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A structure of AGME complexed with ADP-α-D-glucose is available (ref 9); however, the electron density of the hexose moiety was disordered and difficult to interpret. This is likely the result of having the incorrect stereochemistry at both C-1″ and C-2″ of the substrate analogue, and it complicates any mechanistic interpretations regarding the position of transient oxidation.
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See Supporting Information for details.
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