Photochemically induced silicon-carbon bond cleavage in a dimethylsilyl-bridged dicyclopentadienyl diruthenium complex

European Journal of Inorganic Chemistry

Volumn , Issue 3, 2001, Pages 795-803

  Fox, Thomas ^a   Burger, Peter ^a  

^a UNIVERSITY OF ZURICH   (Switzerland)

Author keywords

Cyclopentadienes; Density functional calculations; IR spectroscopy; Photochemistry; Rearrangements; Ruthenium; Thermodynamics

Indexed keywords

BINARY ALLOYS; CARBON; CHEMICAL BONDS; CRYSTAL STRUCTURE; INFRARED IMAGING; LIGANDS; MOLECULAR STRUCTURE; RUTHENIUM COMPOUNDS; SILICON; THERMODYNAMICS; X RAY CRYSTALLOGRAPHY;

BOND CLEAVAGES; CYCLOPENTADIENES; DENSITY-FUNCTIONAL CALCULATIONS; DIRUTHENIUM COMPLEX; IR-SPECTROSCOPY; METAL-METAL BONDS; REARRANGEMENT; SILICON CARBON BOND; TWO TERMINALS; X RAY CRYSTAL STRUCTURES;

DENSITY FUNCTIONAL THEORY;

CARBON; CARBONYL DERIVATIVE; CYCLOPENTADIENE DERIVATIVE; DICYCLOPENTADIENYLRUTHENIUM COMPLEX; LIGAND; METAL; RUTHENIUM COMPLEX; SILANE DERIVATIVE; SILICON; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; PHOTOCHEMISTRY; SYNTHESIS; THERMODYNAMICS;

EID: 0035117598     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0682(200103)2001:3<795::AID-EJIC795>3.0.CO;2-7     Document Type: Article

References (39)

1. T. E. Bitterwolf, J. E. Shade, J. A. Hansen, A. L. Rheingold, J. Organomet. Chem. 1996, 514, 13-21.
2. W. Xie, B. Wang, X. Dai, X. S., X. Zhou, Organometallics 1998, 17, 5406-5410.
3. Y. Zhang, S. Xu, G. Tian, X. Zhou, J. Sun, Organometallics 1998, 17, 1122-1127.
4. X. Zhou, Y. Zhang, W. Xie, S. Xu, J. Sun, Organometallics 1997, 16, 3474-3481.
5. R. Boese, J. K. Cammack, A. J. Matzger, K. Pflug, W. B. Tolman, K. P. C. Vollhardt, T. W. Weidman, J. Am. Chem. Soc. 1997, 119, 6757-6773.
6. C. Cremer, H. Jacobsen, P. Burger, Chimia 1997, 51, 650-653.
7. T. E. Bitterwolf, M. B. Leonard, P. A. Horine, J. E. Shade, A. L. Rheingold, D. J. Staley, G. P. A. Yap, J. Organomet. Chem. 1996, 512, 11-20.
8. X. Zhou, Y. Zhang, S. Xu, G. Tian, B. Wang, Inorg. Chim. Acta 1997, 262, 109-112.
9. S. A. R. Knox, K. Macpherson, A. G. Orpen, M. C. Rendle, J. Chem. Soc., Dalton Trans. 1989, 1807-1813.
10. G. O. Nelson, Organometallics 1983, 2, 1474-1475.
11. A. P. Humphries, S. A. R. Knox, J. Chem. Soc., Dalton Trans. 1975, 1710-1714.
12. 2. N. M. Doherty, S. A. R. Knox, M. J. Morris, C. P. Casey, G. T. Whiteker, Inorg. Synth. 1990, 28, 189-191.
13. C. Nataro, L. M. Thomas, R. J. Angelici, Inorg. Chem. 1997, 36, 6000-6008.
14. J. G. Bullitt, F. A. Cotton, T. J. Marks, Inorg. Chem. 1972, 11, 671-676.
15. F. A. Cotton, G. Yagupsky, Inorg. Chem. 1967, 6, 15-20.
16. L. J. Farrugia and L. Mustoo, Organometallics 1992, 11, 2941-2944.
17. E. D. Jemmis, A. R. Pinhas, R. Hoffmann, J. Am. Chem. Soc. 1980, 102, 2576-2585.
18. A. E. Shilov, G. B. Shul'pin, Chem. Rev. 1997, 97, 2879-2932.
19. C. L. Hill, Activation and Functionalization of Alkanes, John Wiley & Sons, Inc., New York, Chichester, Brisbane, Toronto, Singapore, 1989.
20. A. D. Becke, Phys. Rev. A 1988, 38, 3098-3100.
21. J. P. Perdew, Phys. Rev. B 1986, 33, 8822-8824.
22. D. Andrae, U. Häußermann, M. Dolg, H. Stoll, H. Preuß, Theor. Chim. Acta 1990, 77, 123-141.
23. V. Jonas, W. Thiel, J. Chem. Phys. 1995, 102, 8474-8484.
24. V. Jonas, W. Thiel, J. Chew. Phys. 1996, 105, 3636-3648.
25. A. D. Becke, J. Chem. Phys. 1993, 98, 5648-5652.
26. F. Bernardi, A. Bottoni, M. Calcinari, I. Rossi, M. Robb, J. Phys. Chem. A 1997, 101, 6310-6314.
27. P. Burger, manuscript in preparation.
28. L. A. Curtiss, K. Raghavachari, G. W. Trucks, J. A. Pople, J. Chem. Phys. 1991, 94, 7221-7230.
29. C. M. Fendrick, L. D. Schertz, V. W. Day, T. J. Marks, Organometallics 1988, 7, 1828-1838.
30. R. Ahlrichs, M. Bär, M. Häser, H. Horn, C. Kölmel, Chem. Phys. Letters 1989, 162, 165-169.
31. K. Eichkorn, O. Treutler, H. Oehm, M. Häser, R. Ahlrichs, Chem. Phys. Lett. 1995 242, 652-660
32. R. Ahlrichs, M. Bär, M. Häser, H. Horn, C. Kölmel, Chem. Phys. Letters 1989, 162 165-169.
33. R. Ahlrichs, S. D. Elliott, U. Huniar, Ber. Bunsen, Phys. Chem. 1998, 102, 795-804;
34. M. von Arnim R. Ahlrichs, J. Comp. Chem. 1998, 19, 1746-1757.
35. F. Weigend, M. Häser, Theor. Chem. Acc. 1997, 97, 331-340;
36. F. Weigend, M. Häser, H. Patzelt, R. Ahlrichs, Chem. Phys. Lett. 1998, 294, 143-152.
37. H. Schäfer, H. Horn, R. Ahlrichs, J. Chem. Phys. 1992, 97, 2571-2577.
38. G. M. SHELDRICK, SHELXTL PLUS, University of Göttingen, Germany, 1988.
39. G. M. Sheldrick, SHELXL 93, University of Göttingen, Germany, 1993.