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Volumn 128, Issue 8, 2006, Pages 2524-2525

Ligand-induced control of C-H versus aliphatic C-C migration reactions of Rh carbenoids

Author keywords

[No Author keywords available]

Indexed keywords

CARBENOID; LIGAND; RHODIUM;

EID: 33644651861     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja057739z     Document Type: Article
Times cited : (44)

References (27)
  • 5
    • 52849093599 scopus 로고    scopus 로고
    • Karlin, K. D., Ed.; John Wiley & Sons: New York
    • (e) Doyle, M. P.; Ren, T. In Progress in Inorganic Chemistry; Karlin, K. D., Ed.; John Wiley & Sons: New York, 2001: Vol. 49, p 113.
    • (2001) Progress in Inorganic Chemistry , vol.49 , pp. 113
    • Doyle, M.P.1    Ren, T.2
  • 11
    • 0002282779 scopus 로고
    • Small amounts of α-C-C migration (3-17%) have been reported with metal-free isopropylcarbene: (e) Mansoor, A. M.; Stevens, I. D. R. Tetrahedron Lett. 1966, 7, 1733.
    • (1966) Tetrahedron Lett. , vol.7 , pp. 1733
    • Mansoor, A.M.1    Stevens, I.D.R.2
  • 12
    • 0001469676 scopus 로고
    • The 1,2-C-C migrations of metal carbenes have been observed when no other competing processes are possible: (a) Padwa, A.; Hornbuckle, S. F.; Zhang, Z.; Zhi, L. J. Org. Chem. 1990, 55, 5297.
    • (1990) J. Org. Chem. , vol.55 , pp. 5297
    • Padwa, A.1    Hornbuckle, S.F.2    Zhang, Z.3    Zhi, L.4
  • 15
    • 0002676988 scopus 로고
    • (b) Reactions with commercial TMSD were very much lower yielding than TMSD made by us using the procedure described by Shioiri: Shioiri, T.; Aoyama, T.; Mori, S. Org. Synth. 1990, 68, 1.
    • (1990) Org. Synth. , vol.68 , pp. 1
    • Shioiri, T.1    Aoyama, T.2    Mori, S.3
  • 20
    • 33644641879 scopus 로고    scopus 로고
    • note
    • 4-catalyzed decomposition of 4b at room temperature in either THF or toluene only gave recovery of starting material.
  • 21
    • 33644641746 scopus 로고    scopus 로고
    • note
    • Pivaldehyde was also examined, but the intermediate diazocompound related to 4 was too stable and did not decompose under either protocol A or B.
  • 22
    • 22244490671 scopus 로고    scopus 로고
    • The formation of cyclopropanes via 1,3-C-H insertion when competitive 1,2-C-H migration is also possible has recently been reported: Shi, W.; Zhang, B.; Zhang, J.; Liu, B.; Zhang, S.; Wang, J. Org. Lett. 2005, 7, 3103-3106.
    • (2005) Org. Lett. , vol.7 , pp. 3103-3106
    • Shi, W.1    Zhang, B.2    Zhang, J.3    Liu, B.4    Zhang, S.5    Wang, J.6


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.