Polar self-assembly: Steric effects leading to polar mixed-ligand coordination cages

Chemistry - A European Journal

Volumn 12, Issue 9, 2006, Pages 2448-2453

  Zhang, Jianyong ^a   Miller, Philip W ^a   Nieuwenhuyzen, Mark ^a   James, Stuart L ^a  

^a QUEEN'S UNIVERSITY BELFAST   (United Kingdom)

Author keywords

Anions; Cages; Phosphane; Self assembly

Indexed keywords

COMPLEXATION; CRYSTAL STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SILVER COMPOUNDS; SYNTHESIS (CHEMICAL);

PHOSPHANE; POLAR MIXED-LIGAND COORDINATION CAGES; TRIGONAL-PYRAMIDAL GEOMETRY;

SELF ASSEMBLY;

EID: 33644913655     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200501007     Document Type: Article

References (36)

1. G. F. Swiegers, T. J. Malefetse, Coord. Chem. Rev. 2002, 225, 91-121;
2. D. L. Caulder, K. N. Raymond, Acc. Chem. Res. 1999, 32, 975-982;
3. P. J. Stang, Chem. Eur. J. 1998, 4, 19-27;
4. M. Fujita, Chem. Soc. Rev. 1998, 27, 417-425;
5. C. J. Jones, Chem. Soc. Rev. 1998, 27, 289-299;
6. R. W. Saalfrank, B. Demleitner, "Transition Metals in Supra molecular Chemistry" in Perspectives in Supramolecular Chemistry vol. 5, (Ed.: J. P. Sauvage), Wiley-VCH, Weinheim, 1999, pp. 1-51;
7. S. Leininger, B. Olenyuk, P. J. Stang, Chem. Rev. 2000, 100, 853-908;
8. B. Moulton, J. Lu, A. Mondai, M. J. Zaworotko, Chem. Commun. 2001, 863.
9. J. Zhang, M. Nieuwenhuyzen, J. P. H. Charmant, S. L. James, Chem. Commun. 2004, 2808.
10. For example see; C. Addicott, N. Das, P. J. Stang, Inorg. Chem. 2004, 43, 5335;
11. R. Stiller, J.-M. Lehn, Eur. J. Inorg. Chem. 1998, 977;
12. A. Wu, L. Isaacs, J. Am. Chem. Soc. 2003, 125, 4831.
13. a) K. Kumazawa, K. Biradha, T. Kusukawa, T. Okano, M. Fujita, Angew. Chem. 2003, 115, 4039-4043;
14. Angew. Chem. Int. Ed. 2003, 42, 3909-3913;
15. b) Z. Grote, R. Scopelliti, K. Severin, Angew. Chem. 2003, 115, 3951-3955;
16. Angew. Chem. Int. Ed. 2003, 42, 3821-3825;
17. c) P. Baxter, J.-M. Lehn, A. DeCian, J. Fischer, Angew. Chem. 1993, 105, 92-95;
18. Angew. Chem. Int. Ed. Engl. 1993, 32, 69;
19. d) K. Kobayashi, Y. Yamada, M. Yamanaka, Y. Sei, K. Yamaguchi, J. Am. Chem. Soc. 2004, 126, 13896;
20. e) see for example: M. Schmittel, A. Ganz, Chem. Commun. 1997, 99;
21. M. Schmittel, V. Kalsani, D. Fenske, A. Wiegrefe, Chem. Commun. 2004, 490;
22. M. Schmittel, V. Kalsani, R. S. K. Kishore, H. Colfen, J. W. Bats, J. Am. Chem. Soc. 2005, 127, 11544-11545.
23. X. Xu, M. Nieuwenhuyzen, S. L. James, Angew. Chem. 2002, 114, 790-793;
24. Angew. Chem. Int. Ed. 2002, 41, 764-767;
25. E. Lozano, M. Niewenhuyzen and S. L. James, Chem. Eur. J. 2001, 7, 2644;
26. X. Xu, M. Niewenhuyzen, M. Chambers, E. MacLean, S. J. Teat, S. L. James, Chem. Commun. 2002, 78;
27. P. W. Miller, M. Nieuwenhuyzen, S. L. James, Chem. Commun. 2002, 2008.
28. P. W. Miller, M. Nieuwenhuyzen, J. P. H. Charrmant, S. L. James, CrystEngComm 2004, 408.
29. For examples of anions templating adamantoid silver-triphosphine cages see: S. L. James, D. M. P. Mingos, A. J. P. White, D. J. Williams, Chem. Commun. 1998, 2323;
30. X. Xu, M. Niewenhuyzen, M. Chambers, E. MacLean, S. J. Teat, S. L. James, Chem. Commun. 2002, 78.
31. D. M. P. Mingos, Inorg. Chem. 1982, 21, 464-466.
32. A. Bondi, J. Phys. Chem. 1964, 68, 441.
33. To take account of van der Waals radii, two further angles were added to the atom⋯Sb⋯atom angles. The tan of each additional angle is (v/d) for each of the ligand atoms (where v = van der Waals radius of atom, and d = distance from cage centroid (Sb1) to that atom. A diagram is given in the Supporting Information.
34. J. Podlaha, I. Cisarova, D. Alexander, P. Holy, T. Kraus, J. Zavada, Collect. Czech. Chem. Commun. 2000, 65, 1587.
35. G. M. Sheldrick, SHELXTL, An Integrated System for Data Collection, Processing, Structure Solution and Refinement, Bruker Analytical X-Ray Systems Inc., Madison, WI, 1998.
36. SMART Software Reference Manual, version 5.054, Bruker Analytical X-Ray Systems Inc., Madison, WI, 1998.