Comment on "disproving a silicon analog of an alkyne with the aid of topological analyses of the electronic structure and ab initio molecular dynamics calculations"

ChemPhysChem

Volumn 7, Issue 4, 2006, Pages 799-800

  Frenking, Gernot ^a   Krapp, Andreas ^a   Nagase, Shigeru ^b   Takagi, Nozomi ^b   Sekiguchi, Akira ^c  

^a PHILIPPS UNIVERSITY MARBURG   (Germany)

^b INSTITUTE FOR MOLECULAR SCIENCE   (Japan)

^c UNIVERSITY OF TSUKUBA   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; ELECTRONIC STRUCTURE; MOLECULAR DYNAMICS; SILICON;

AB INITIO MOLECULAR DYNAMICS; BOND ORDERING; BONDING SITUATION; DONOR ACCEPTORS; SILICON-SILICON BOND; TOPOLOGICAL ANALYSIS; TRIPLE BONDS;

CALCULATIONS;

EID: 33645825850     PISSN: 14394235     EISSN: 14397641     Source Type: Journal    
DOI: 10.1002/cphc.200500689     Document Type: Review

References (8)

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7. In the planar structure there is an additional π contribution due to the donation from the nitrogen lone pair orbital into the vacant p(π) AO of boron.
8. H. Grützmacher, T. Fässler, Chem. Eur. J. 2000, 6, 2317.