The first pincer-aryl [M-(NCN)] complexes {M = Pd(II); Pt(II)} with chiral pyridine donors: Synthesis and catalytic activity in C-C bond formation

Inorganica Chimica Acta

Volumn 359, Issue 6, 2006, Pages 1879-1888

  Soro, Barbara ^a   Stoccoro, Sergio ^a   Minghetti, Giovanni ^a   Zucca, Antonio ^a   Cinellu, Maria Agostina ^a   Manassero, Mario ^b   Gladiali, Serafino ^a  

^a UNIVERSITY OF SASSARI   (Italy)

^b UNIVERSITY OF MILAN   (Italy)

Author keywords

Chiral pyridine ligands; Crystal structures; Palladium complexes; Pincer complexes; Platinum complexes

Indexed keywords

ACETIC ACID; ACTIVATION ANALYSIS; BENZENE; CATALYST ACTIVITY; CHEMICAL BONDS; CONDENSATION REACTIONS; CRYSTAL STRUCTURE; ENANTIOSELECTIVITY; KETONES; LIGANDS; MERCURY COMPOUNDS; PH; PLATINUM COMPOUNDS; PYRIDINE; STEREOCHEMISTRY; SYNTHESIS (CHEMICAL);

ALDOL CONDENSATION; C-C BOND FORMATION; CHIRAL PYRIDINES; ORGANOMERCURY COMPOUNDS; PALLADIUM COMPLEXES; PINCER COMPLEXES; PLATINUM COMPLEXES; TRANSMETALATION REACTION;

PALLADIUM COMPOUNDS;

EID: 33644915811     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ica.2005.07.045     Document Type: Article

References (26)

1. For recent reviews see: P. Steenwinkel, R.A. Gossage, and G. van Koten Chem. Eur. J. 4 1998 759
2. M.A. Albrecht, and G. van Koten Angew. Chem., Int. Ed. 40 2001 3750
3. J.T. Singleton Tetrahedron 59 2003 1837
4. M.E. van der Boom, and D. Milstein Chem. Rev. 103 2003 1759
5. J.S. Fossey, and C.J. Richards Organometallics 21 2002 5259
6. M. Beley, J.-P. Collin, and J.-P. Sauvage Inorg. Chem. 32 1993 4539
7. D.J. Cardenas, A.M. Echavarren, and C.M. RamIÍrez de Arellano Organometallics 18 1999 3337
8. A.J. Canty, N.J. Minchin, B.W. Skelton, and A.H. White J. Chem. Soc., Dalton Trans. 1987 1477
9. Other [6,6]-cyclopalladated derivatives with N-C-N ligand obtained by direct C-H activation have been reported: D. Song, Q. Wu, A. Hook, I. Korin, and S. Wang Organometallics 20 2001 4683
10. C.M. Hartshorn, and P.J. Steel Organometallics 17 1998 3487
11. E. Diez-Barra, J. Guerra, I. Lopez-Solera, S. Merino, J. Rodriguez-Lopez, P. Sanchez-Verdu, and J. Tejeda Organometallics 22 2003 541
12. E. Diez-Barra, J. Guerra, V. Hornillos, S. Merino, and J. Tejeda Organometallics 22 2003 4610
13. B. Soro, S. Stoccoro, G. Minghetti, A. Zucca, M.A. Cinellu, S. Gladiali, M. Manassero, and M. Sansoni Organometallics 24 2005 53
14. F. Kröhnke Angew. Chem., Int. Ed. Engl. 2 1963 380
15. F. Kröhnke Synthesis 1976 1
16. I. Sasaki, J.-C. Daran, and G.G.A. Balavoine Synthesis 1999 137
17. A. Von Zelewsky, and O. Mamula J. Chem. Soc., Dalton Trans. 2000 219
18. E.D. Michelich, and D.J. Eickhoff J. Org. Chem. 48 1983 4135
19. P.K. Byers, and A.J. Canty Organometallics 9 1990 210
20. 4J(Hg-H) = 69 Hz, see P. Peringer, and P.-P. Winkler J. Organomet. Chem. 195 1980 249
21. G. Guillena, G. Rodriguez, and G. van Koten Tetrahedron Lett. 43 2002 3895
22. saint Reference Manual, Siemens Energy and Automation: Madison, WI, 1994-1996.
23. G.M. Sheldrick sadabs: Empirical Absorption Correction Program 1997 University of Göttingen Göttingen, Germany
24. B.A. Frenz Comput. Phys. 2 1988 42
25. B.A. Frenz Crystallographic Computing vol. 5 1991 Oxford University Press Oxford p. 126 (Chapter 11)
26. G.M. Sheldrick shelxs 86: Program for the Solution of Crystal Structures 1985 University of Göttingen Göttingen, Germany