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Volumn , Issue 7, 2006, Pages 1672-1677

A mild chemo-enzymatic oxidation-hydrocyanation protocol

Author keywords

Hydroxynitrile lyase; Oxidation; Oxynitrilase; TEMPO

Indexed keywords


EID: 33645516788     PISSN: 1434193X     EISSN: 10990690     Source Type: Journal    
DOI: 10.1002/ejoc.200500905     Document Type: Article
Times cited : (37)

References (45)
  • 6
    • 4944219572 scopus 로고    scopus 로고
    • Synthesis and Applications of Non-Racemic Cyanohydrins and alpha-Ammo Nitriles
    • Tetrahedron
    • Special issue of Tetrahedron on "Synthesis and Applications of Non-Racemic Cyanohydrins and alpha-Ammo Nitriles": Tetrahedron 2004, 60, 10371-10568.
    • (2004) Tetrahedron , vol.60 , Issue.SPEC. ISSUE , pp. 10371-10568
  • 11
    • 0037519029 scopus 로고    scopus 로고
    • (Eds.: K. Drauz, H. Waldmann), Wiley-VCH, Weinheim, and references cited therein
    • M. H. Fechter, H. Griengl, Enzyme Catalysis in Organic Synthesis (Eds.: K. Drauz, H. Waldmann), Wiley-VCH, Weinheim, 2002, vol. 2, p. 974 and references cited therein.
    • (2002) Enzyme Catalysis in Organic Synthesis , vol.2 , pp. 974
    • Fechter, M.H.1    Griengl, H.2
  • 13
    • 0003993814 scopus 로고    scopus 로고
    • (Ed.: R. N. Patel), Marcel Dekker Inc., New York
    • F. Effenberger, Stereoselective Biocatalysis (Ed.: R. N. Patel), Marcel Dekker Inc., New York, 2000, p. 321.
    • (2000) Stereoselective Biocatalysis , pp. 321
    • Effenberger, F.1
  • 22
  • 35
    • 33645516490 scopus 로고    scopus 로고
    • note
    • When NaOCl or NaOCl/KBr was used as primary oxidant in the oxidation reaction of 3 also epoxidation of the double bond was observed.
  • 39
    • 0037021571 scopus 로고    scopus 로고
    • Biocatalysts in combination with immobilized chemical catalysts have been used before. See for example: F. Gelman, J. Blum, D. Avnir, J. Am. Chem. Soc. 2002, 124, 14460-14463.
    • (2002) J. Am. Chem. Soc. , vol.124 , pp. 14460-14463
    • Gelman, F.1    Blum, J.2    Avnir, D.3
  • 40
    • 33645516682 scopus 로고    scopus 로고
    • note
    • Due to the relatively volatile nature of the γ,δ-unsaturated alcohols 3 and their corresponding aldehydes 2, isolated yields are reported taking a 5 % error into account.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.