-CD molecule. Thus, the polymer on the surface of the silica-gel should be a unimolecular layer or bilayer.
24. 9. Intrinsically, β-CD prefers D-Phe-D-Phe to its enantiomer: see Ref. 5e.
25. 10. All the substrates used here have aromatic groups which form complexes with CD in water.