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Volumn 6, Issue 13, 2000, Pages 2317-2325

Topographical analyses of homonuclear multiple bonds between main group elements

Author keywords

Bond theory; Electron localization function; Main group elements; Multiple bonds

Indexed keywords

ARTICLE; CHEMICAL BINDING; CHEMICAL BOND; CHEMICAL STRUCTURE; STRUCTURE ANALYSIS; TOPOGRAPHY;

EID: 0040531391     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3765(20000703)6:13<2317::AID-CHEM2317>3.0.CO;2-X     Document Type: Article
Times cited : (129)

References (89)
  • 1
    • 0342522385 scopus 로고
    • [1a]: "By the term bond I intend merely to give a more concrete expression to such names as 'an atomicity', 'an atomic power', or 'an equivalence'.... By this term I do not intend to convey the idea of any material connection." E. Frankland, J. Chem. Soc. 1866, 19, 372;
    • (1866) J. Chem. Soc. , vol.19 , pp. 372
    • Frankland, E.1
  • 26
    • 0042294914 scopus 로고    scopus 로고
    • c) M. Driess, H. Grützmacher, Angew. Chem. 1996, 108, 900; Angew. Chem. Int. Ed. Engl. 1996, 35, 829;
    • (1996) Angew. Chem. Int. Ed. Engl. , vol.35 , pp. 829
  • 27
    • 0004144394 scopus 로고    scopus 로고
    • Special issue
    • d) Special issue Adv. Organomet. Chem. 1996, 39;
    • (1996) Adv. Organomet. Chem. , pp. 39
  • 30
    • 33748240837 scopus 로고
    • f) T. Tsumaraya, S. A. Batcheller, S. Masamune, Angew. Chem. 1991, 103, 916; Angew. Chem. Int. Ed. Engl. 1991, 30, 902;
    • (1991) Angew. Chem. Int. Ed. Engl. , vol.30 , pp. 902
  • 33
    • 0001515838 scopus 로고
    • i) R. West, Angew. Chem. 1987, 99, 1231; Angew. Chem. Int. Ed. Engl. 1987, 26, 1201;
    • (1987) Angew. Chem. , vol.99 , pp. 1231
    • West, R.1
  • 34
    • 84985559872 scopus 로고
    • i) R. West, Angew. Chem. 1987, 99, 1231; Angew. Chem. Int. Ed. Engl. 1987, 26, 1201;
    • (1987) Angew. Chem. Int. Ed. Engl. , vol.26 , pp. 1201
  • 39
    • 85037452346 scopus 로고    scopus 로고
    • For a discussion of Si=Si bond lengths see refs. [11a,f]
    • b) For a discussion of Si=Si bond lengths see refs. [11a,f];
  • 42
    • 0031906803 scopus 로고    scopus 로고
    • and references therein
    • d) recent calculations: K. W. Klinkhammer, T. F. Fässler, H. Grützmacher, Angew. Chem. 1998, 110, 114; Angew. Chem. Int. Ed. 1998, 37, 124 and references therein.
    • (1998) Angew. Chem. Int. Ed. , vol.37 , pp. 124
  • 43
    • 85037456319 scopus 로고    scopus 로고
    • For a general discussion see ref. [11b], a Group 15: P=P: refs. [10, 11h]
    • For a general discussion see ref. [11b], a) Group 15: P=P: refs. [10, 11h];
  • 46
    • 0030824246 scopus 로고    scopus 로고
    • d) Bi=Bi: N. Tokitoh, Y. Arai, R. Okazaki, S. Nagase, Science 1997, 277, 78; B. Twamley, C. D. Sofield, M. M. Olmstead, P. P. Power, J. Am. Chem. Soc. 1999, 121, 3357.
    • (1997) Science , vol.277 , pp. 78
    • Tokitoh, N.1    Arai, Y.2    Okazaki, R.3    Nagase, S.4
  • 51
    • 0002938113 scopus 로고    scopus 로고
    • Gallium triple bonds under fire
    • March 16
    • a) See the "hot article": Gallium Triple Bonds Under Fire by R. Dagani in Chem. Eng. News 1998, March 16.
    • (1998) Chem. Eng. News
    • Dagani, R.1
  • 52
    • 85037453932 scopus 로고    scopus 로고
    • Note that the ambiguity of the graphical representation of acetylene as HC≡CH or HC:-C:H was already recognized in the middle of the last century (see ref. [2b])
    • b) Note that the ambiguity of the graphical representation of acetylene as HC≡CH or HC:-C:H was already recognized in the middle of the last century (see ref. [2b]).
  • 55
    • 84989515977 scopus 로고
    • b) For a rather complete listing of work devoted to Group 14 double bonds see: H. Jacobsen, T. Ziegler, J. Am. Chem. Soc. 1994, 116, 3667;
    • (1994) J. Am. Chem. Soc. , vol.116 , pp. 3667
    • Jacobsen, H.1    Ziegler, T.2
  • 61
    • 0000615410 scopus 로고
    • For a discussion of the effect of intra atomic repulsion on the bonding in main group elements see: h) W. Kutzelnigg, Angew. Chem. 1984, 96, 262; Angew. Chem. Int. Ed. Engl. 1984, 23, 272.
    • (1984) Angew. Chem. , vol.96 , pp. 262
    • Kutzelnigg, W.1
  • 62
    • 0343265434 scopus 로고
    • For a discussion of the effect of intra atomic repulsion on the bonding in main group elements see: h) W. Kutzelnigg, Angew. Chem. 1984, 96, 262; Angew. Chem. Int. Ed. Engl. 1984, 23, 272.
    • (1984) Angew. Chem. Int. Ed. Engl. , vol.23 , pp. 272
  • 71
    • 85037476531 scopus 로고    scopus 로고
    • note
    • (S→T).
  • 75
    • 0030773972 scopus 로고    scopus 로고
    • a) A. Savin, R. Nesper, S. Wengert, T. F. Fässler, Angew. Chem. 1997, 109, 1892; Angew. Chem. Int. Ed. Engl. 1997, 36, 1808;
    • (1997) Angew. Chem. Int. Ed. Engl. , vol.36 , pp. 1808
  • 77
    • 33748225339 scopus 로고
    • b) A. Savin, A. D. Becke, J. Flad, R. Nesper, H. G. von Schnering, Angew. Chem. 1991, 103, 421; Angew. Chem. Int. Ed. Engl. 1991, 30, 409;
    • (1991) Angew. Chem. Int. Ed. Engl. , vol.30 , pp. 409
  • 80
    • 33749113333 scopus 로고    scopus 로고
    • a) R. J. Gillespie, E. A. Robinson, Angew. Chem. 1996, 108, 539; Angew. Chem. Int. Ed. Engl. 1996, 35, 495;
    • (1996) Angew. Chem. Int. Ed. Engl. , vol.35 , pp. 495
  • 82
    • 0040537186 scopus 로고    scopus 로고
    • 2 must lie within one region with ELF ≥ 0.8. This value might depend on the theoretical method or basis set used. In order to obtain comparable results, extended Hückel (EH) calculations were performed even when the structures were optimized with advanced methods. For a further discussion of the separation of attractors and related bifurcation diagrams see: D. Marx, A. Savin, Angew. Chem. 1997, 109, 2168; Angew. Chem. Int. Ed. Engl. 1997, 36, 2077.
    • (1997) Angew. Chem. , vol.109 , pp. 2168
    • Marx, D.1    Savin, A.2
  • 83
    • 0030727413 scopus 로고    scopus 로고
    • 2 must lie within one region with ELF ≥ 0.8. This value might depend on the theoretical method or basis set used. In order to obtain comparable results, extended Hückel (EH) calculations were performed even when the structures were optimized with advanced methods. For a further discussion of the separation of attractors and related bifurcation diagrams see: D. Marx, A. Savin, Angew. Chem. 1997, 109, 2168; Angew. Chem. Int. Ed. Engl. 1997, 36, 2077.
    • (1997) Angew. Chem. Int. Ed. Engl. , vol.36 , pp. 2077
  • 84
    • 0000481373 scopus 로고    scopus 로고
    • [12d] where we intended to include a topographical analysis of classical and nonclassical double bonds. However, this part was excluded in the refereeing process but subsequently used by K. W. Klinkhammer in a commentary on ref. [16] see: K. W. Klinkhammer, Angew. Chem. 1997, 109, 2414; Angew. Chem. Int. Ed. Engl. 1997, 36, 2320.
    • (1997) Angew. Chem. , vol.109 , pp. 2414
    • Klinkhammer, K.W.1
  • 85
    • 0030712047 scopus 로고    scopus 로고
    • [12d] where we intended to include a topographical analysis of classical and nonclassical double bonds. However, this part was excluded in the refereeing process but subsequently used by K. W. Klinkhammer in a commentary on ref. [16] see: K. W. Klinkhammer, Angew. Chem. 1997, 109, 2414; Angew. Chem. Int. Ed. Engl. 1997, 36, 2320.
    • (1997) Angew. Chem. Int. Ed. Engl. , vol.36 , pp. 2320
  • 86
    • 85037475926 scopus 로고    scopus 로고
    • note
    • 2v symmetry. Since in the heavier homologues the π - σ* gap becomes smaller, this mixing becomes more efficient and the stabilization of the π-HOMO overcompensates eventually the destabilization of the bonding E-E σ-orbital (see refs. [8c, 18b] for a more thorough discussion).
  • 89
    • 0001628833 scopus 로고
    • For attempts to visualize localized chemical bonds in digermene by relocalization of the delocalized MOs according to Boy's criterion see: G. Tinquier, J.-P. Malrieu, P. Riviere, J. Am. Chem. Soc. 1982, 104, 4529.
    • (1982) J. Am. Chem. Soc. , vol.104 , pp. 4529
    • Tinquier, G.1    Malrieu, J.-P.2    Riviere, P.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.