STM/STS observation of polyoxoanions on HOPG surfaces: The wheel-shaped [Cu20Cl(OH)24(H2O)12(P 8W48O184)]25- and the ball-shaped [{Sn(CH3)2(H2O)}24{Sn(CH 3)2}12(A-PW9O34) 12]36-

Inorganic Chemistry

Volumn 45, Issue 7, 2006, Pages 2866-2872

  Alam, Mohammad S ^a   Dremov, Viacheslav ^a   Müller, Paul ^a   Postnikov, Andrei V ^b,c   Mal, Sib Sankar ^d   Hussein, Firasat ^d   Kortz, Ulrich ^d  

^a UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

^b UNIVERSITÉ DE LORRAINE   (France)

^c INSTITUTE OF METAL PHYSICS   (Russian Federation)

^d JACOBS UNIVERSITY BREMEN   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33645854367     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic051586z     Document Type: Article

References (47)

1. Binnig, G.; Rohrer, H.; Gerber, C.; Weibel, E. Phys. Rev. Lett. 1982, 49, 57.
2. Chiang, S. in: Güntherodt, H. J., Wiesendanger, R., Eds. Scanning Tunneling Microscopy 1; Springer-Verlag: Berlin, 1992; p 182.
3. Jung, T. A.; Himpsel, F. J.; Schlittler, R. R.; Gimzewski, J. K. In Scanning Probe Microscopy; Wiesendanger, R., Ed.; Springer-Verlag: Berlin, 1998; p 11.
4. Song, I. K.; Shnitser, R. B.; Cowan, J. J.; Hill, C. L.; Barteau, M. A. Inorg. Chem. 2002, 41, 1292.
5. Song, I. K.; Barteau, M. A. Kor. J. Chem. Eng. 2002, 19, 567.
6. Song, I. K.; Lyons, J. E.; Barteau, M. A. Catal. Today 2003, 81, 137.
7. Kaba, M. S.; Song, I. K.; Duncan, D. C.; Hill, C. L.; Barteau, M. A. Inorg. Chem. 1998, 37, 398.
8. Song, I. K.; Kaba, M. S.; Barteau, M. A. Langmuir 2002, 18, 2358.
9. Kaba, M. S.; Song, I. K.; Barteau, M. A. J. Phys. Chem. B 2002, 106, 2337.
10. Fisher, A. J.; Blóchl, P. E. Phys. Rev. Lett. 1993, 70, 3263.
11. Paz, Ó.; Brihuega, I.; Gómez-Rodríguez, J. M.; Soler, J. M. Phys. Rev. Lett. 2005, 94, 056103.
12. Feyter, S. D.; Schryver, F. C. D. J. Phys. Chem. B 2005, 109, 4290.
13. Hembacher, S.; Giessibl, F. J.; Mannhart, J. Phys. Rev. Lett. 2005, 94, 056101.
14. Novokmet, S.; Alam, M. S.; Dremov, V.; Heinemann, F. W.; Müller, P.; Alsfasser, R. Angew. Chem., Int. Ed. 2005, 44, 803.
15. Ako, A. M.; Maid, H.; Sperner, S.; Zaidi, S. H. H.; Saalfrank, R. W.; Alam, M. S.; Müller, P.; Heinnemann, F. W. Supramol. Chem. 2005, 17, 315.
16. (a) Pope, M. T. Heteropoly and Isopoly Oxometalates; Springer-Verlag: Berlin, 1983.
17. (b) Pope, M. T.; Müller, A. Angew. Chem., Int. Ed. Engl. 1991, 30, 34.
18. (c) Polyoxometalates: From Platonic Solids to Anti-Retroviral Activity; Pope, M. T., Müller, A., Eds.; Kluwer: Dordrecht, The Netherlands, 1994.
19. (d) Chemical Reviews, Polyoxometalates; Hill, C. L., Ed.; 1998.
20. (e) Polyoxometalate Chemistry: From Topology via Self-Assembly to Applications; Pope, M. T., Müller, A., Eds.; Kluwer: Dordrecht, The Netherlands, 2001.
21. (f) Polyoxometalate Chemistry for Nano-Composite Design; Yamase, T., Pope, M. T., Eds.; Kluwer: Dordrecht, The Netherlands, 2002.
22. (g) Pope, M. T. Comput. Coord. Chem. II 2003, 4, 635.
23. (h) Hill, C. L. Comput. Coord. Chem. II 2003, 4, 679.
24. (i) Polyoxometalate Molecular Science; Borrás-Almenar, J. J., Coronado, E., Müller, A., Pope, M. T., Eds.; Kluwer: Dordrecht, The Netherlands, 2004.
25. (j) Casan-Pastor, N.; Gomez-Romero, P. Fron. Biosci. 2004, 9, 1759.
26. Mal, S. S.; Kortz, U. Angew. Chem., Int. Ed. 2005, 44, 3777.
27. Jabbour, D.; Keita, B.; Nadjo, L.; Kortz, U.; Mal, S. S. Electrochem. Comm. 2005, 7, 841.
28. Kortz, U.; Hussain, F.; Reicke, M. Angew. Chem., Int. Ed. 2005, 44, 3773.
29. Errington, R. J.; Petkar, S. S.; Horrocks, B. R.; Houlton, A.; Lie, L. H.; Patole, S. N. Angew. Chem. 2005, 117, 1280.
30. Keita, B.; Nadjo, L. Surf. Sci. 1991, 254, L443.
31. De Feyter, S.; De Schryver, F. C. Chem. Soc. Rev. 2003, 32, 139.
32. Samorì, P. Chem. Soc. Rev. 2005, 34, 551.
33. (a) Ho, W. J. Chem. Phys. 2002, 117, 11033.
34. (b) Wahl, P.; Diekhöner, L.; Schneider, M. A.; Vitali, L.; Wittich, G.; Kern, K. Phys. Rev. Lett. 2004, 93, 176603.
35. (a) Miura, A.; Chen, Z.; Uji-i, H.; De Feyter, S.; Zdanowska, M.; Jonkheijm, P.; Schenning, A. P. H. J.; Meijer, E. W.; Würthner, F.; De Schryver, F. C. J. Am. Chem. Soc. 2003, 125, 14968.
36. (b) Gesquière, A.; De Feyter, S.; De Schryver, F. C.; Schoonbeek, F.; van Esch, J.; Kellogg, R. M.; Feringa, B. L. Nano Lett. 2001, 1, 201.
37. (c) Jäckel, F.; Watson, M. D.; Müllen, K.; Rabe, J. P. Phys. Rev. Lett. 2004, 92, 188303.
38. Matsui, T.; Kambara, H.; Niimi, Y.; Tagami, K.; Tsukada, M.; Fukuyama, H. Phys. Rev. Lett. 2005, 94, 226403.
39. Klusek, Z.; Kozlowski, W. J. Electron Spectrosc. Relat. Phenom. 2000, 107, 63.
40. Hamers, R. J.; Tromp, R. M.; Demuth, J. E. Phys. Rev. Lett. 1986, 56, 1974.
41. Alam, M. S.; Strömsdörfer, S.; Dremov, V.; Müller, P.; Kortus, J.; Ruben, M.; Lehn, J. M. Angew. Chem. Int. Ed. 2005, 44, 7896.
42. Scanning Tunneling Microscopy; Stroscio, J. A., Kaiser, W. J., Eds.; Academic Press: New York, 1993.
43. Rivera, M.; Williamson, R. L.; Miles, M. J. J. Vac. Sci. Technol. B 1996, 14, 1472.
44. Soler, J. M.; Artacho, E.; Gale, J. D.; García, A.; Junquera, J.; Ordejón, P.; Sánchez-Portal, D. J. Phys.: Condens. Matter 2002, 14, 2745; http://www.uam.es/siesta/.
45. Allalen, M.; Schnack, J., private communication.
46. It could be added that a notably insufficient inclusion of Coulomb correlation effects in a conventional DFT calculation like the present one cannot be responsible for the discrepancy observed. Namely, the qualitative effect of stronger Coulomb correlation within the quite localized Cu 3d shell is predictable. It would be the shift of the occupied Cu d levels downward, enhancing the O 2p character in the highest occupied states.
47. Lindsay, S. J. Chem. Educ. 2005, 82, 727.