Largest mixed transition metal/actinide cluster: A bimetallic Mn/Th complex with a [Mn10Th6O22(OH)2] 18+ core

Inorganic Chemistry

Volumn 45, Issue 6, 2006, Pages 2364-2366

  Mishra, Abhudaya ^a   Abboud, Khalil A ^a   Christou, George ^a  

^a University of Florida ^*  (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33645506528     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic052089l     Document Type: Article

References (24)

1. (a) Yachandra, V. K.; Sauer, K.; Klein, M. P. Chem. Rev. 1996, 96, 2927.
2. (b) Ferreira, K. N.; Iverson, T. M.; Maghlaoui, K.; Barber, J.; Iwata, S. Science 2004, 303, 1831.
3. (c) Mishra, A.; Wernsdorfer, W.; Abboud, K. A.; Christou; G. Chem. Commun. 2005, 54.
4. Christou, G.; Gatteschi, D.; Hendrickson, D. N.; Sessoli, R. MRS Bull. 2000, 25, 66 and references cited therein.
5. Arndt, D. In Manganese Compounds as Oxidizing Agents in Organic Chemistry; Open Court Publishing Co.: La Salle, IL, 1981.
6. (a) Mishra, A.; Wernsdorfer, W.; Parsons, S.; Christou, G.; Brechin, E. K. Chem. Commun. 2005, 2086.
7. (b) Zaleski, C. M.; Depperman, E. C.; Kampf, J. W.; Kirk, M. L.; Pecoraro, V. L. Angew. Chem., Int. Ed. 2004, 43, 3912.
8. (c) Mishra, A.; Wernsdorfer, W.; Abboud, K. A.; Christou, G. J. Am. Chem. Soc. 2004, 126, 15648.
9. (a) Sokol, J. J.; Hee, A. G.; Long, J. R. J. Am. Chem. Soc. 2002, 124, 7656.
10. (b) Schelter, E. J.; Prosvirin, A. V.; Dunbar, K. R. J. Am. Chem. Soc. 2004, 126, 15004.
11. (a) Sternal, R. S.; Marks, T. J. Organometallics 1987, 6, 2621.
12. (b) Borgne, T. L.; Rivière, E.; Marrot, J.; Thuéry, P.; Girerd, J. J.; Ephritikhine, M. Chem. - Eur. J. 2002, 8, 74.
13. Lintvedt, R. L.; Schoenfelner, B. A.; Ceccarelli, C.; Glick, M. D. Inorg. Chem. 1984, 23, 2867.
14. (a) Kim, J.; Norquist, A. J.; O'Hare, D. J. Am. Chem. Soc. 2003, 125, 12688.
15. (b) Kim, J.; Norquist, A. J.; O'Hare, D. Chem. Commun. 2002, 2198.
16. Barnhart, D. M.; Butcher, R. J.; Clark, D. L.; Gordon, J. C.; Watkin J. G.; Zwick, B. D. New J. Chem. 1995, 19, 503.
17. Wemple, M. W.; Tsai, H.-L.; Wang, S.; Claude, J.-P.; Streib, W. E.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1996, 35, 6450.
18. 16 was used to calculate the solvent disorder area and remove its contribution to the overall intensity data.
19. IV-O bond.
20. (b) Brese, N. E.; O'Keeffe, M. Acta Crystallogr., Sect. B 1991, 47, 192. BVS values were in the range of 4.23-4.31 for the Th ions of 1.
21. Sullens, T. A.; Albrecht-Schmitt, T. E. Inorg. Chem. 2005, 44, 2282.
22. Tasiopoulos, A. J.; O'Brien, T. A.; Abboud, K. A.; Christou, G. Angew. Chem., Int. Ed. 2004, 43, 345.
23. Petrukhina, M. A.; Sergienko, V. S.; Sadikov, G. G.; Tat'yanina, I. V.; Torchenkova, E. A. Koord. Khim. 1990, 16, 354.
24. PLATON: Spek, L. Acta Crystallogr., Sect. A 1990, 46, 1.