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Volumn 110, Issue 5, 2006, Pages 2159-2163

Linear nanostructure formation of aldehydes by self-directed growth on hydrogen-terminated silicon(100)

Author keywords

[No Author keywords available]

Indexed keywords

HYDROGEN; NANOSTRUCTURED MATERIALS; QUANTUM THEORY; SCANNING TUNNELING MICROSCOPY; SILICON;

EID: 33644776035     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp055153t     Document Type: Article
Times cited : (53)

References (27)
  • 2
    • 84906387545 scopus 로고    scopus 로고
    • note
    • The naming convention we have used in the past to describe the composition of the nanostructures was based on polymer nomenclature, despite the fact that the nanostructures are not polymeric in nature. In this work, we have described linear nanostructures derived from benzaldehyde as "benzaldehyde lines"; however, the line growth process results in the reduction of the aldehyde moiety, giving lines of phenylcarbinolyl covalently bonded to the silicon surface.
  • 15
    • 84906358808 scopus 로고    scopus 로고
    • note
    • 2. The hydrogen atoms used to cap the silicon atoms in the model system were given Si-H bond lengths of 1.50 Å or C-H bond lengths of 1.11 Å.
  • 23
    • 33845554944 scopus 로고
    • The addition of triethylsilyl radical to benzaldehyde in solution has an activation energy of 0.14 eV. See Chatgilialoglu, G.; Ingold, K. U.; Scaiano, J. C. J. Am. Chem. Soc. 1982, 104, 5119-5123.
    • (1982) J. Am. Chem. Soc. , vol.104 , pp. 5119-5123
    • Chatgilialoglu, G.1    Ingold, K.U.2    Scaiano, J.C.3
  • 25
    • 84906358809 scopus 로고    scopus 로고
    • note
    • 15 Thus, the computational approaches used likely cannot resolve energy differences < 0.1 eV.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.