Tri-tert-butylphosphine is an efficient promoter for the trifluoromethylation reactions of aldehydes, ketones, imides and imines

Synlett

Volumn , Issue 2, 2006, Pages 267-270

  Mizuta, Satoshi ^a   Shibata, Norio ^a   Sato, Takayuki ^a   Fujimoto, Hiroyuki ^a   Nakamura, Shuichi ^a   Toru, Takeshi ^a  

^a NAGOYA INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

Aldehydes; Fluorine; Imines; Lewis bases; Trifluoromethylation

Indexed keywords

ALDEHYDE DERIVATIVE; CARBONYL DERIVATIVE; FLUORINE DERIVATIVE; IMIDE; IMINE; KETONE DERIVATIVE; PHOSPHINE DERIVATIVE; REAGENT; SILICON DERIVATIVE;

ARTICLE; BIOTRANSFORMATION; CATALYSIS; CATALYST; CHEMICAL REACTION; QUANTUM YIELD; REACTION ANALYSIS; STEREOSPECIFICITY; TRIFLUOROMETHYLATION;

EID: 32344446963     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2006-926223     Document Type: Article

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48. 3 (57 μL, 0.38 mmol) was added at r.t. The mixture was stirred at r.t. for 0.5 h; the reaction was concentrated under reduced pressure. The residue was chromatographed on silica gel using hexane to afford 2b in 99% yield.