Eastern Atlantic Spring Experiment 1997 (EASE97) 2. Comparisons of model concentrations of OH, HO2, and RO2 with measurements

Journal of Geophysical Research Atmospheres

Volumn 107, Issue 14, 2002, Pages ACH-5-1-ACH-5-16

  Carslaw, N ^a,d   Creasey, D J ^a   Heard, D E ^a   Jacobs, P J ^a   Lee, J D ^a   Lewis, A C ^a   McQuaid, J B ^a   Pilling, M J ^a   Bauguitte, S ^b   Penkett, S A ^b   Monks, P S ^c   Salisbury, G ^c  

^a UNIVERSITY OF LEEDS   (United Kingdom)

^b UNIVERSITY OF EAST ANGLIA   (United Kingdom)

^c UNIVERSITY OF LEICESTER   (United Kingdom)

^d UNIVERSITY OF YORK   (United Kingdom)

Author keywords

Mace Head Atmospheric Research Station; OH radical; Peroxy radicals; Tropospheric chemistry

Indexed keywords

AIR POLLUTION; MARINE BIOLOGY; MATHEMATICAL MODELS; METEOROLOGY; OZONE; PHOTOLYSIS; TROPOSPHERE;

ATMOSPHERIC CHEMISTRY; HYDROXYL RADICAL; PEROXY RADICAL; TROPOSPHERE;

CONNACHT; COUNTY GALWAY; EURASIA; EUROPE; IRELAND; MACE HEAD; WESTERN EUROPE;

EID: 32044474435     PISSN: 01480227     EISSN: None     Source Type: Journal    
DOI: 10.1029/2001JD001568     Document Type: Article

References (53)

1. 2 and a series of organic peroxy radicals, J. Atmos. Chem., 29, 233-266, 1998.
2. Bauguitte, S., Measurements of nitrogen oxides, in Testing Atmospheric Chemistry in Anticyclones-(TACIA): Final Report to the EU, edited by Ø. Hov et al., Rep. ENV4-CT95-0038, pp. 21-26, Geophys. Inst., Univ. of Bergen, Bergen, Norway, 1998.
3. Bauguitte, S., A study of tropospheric reactive nitrogen oxides in the North Atlantic region, Ph.D. dissertation, Univ. of East Anglia, Norwich, England, 2000.
4. Burkert, J., M. D. Andres-Hernandez, D. Stobener, J. P. Burrows, M. Weissenmayer, and A. Kraus, Peroxy radical and related trace gas measurements in the boundary above the Atlantic Ocean, J. Geophys. Res., 106, 5457-5477, 2001.
5. Calvert, J. G., G. Yarwood, and A. M. Dunker, An evaluation of the mechanism of nitrous acid formation in the urban atmosphere, Res. Chem. Intermed., 20, 463-502, 1994.
6. Cantrell, C. A., D. H. Stedman, and G. J. Wendel, Measurement of atmospheric peroxy radicals by chemical amplification, Anal. Chem., 56, 1496-1502, 1984.
7. Cantrell, C. A., R. E. Shetter, T. M. Gilpin, and J. G. Calvert, Peroxy radicals measured during Mauna Loa observatory photochemistry experiment 2: The data and first analysis, J. Geophys. Res., 101, 14,643-14,652, 1996.
8. Cantrell, C. A., R. E. Shetter, J. G. Calvert, F. L. Eisele, E. Williams, K. Baumann, W. H. Brune, P. S. Stevens, and J. H. Mather, Peroxy radicals from photostationary state deviations and steady state calculations during the Tropospheric OH Photochemistry Experiment at Idaho Hill, Colorado, 1993, J. Geophys. Res., 102, 6369-6378, 1997.
9. Cardenas, L. M., D. J. Brassington, B. J. Allan, H. Coe, B. Alicke, U. Platt, K. M. Wilson, J. M. C. Plane, and S. A. Penkett, Intercomparison of formaldehyde measurements in clean and polluted atmospheres, J. Atmos. Chem., 37, 53-80, 2000.
10. Carpenter, L. J., P. S. Monks, I. E. Galbally, C. P. Meyer, B. J. Bandy, and S. A. Penkett, A study of peroxy radicals and ozone production/destruction rates at coastal sites in the northern and southern hemispheres, J. Geophys. Res., 102, 25,417-25,427, 1997.
11. Carpenter, L. J., W. T. Sturges, S. A. Penkett, P. S. Liss, B. Alicke, K. Hebestreit, and U. Platt, Short-lived alkyl iodides and bromides at Mace Head, Ireland: Links to biogenic sources and halogen oxide production, J. Geophys. Res., 104, 1679-1689, 1999.
12. 2 radicals in the marine boundary layer, 1, Model construction and comparison with field measurements, J. Geophys. Res., 104, 30,241-30,255, 1999a.
13. 2 radicals in the marine boundary layer, 2, Mechanism reduction and uncertainty analysis, J. Geophys. Res., 104, 30,257-30,273, 1999b.
14. 2 radicals in a forested region of north-western Greece, Atmos. Environ., 35, 4725-4737, 2001.
15. 2 in the troposphere by laser-induced fluorescence, J. Chem. Soc. Faraday Trans., 93, 2907-2913, 1997.
16. 2 measurements in a forested region of north-western Greece, Atmos. Environ., 35, 4713-4724, 2001.
17. 2 concentrations at Mace Head, Ireland, J. Geophys. Res., 107(D10), 10.1029/2001JD000892, 2002.
18. Curtis, A. R., and W. P. Sweetenham, FACSIMILE/CHEKMAT users manual, Rep. AERER12805, Her Majesty's Stn. Off., Norwich, England, 1987.
19. Cvitas, T., and D. Kley, The TOR network: A description of TOR measurement stations, EUROTRAC Spec. Publ., Int. Sci. Secr., Garmisch-Partenkirchen, Germany, 1994.
20. Eisele, F. L., G. H. Mount, F. C. Fehsenfeld, J. Harder, E. Marovich, D. D. Parrish, J. Roberts, and M. Trainer, Intercomparison of tropospheric OH and ancillary trace gas measurements at Fritz Peak Observatory, Colorado, J. Geophys. Res., 99, 18,605-18,626, 1994.
21. Eisele, F. L., D. J. Tanner, C. A. Cantrell, and J. G. Calvert, Measurements and steady state calculations of OH concentrations at Mauna Loa Observatory, J. Geophys. Res., 101, 14,665-14,679, 1996.
22. y in the atmosphere, J. Atmos. Chem., 3, 435-468, 1985.
23. 2 in Los Angeles smog, J. Geophys. Res., 104, 11,643-11,655, 1999.
24. 2 radicals on material surfaces of atmospheric interest, in 14th International Symposium on Gas Kinetics Book of Abstracts, abstract A12, Univ. of Leeds, Leeds, England, 1996.
25. Hard, T. M., R. J. O'Brien, C. Y. Chan, and A. A. Mehrabzadeh, Tropospheric free radical determination by FACE, Environ. Sci. Technol., 18, 768-777, 1984.
26. Harrison, R. M., J. D. Peak, and G. M. Collins, Tropospheric cycle of nitrous acid, J. Geophys. Res., 101, 14,429-14,439, 1996.
27. Harrison, R. M., J. L. Grenfell, N. Savage, A. Allen, K. C. Clemitshaw, S. Penkett, C. N. Hewitt, and B. Davison, Observations of new particle production in the atmosphere of a moderately polluted site in eastern England, J. Geophys. Res., 105, 17,819-17,832, 2000.
28. Hofzumahaus, A., U. Aschmutat, M. Hessling, F. Holland, and D. H. Ehhalt, The measurement of tropospheric OH radicals by laser-induced fluorescence spectroscopy during the POPCORN campaign, Geophys. Res. Lett., 23, 2541-2544, 1996.
29. Hough, A. M., The calculation of photolysis rates for use in global tropospheric modelling studies, AERE Rep. R-13259, Her Majesty's Stn. Off., Norwich, England, 1988.
30. Jacob, D. J., Heterogeneous chemistry and tropospheric ozone, Atmos. Environ., 34, 2131-2159, 2000.
31. x in the upper troposphere at northern midlatitudes, J. Geophys. Res., 105, 3877-3892, 2000.
32. Jenkin, M. E., S. M. Saunders, and M. J. Pilling, The tropospheric degradation of volatile organic compounds: A protocol for mechanism development, Atmos. Environ., 31, 81-104, 1997.
33. 2 concentrations at Oki island, Japan, in summer 1998: Comparison between measurement and theory, J. Geophys. Res., 105, 24,205-24,222, 2000.
34. Lewis, A. C., J. B. McQuaid, N. Carslaw, and M. J. Pilling, Short communication: Diurnal cycles of short-lived tropospheric alkenes at a North Atlantic coastal site, Atmos. Environ., 33, 2417-2422, 1999.
35. Lewis, A. C., N. Carslaw, P. J. Marriott, R. M. Kinghorn, P. Morrison, A. L. Lee, K. D. Bartle, and M. J. Pilling, A larger pool of ozone-forming carbon compounds in urban atmospheres, Nature, 405, 778-781, 2000.
36. Logan, J. A., M. J. Prather, S. C. Wofsy, and M. B. McElroy, Tropospheric chemistry: A global perspective, J. Geophys. Res., 86, 7210-7254, 1981.
37. Mauldin, R. L., G. J. Frost, G. Chen, D. J. Tanner, A. S. H. Prevot, D. D. Davis, and F. L. Eisele, OH measurements during the First Aerosol Characterization Experiment (ACE 1): Observations and model comparisons, J. Geophys. Res., 103, 16,713-16,729, 1998.
38. McKeen, S. A., et al., Photochemical modeling of hydroxyl and its relationship to other species during the Tropospheric OH Photochemistry Experiment, J. Geophys. Res., 102, 6467-6493, 1997.
39. McQuaid, J. B., Studies of tropospheric chemistry in urban and remote areas, Ph.D. thesis, Univ. of Leeds, Leeds, England, 1999.
40. Mihele, C. M., and D. R. Hastie, The sensitivity of the radical amplifier to ambient water vapor, Geophys. Res. Lett., 25, 1911-1913, 1998.
41. Mihele, C. M., M. Mozurkewich, and D. R. Hastie, Radical loss in a chain reaction of CO and NO in the presence of water: Implications for the radical amplifier and atmospheric chemistry, Int. J. Chem. Kinet., 31, 145-152, 1999.
42. O'Dowd, C. D., J. A. Lowe, and M. H. Smith, Marine aerosol, sea-salt, and the marine sulphur cycle: A short review, Atmos. Environ., 31, 73-80, 1997.
43. Penkett, S. A., C. E. Reeves, B. J. Bandy, J. M. Kent, and H. R. Richer, Comparison of calculated and measured peroxide data collected in marine air to investigate prominent features of the annual cycle of ozone in the troposphere, J. Geophys. Res., 103, 13,377-13,388, 1998.
44. Plummer, D. A., J. C. McConnell, P. B. Shepson, D. R. Hastie, and H. Niki, Modeling of ozone formation at a rural site in Southern Ontario, Atmos. Environ., 30, 2195-2217, 1996.
45. Poppe, D., et al., Comparison of measured OH concentrations with model calculations, J. Geophys. Res., 99, 16,633-16,642, 1994.
46. Rogak, S. N., U. Baltensperger, and R. C. Flagan, Measurement of masstransfer to agglomerate aerosols, Aerosol Sci. Technol., 14, 447-458, 1991.
47. Salisbury, G., et al., The production of peroxy radicals at night via reactions of ozone and the nitrate radical in the marine boundary layer, J. Geophys. Res., 106, 12,669-12,687, 2001.
48. Salisbury, G., P. S. Monks, S. Bauguitte, B. J. Bandy, and S. A. Penkett, A seasonal comparison of ozone photochemistry in clean and polluted air masses at Mace Head, Ireland, J. Atmos. Chem., 41(2), 163-187, 2002.
49. 2 radicals in the troposphere, Atmos. Environ., 31, 3653-3658, 1997.
50. Simmonds, P. G., R. G. Derwent, A. McCulloch, S. O. Doherty, and A. Gaudry, Long-term trends in concentrations of halocarbons and radiatively active trace gases in Atlantic and European air masses monitored at Mace Head, Ireland, from 1987-1994, Atmos. Environ., 30, 4041-4063, 1996.
51. 2 ratios during the Tropospheric OH Photochemistry Experiment: Measurement and theory, J. Geophys. Res., 102, 6379-6391, 1997.
52. Yin, F., D. Grosjean, and J. H. Seinfeld, Photooxidation of dimethyl sulfide and dimethyl disulfide, 1, Mechanism development, J. Atmos. Chem., 11, 309-364, 1990a.
53. Yin, F., D. Grosjean, and J. H. Seinfeld, Photooxidation of dimethyl sulfide and dimethyl disulfide, 2, Mechanism evaluation, J. Atmos. Chem., 11, 365-399, 1990b.