Comparison of calculated and measured peroxide data collected in marine air to investigate prominent features of the annual cycle of ozone in the troposphere

Journal of Geophysical Research Atmospheres

Volumn 103, Issue D11, 1998, Pages 13377-13388

  Penkett, S A ^a   Reeves, C E ^a   Bandy, B J ^a   Kent, J M ^b,c   Richer, H R ^b,c  

^a UNIVERSITY OF EAST ANGLIA   (United Kingdom)

^b DEFENCE SCIENCE AND TECHNOLOGY LABORATORY   (United Kingdom)

^c DRA   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

MARINE AIR; OZONE; PEROXIDE; TROPOSPHERE;

(NORTH); ATLANTIC;

EID: 0032551068     PISSN: 01480227     EISSN: None     Source Type: Journal    
DOI: 10.1029/97JD02852     Document Type: Article

References (31)

1. Ayers, G.P., S.A. Penkett, R.W. Gillett, B. Bandy, I.E. Galbally, C.M. Meyer, M. Elsworth, S.T. Bentley, and B.W. Forgan, Photochemical production of hydrogen peroxides and destruction of ozone in marine air over the Southern Ocean, Nature, 360, 446-449, 1992.
2. Ayers, G.P., S.A. Penkett, R.W. Gillett, B.J. Bandy, I.E. Galbally, C.P. Meyer, C.M. Elsworth, S.T. Bentley, and B.W. Forgan, Annual cycle of peroxides and ozone in marine air at Cape Grim, Tasmania, J. Atmos. Chem., 23, 221-252, 1996.
3. Barrie, L.A., J.W. Bottenheim, R.C. Schnell, P.J. Crutzen, and R.A. Rasmussen, Ozone destruction and photochemical-reactions at polar sunrise in the lower Arctic atmosphere, Nature, 334, 138-141, 1988.
4. Carpenter, L.J., P.S. Monks, I.E. Galbally, C.P. Meyer, B.J. Bandy, and S.A. Penkett, A study of peroxy radicals and ozone photochemistry at coastal sites in the northern and southern hemispheres, J. Geophys. Res., 102, 25,417-25,427, 1997.
5. Crutzen, P.J., Introductory lecture: Overview of tropospheric chemistry: Developments during the past quarter century and a look ahead, Faraday Discuss., 100, 1-21, 1995.
6. Dollard, G.J., T.J. Davies, and J.P.C. Lindstrom, Measurements of the dry deposition rates of some trace gas species, in Physico-Chemical Behaviour of Atmospheric Pollutants, edited by G. Angeletti and G. Restelli, pp. 470-479, D. Reidel, Norwell, Mass., 1986.
7. Fishman, J., C.E. Watson, J.C. Larsen, and J.A. Logan, Distribution of tropospheric ozone determined from satellite data, J. Geophys. Res., 95, 3599-3617, 1990.
8. Guicherit, R., Ozone on an urban and regional scale, with special reference to the situation in the Netherlands, in Tropospheric Ozone, edited by I.S.A. Isaksen, pp. 49-62, D. Reidel, Norwell, Mass., 1988.
9. Heikes, B.C., Formaldehyde and hydroperoxides at Mauna-Loa Observatory, J. Geophys. Res., 97, 18,001-18,013, 1992.
10. 2 to wheat, Eos Trans. AGU, 67, 885, 1986.
11. Hough, A.M., The calculation of photolysis rates for use in global troposheric modelling studies, AERE Rep. R-13259, pp. 53, Her Majesty's Stationery Office, London, 1988.
12. Hough, A. M., Development of a two-dimensional global tropospheric model: Model chemistry, J. Geophys. Res., 96, 7325-7362, 1991.
13. Kleinman, L.I., Photochemical formation of peroxides in the boundary layer, J. Geophys. Res., 91, 10,889-10,904, 1986.
14. Kok, G.L., J.G. Walega, B.G. Heikes, J.A. Lind, and A.L. Lazrus, Measurements of hydrogen peroxide and formaldehyde in Glendora, California, Aerosol Sci. Technol., 12, 49-55, 1990.
15. Lazrus, A.L., G.L. Kok, J.A. Lind, S.N. Gitlin, B.G. Heikes, and R.E. Shetter, Automated fluorometric method for hydrogen peroxide in air, Anal. Chem., 58, 594-597, 1986.
16. Lelieveld, J. and P.J. Crutzen, Influences of cloud photochemical processes on tropospheric ozone, Nature, 343, 227-233, 1990.
17. Liu, S.C., M. Trainer, F.C. Fehsenfeld, D.D. Parish, E.J. Williams, D.W. Fahey, G. Hüber, and P.C. Murphy, Ozone production in the rural troposphere and the implications for regional and global ozone distributions, J. Geophys. Res., 92, 4191-4207, 1987.
18. Oltmans, S.J., and H. Levy, Surface ozone measurements from a global network, Atmos. Environ., 28, 9-24, 1994.
19. Oltmans, S.J., et al., Summer and spring ozone profiles over the North Atlantic from ozone sonde measurements, J. Geophys. Res., 101, 29,179-29,200, 1996.
20. Penkett, S.A., Indications and causes of ozone increase in the troposphere, in The Changing Atmosphere, edited by F.S. Rowland and I.S.A. Isaksen, pp. 91-103, John Wiley, New York, 1988.
21. Penkett, S.A., and K.A. Brice, The spring maximum in photo-oxidants in the northern hemisphere troposphere, Nature, 319, 655-657, 1986.
22. Penkett, S.A., B.M.R. Jones, K.A. Brice, and A.E.J. Eggleton, The importance of atmospheric ozone and hydrogen peroxide in oxidising sulphur dioxide in cloud and rainwater, Atmos. Environ., 13, 123-127, 1979.
23. Penkett, S.A., N.J. Blake, P. Lightman, A.R.W. Marsh, P. Anwyl, and G. Butcher, The seasonal variation of non-methane hydrocarbons in the free troposphere over the North Atlantic Ocean: Possible evidence for extensive reaction of hydrocarbons with the nitrate radical, J. Geophys. Res. 98, 2865-2885, 1993.
24. Penkett, S.A., B.J. Bandy, C.E. Reeves, D. McKenna, and P. Hignett, Measurements of peroxides in the atmosphere and their relevance to the understanding of global tropospheric chemistry, Faraday Discuss., 100, 155-174, 1995.
25. Penkett, S.A., P.S. Monks, L.J. Carpenter, K.C. Clemitshaw, G.P. Ayers, R.W. Gillett, I.E. Galbally, and C.P. Meyer, Relationships between ozone photolysis rates and peroxy radical concentrations in clean marine air over the Southern Ocean, J. Geophys. Res., 102, 12,805-12,817, 1997.
26. Slemr, F., and H.G. Tremmel, Hydroperoxides in the marine troposphere over the Atlantic Ocean, J. Atmos. Chem., 19, 371-404, 1994.
27. 2 reaction: Its misapplication in atmospheric chemistry models, J. Geophys. Res., 100, 11,695-11,698, 1995.
28. Stordal, F., R.G. Derwent, I.S.A. Isaksen, D. Jacob, M. Kanakidou, J.A. Logan, and M.J. Prather, Model simulations of global tropospheric ozone, in Scientific Assessment of Ozone Depletion: 1994, edited by D.L. Albritton, R.T. Watson, and P.J. Aucamp, chap. 7, World Meteorological Orgianzation, Geneva, Switzerland, 1995.
29. Tremmel, H.G., W. Junkermann, and F. Slemr, On the distribution of hydrogen peroxide in the lower troposphere over the northeastern United States during late summer 1988, J. Geophys. Res., 98, 1083-1099, 1993.
30. Tremmel, H. G., W. Junkermann, and F. Slemr, Distribution of organic hydroperoxides during aircraft measurements over the northeastern United States J. Geophys. Res., 99, 5295-5307, 1994.
31. Wild, O., K.S. Law, J.A. Pyle, D.S. McKenna, B.J. Bandy, S.A. Penkett, and J.A. Pyle, Photochemical trajectory modeling studies of the North Atlantic region during August 1993, J. Geophys. Res., 101, 29,269-29,288, 1996.