Is phenol condensation one of the major pathways in the formation of polychlorinated dibenzofurans in municipal waste incinerators?: Model prediction vs. field observation

Science of the Total Environment

Volumn 357, Issue 1-3, 2006, Pages 237-246

  Ryu, Jae Yong ^a   Takeuchi, Masao ^a   Mulholland, James A ^b  

^a NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY AIST   (Japan)

^b Georgia Institute of Technology   (United States)

Author keywords

Municipal waste incinerator; Phenol condensation pathways; Phenols; Polychlorinated dibenzofurans (PCDF); Two phenol condensation model

Indexed keywords

CONDENSATION; ISOMERS; REFUSE INCINERATORS;

CONGENERS; PHENOL CONDENSATION PATHWAYS; POLYCHLORINATED DIBENZOFURANS (PCDF);

PHENOLS;

PHENOL; POLYCHLORINATED DIBENZOFURAN;

INCINERATION; MUNICIPAL SOLID WASTE; PHENOL;

ARTICLE; CHEMICAL STRUCTURE; ISOMER; MATHEMATICAL ANALYSIS; MUNICIPAL SOLID WASTE; PRIORITY JOURNAL; WASTE MANAGEMENT;

AIR POLLUTANTS; BENZOFURANS; INCINERATION; ISOMERISM; MODELS, CHEMICAL; PHENOL;

EID: 33244458213     PISSN: 00489697     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.scitotenv.2005.04.026     Document Type: Article

References (37)

1. E.R. Altwicker Relative rates of formation of polychlorinated dioxins and furans from precursors and de novo reactions Chemosphere 33 1996 1897 1904
2. E.R. Altwicker, and M.S. Milligan Formation of dioxins: competing rates between chemically similar precursors and de novo reactions Chemosphere 27 1993 301 307
3. K. Ballschmitter, W. Zoller, H. Buchert, and Th. Class Correlation between substitution pattern and reaction pathway in the formation of polychlorodibenzofurans Fres Z Anal Chem 322 1985 587 594
4. J.G.P. Born, R. Louw, and P. Mulder Formation of dibenzodioxins and dibenzofurans in homogeneous gas-phase reactions of phenols Chemosphere 9 1989 401 406
5. J.G.P. Born, P. Mulder, and R. Louw Fly ash mediated reactions of phenol and monochlorophenols: oxychlorination, deep oxidation, and condensation Environ Sci Technol 27 1993 1849 1863
6. L.C. Dickson, D. Lenoir, and O. Hutzinger Surface-catalyzed formation of chlorinated dibenzodioxins and dibenzofurans during ncineration Chemosphere 19 1989 277 282
7. A. Fullana, H. Nakka, and S. Sidhu PCDF formation from PAH reactions Organohalogen Compd 66 2004 1126 1131
8. T. Hatanaka, A. Kitajima, and M. Takeuchi Role of copper chloride in the formation of polychlorinated dibenzo-p-dioxins and dibenzofurans during incineration Chemosphere 57 2004 73 79
9. K. Hell, L. Stieglitz, G. Zwick, and R. Will Mechanistic aspects of the de-novo-synthesis of PCDD/PCDF on model fly ash Organohalogen Compd 31 1997 492 496
10. 2, condensation to PCDD/F and conversion into related compounds Chemosphere 42 2001 697 702
11. 13C-labeled carbon Environ Sci Technol 35 2001 3892 3898
12. H. Huang, and A. Buekens On the mechanisms of dioxin formation in combustion processes Chemosphere 31 1995 4099 4117
13. Iino F. Formation mechanisms of dioxins from municipal waste incinerators. Ph.D. dissertation. University of Tokyo, Japan; 1999.
14. F. Iino, T. Imagawa, and B. Gullett Dechlorination-controlled polychlorinated dibenzo-furan isomer patterns from municipal waste incinerators Environ Sci Technol 34 2000 3143 3147
15. F. Iino, K. Tsuchiya, T. Imagawa, and B. Gullett An isomer prediction model based on dechlorination kinetics for polychlorinated naphthalenes, polychlorinated dibenzo-p-dioxins, and polychlorinated biphenyls from municipal waste incinerators Environ Sci Technol 35 2001 3175 3181
16. S. Lomnicki, and B. Dellinger A detailed mechanism of the surface-mediated formation of PCDD/F from oxidation of 2-chlorophenol on a CuO/Silica surface J Phys Chem, A 107 2003 4387 4395
17. R. Luijk, D. Akkerman, P. Slot, K. Olie, and F. Kepteijn Mechanism of formation of polychlorinated dibenzo-p-dioxins and dibenzofurans in the catalyzed combustion of carbon Environ Sci Technol 28 1994 312 321
18. 2-catalyzed condensation of 2,6 chlorinated phenols Combust Sci Technol 169 2001 107 126
19. Ryu JY. Dioxin formation on copper (II) chloride from chlorinated phenol, dibenzo-p-dioxin, and dibenzofuran precursors. Ph.D. dissertation. Georgia Institute of Technology, Atlanta, Georgia, USA; 2002.
20. J.Y. Ryu, J.A. Mulholland, and B. Chu Chlorination of dibenzofuran and dibenzo-p-dioxin vapor by copper (II) chloride Chemosphere 51 2003 1031 1039
21. J.Y. Ryu, J.A. Mulholland, J.E. Oh, D.T. Nakahata, and D.H. Kim Prediction of polychlorinated dibenzofuran congener distribution from gas-phase phenol condensation pathways Chemosphere 55 2004 1447 1455
22. J.Y. Ryu, J.A. Mulholland, J.E. Dunn, F. Iino, and B.K. Gullett Potential role of chlorination pathways in PCDD/F formation in a municipal waste incinerator Environ Sci Technol 38 2004 5112 5119
23. J.Y. Ryu, J.A. Mulholland, D.H. Kim, and M. Takeuchi Homologue and isomer patterns of polychlorinated dibenzo-p-dioxin (PCDD) and dibenzofuran (PCDF) from phenol precursors: comparison with municipal waste incinerator data Environ Sci Technol 2004 in press
24. K.W. Schramm, A. Wehrmeier, D. Lenoir, B. Henkelmann, K. Hahn, and R. Zimmermann Deduction of a typical pattern for the isomers of tetra- to heptachloro-dibenzo-p-dioxins-and-furans formed in combustion processes Organohalogen Compd 27 1996 196 200
25. L. Stieglitz, and H. Vogg On formation conditions of PCDD/PCDF in fly ash from municipal waste incinerators Chemosphere 16 1987 1917 1922
26. L. Stieglitz, G. Zwick, J. Beck, H. Bautz, and W. Roth Carbonaceous particles in fly ash - A source for the de-novo-synthesis of organochlorocompounds Chemosphere 19 1989 283 290
27. K. Tuppurainen, I. Halonen, P. Rukojarvi, J. Tarhanen, and J. Ruuskanen Formation of PCDDs and PCDFs in municipal waste incineration and its inhibition mechanisms: a review Chemosphere 36 1998 1493 1511
28. K. Tuppurainen, A. Marjaleena, P. Ruokojarvi, I. Halonen, and J. Ruuskanen Effect of liquid inhibitors on PCDD/F formation: prediction of particle-phase PCDD/F concentrations using PLS modeling with gas-phase chlorophenol concentrations as independent variables Chemosphere 38 1999 2205 2217
29. K. Tuppurainen, P. Ruokojarvi, A. Asikainen, A. Marjaleena, and J. Ruuskanen Chlorophenols as precursors of PCDD/Fs in incineration processes: correlations, PLS modeling, and reaction mechanisms Environ Sci Technol 34 2000 4958 4962
30. K. Tuppurainen, A. Asikainen, P. Ruokojarvi, and J. Ruuskanen Perspectives on the formation of polychlorinated dibenzo-p-dioxins and dibenzofurans during municipal solid waste (MSW) incineration and other combustion processes Acc Chem Res 36 2003 652 658
31. R. Weber, and H. Hagenmaier PCDD/PCDF formation in fluidized bed incineration Chemosphere 38 1999 2643 2654
32. R. Weber, F. Iino, T. Imagawa, M. Takeuchi, T. Sakurai, and M. Sadakata Formation of PCDF, PCDD, PCB, and PCN in de novo synthesis from PAH: mechanistic aspects and correlation to fluidized bed incinerators Chemosphere 44 2001 1429 1438
33. A. Wehrmeier, D. Lenoir, K.W. Schramm, R. Zimmermann, K. Hahn, and B. Henkelmann Patterns of isomers of chlorinated dibenzo-p-dioxins as tool for elucidation of thermal formation mechanism Chemosphere 36 1998 2775 2801
34. E. Wikstrom, and S. Marklund Secondary formation of chlorinated dibenzo-p-dioxins, dibenzofurans, biphenyls, benzenes and phenols during MSW combustion Environ Sci Technol 34 2000 604 609
35. E. Wikstrom, S. Ryan, A. Touati, and B.K. Gullett In situ formed soot deposit as a carbon source for polychlorinated dibenzo-p-dioxins and dibenzofurans Environ Sci Technol 38 2004 2097 2101
36. J. Wilhelm, L. Stieglitz, E. Dinjus, and R. Will Mechanistic studies on the role of PAHs and related compounds in PCDD/F formation on model fly ashes Chemosphere 42 2001 797 802
37. R. Zimmermann, M. Blumenstock, H.J. Heger, K.W. Schramm, and A. Kettrup Emission of nonchlorinated and chlorinated aromatics in the flue gas of incineration plants during and after transient disturbances of combustion conditions: delayed emission effects Environ Sci Technol 35 2001 1019 1030