The first synthesis and x-ray structure of [1.1]silaferrocenophane containing pentacoordinate silicon moieties

Chemistry Letters

Volumn 33, Issue 5, 2004, Pages 520-521

  Bao, Ming ^a   Hatanaka, Yasuo ^b   Shimada, Shigeru ^a  

^a NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY AIST   (Japan)

^b Osaka Prefecture University   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

COORDINATION COMPOUND; SILANE DERIVATIVE; SILICONE DERIVATIVE;

ARTICLE; CRYSTAL STRUCTURE; DIMERIZATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; STRUCTURE ANALYSIS; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 3242798148     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2004.520     Document Type: Article

References (19)

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15. 2FeSi: C, 44.48; H, 3.39. Found: C, 44.56; H, 3.44%.
16. 16ClFeNOSi: C, 50.39; H, 4.83; N, 4.20. Found: C, 50.15; H, 5.19; N, 4.17%.
17. 2: C, 50.39; H, 4.83; N, 4.20. Found: C, 49.94; H, 5.26; N, 3.84%.
18. 29Si NMR chemical shifts for pentacoordinate Si usually exhibit an upfield chemical shift relative to the shifts for tetracoordinate Si. See Ref. 7a.
19. 2 = 0.163 (all data). Atomic coordinates, additional bond lengths and angles, and other important parameters have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication, CCDC No. 232427. Copies of this information can be obtained, free of charge, on application to CCDC, 12 Union Road, Cambridge, CB2 1EZ, UK (fax: +44(1233)336033 or e-mail: deposit@ccdc.cam.ac.uk).