Stereochemistry of isoplagiochin C, A macrocyclic bisbibenzyl from liverworts

Journal of the American Chemical Society

Volumn 126, Issue 30, 2004, Pages 9283-9290

  Bringmann, Gerhard ^a   Mühlbacher, Jörg ^a,c   Reichert, Matthias ^a   Dreyer, Michael ^a   Kolz, Jürgen ^b   Speicher, Andreas ^b  

^a UNIVERSITY OF WÜRZBURG   (Germany)

^b SAARLAND UNIVERSITY   (Germany)

^c NOVARTIS PHARMA AG   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

CHROMATOGRAPHIC ANALYSIS; COMPUTER SIMULATION; CONFORMATIONS; MOLECULAR DYNAMICS; ORGANIC ACIDS; STEREOCHEMISTRY;

DIASTEREOMERS; STEREOGENIC ELEMENTS;

BIOLOGICAL MATERIALS;

ISOPLAGIOCHIN C; MACROCYCLIC COMPOUND; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; CONFORMATION; ENANTIOMER; LIVERWORT; MOLECULAR DYNAMICS; QUANTUM CHEMISTRY; RACEMIC MIXTURE; ROOM TEMPERATURE; STEREOCHEMISTRY; STEREOISOMERISM; STRUCTURE ANALYSIS;

BIBENZYLS; BIPHENYL COMPOUNDS; CIRCULAR DICHROISM; COMPUTER SIMULATION; HEPATOPHYTA; MODELS, MOLECULAR; MOLECULAR CONFORMATION; NUCLEAR MAGNETIC RESONANCE, BIOMOLECULAR; QUANTUM THEORY; STEREOISOMERISM; THERMODYNAMICS;

EID: 3342981123     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0373162     Document Type: Article

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42. The formal value of the standard deviation for the linear regression was determined as ±1.0 kJ/mol; this, however, does not yet take into account systematic errors, so that an overall deviation of ∼±10 kJ/mol was estimated.