Reactions of CpArCHCHArCp with Ru3(CO)12: An unexpected cleavage of a bridging C-C bond and coupling of the two cyclopentadienyl rings to fulvalene diruthenium complexes

Organometallics

Volumn 25, Issue 5, 2006, Pages 1158-1166

  Li, Bin ^a   Wang, Baiquan ^a   Xu, Shansheng ^a   Zhou, Xiuzhong ^a   Song, Haibin ^a  

^a NANKAI UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; HYDROGENATION; ORGANOMETALLICS; STEREOCHEMISTRY; X RAY DIFFRACTION ANALYSIS; XYLENE;

CYCLOPENTADIENYL RINGS; DIRUTHENIUM COMPLEXES; REFLUXING;

RUTHENIUM COMPOUNDS;

EID: 33644984375     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om050673w     Document Type: Article

References (43)

1. (a) Muetterties, E. L.; Rhodin, T. N.; Band, E.; Brucker, C. F.; Pretzer, W. R. Chem. Rev. 1979, 79, 91.
2. (b) Bruce, M. I. J. Organomet. Chem. 1983, 242, 147.
3. (c) Chifotides, H. T.; Dunbar, K. R. Acc. Chem. Res. 2005, 38, 146.
4. (a) Srivastava, R. S.; Nicholas, K. M. Chem. Commun. 1998, 2705.
5. (b) Kolel-Veetil, M.; Khan, M. A.; Nicholas, K. M. Organometallics 2000, 19, 3754.
6. (c) Penoni, A.; Nicholas, K. M. Chem. Commun. 2002, 484.
7. (d) Penoni, A.; Volkmann, J.; Nicholas, K. M. Org. Lett. 2002, 4, 699.
8. For general reviews of bridged bis(cyclopentadienyl) dinuclear metal complexes, see: (a) Barlow, S.; O'Hare, D. Chem. Rev. 1997, 97, 637.
9. (b) Werner, H. Inorg. Chim. Acta 1992, 198-200, 715.
10. (c) Bonifaci, C.; Ceccon, A.; Gambaro, A.; Manoli, F.; Mantovani, L.; Ganis, P.; Santi, S.; Venzo, A. J. Organomet. Chem. 1998, 557, 97.
11. (d) Cuenca, T.; Royo, P. Coord. Chem. Rev. 1999, 193-195, 447.
12. (e) Ceccon, A.; Santi, S.; Orian, L.; Bisello, A. Coord. Chem. Rev. 2004, 248, 683.
13. (f) Royo, P. New J. Chem. 1997, 27, 791.
14. (a) Boese, R.; Cammack, J. K.; Matzger, A. J.; Pflug, K.; Tolman, W. B.; Vollhardt, K. P. C.; Weidman, T. W. J. Am. Chem. Soc. 1997, 119, 6757.
15. (b) Vollhardt, K. P. C.; Weidman, T. W. J. Am. Chem. Soc. 1983, 105, 1676.
16. Fox, T.; Burger, P. Eur. J. Inorg. Chem. 2001, 795.
17. (a) Burger, P. Angew. Chem., Int. Ed. 2001, 40, 1917.
18. (b) Bitterwolf, T. E.; Leonard, M. B.; Horine, P. A.; Shade, J. E.; Rheingold, A. L.; Staley, D. J.; Yap, G. P. A. J. Organomet. Chem. 1996, 512, 11.
19. (a) Zhang, Y.; Xu, S.; Zhou, X. Organometallics 1997, 16, 6017.
20. (b) Zhang, Y.; Wang, B.; Xu, S.; Zhou, X. Organometallics 2001, 20, 3829.
21. (c) Zhang, Y.; Wang, B.; Xu, S.; Zhou, X.; Sun, J. J. Organomet. Chem. 1999, 584, 356.
22. (a) Nataro, C.; Thomas, L. M.; Angelici. R. J. Inorg. Chem. 1997, 36, 6000.
23. (b) Khayatpoor, R.; Shapley, J. R. Organometallics 2002, 21, 4794.
24. (a) Li, B.; Wang, B.; Xu, S.; Zhou, X. J. Organomet. Chem. 2005, 690, 5309.
25. (b) Kane, K. M.; Shapiro, P. J.; Vij, A.; Cubbon, R.; Rheingold, A. L. Organometallics 1997, 16, 4567.
26. Stone, K. J.; Little, R. D. J. Org. Chem. 1984, 49, 1849.
27. The sequence of the carbons in the parent fulvalene was labeled as shown.
28. 1H NMR spectra appears to correlate with the presence of metal-metal bonding, as observed earlier: (a) Smart, J. C.; Curtis, C. J. Inorg. Chem. 1977, 16, 1788.
29. (b) See also ref 4.
30. Wang, B.; Zhu, B.; Zhang, J.; Xu, S.; Zhou, X.; Weng, L. Organometallics 2003, 22, 5543.
31. Schiavo, S. L.; Renouard, C.; Simpson, M. C.; Adams, H.; Bailey, N. A.; White, C. J. Chem. Soc., Dalton Trans. 1994, 1731.
32. Vollhardt, K. P. C.; Weidman, T. W. Organometallics 1984, 3, 82.
33. Behrens, U.; Weiss, E. J. Organomet. Chem. 1975, 96, 435.
34. Cotton, F. A.; DeBoer, B. G.; Marks, T. J. J. Am. Chem. Soc. 1971, 93, 5069.
35. Mills, O. S.; Nice, J. P. J. Organomet. Chem. 1967, 9, 339.
36. (a) Zhou, X.; Zhang, Y.; Xu, S.; Tian, G.; Wang, B. Inorg. Chim. Acta 1997, 262, 109.
37. (b) Zhang, Y.; Wang, B.; Xu, S.; Zhou, X. Transition Met. Chem. 1999, 24, 610.
38. (c) Knox, S. A. R.; Macpherson, K. A.; Orpen, A. G.; Rendle. M. C. J. Chem. Soc., Dalton Trans. 1989, 1807.
39. (d) Ovchinnikov, M. V.; Klein, D. P.; Guzei, I. A.; Choi, M. G.; Angelici, R. J. Organometallics 2002, 21, 617.
40. You, S.; Gubler, M.; Neuenschwander, M. Helv. Chim. Acta 1994, 77, 1346.
41. (a) Lutz, R. P. Chem. Rev. 1984, 84, 205.
42. (b) Gajewski, J. J. Acc. Chem. Res. 1980, 13, 142.
43. Lutz, R. P.; Bernal, S.; Boggio, R. J.; Harris, R. O.; McNicholas, M. W. J. Am. Chem. Soc. 1971, 93, 3985.