Photochemical modeling of hydroxyl and its relationship to other species during the Tropospheric OH Photochemistry Experiment

Journal of Geophysical Research Atmospheres

Volumn 102, Issue 5, 1997, Pages 6467-6493

  McKeen, S A ^a,b   Mount, G ^a   Eisele, F ^c   Williams, E ^a,b   Harder, J ^a,b   Goldan, P ^a   Kuster, W ^a   Liu, S C ^d   Baumann, K ^a,b   Tanner, D ^c   Fried, A ^c   Sewell, S ^c,e   Cantrell, C ^c   Shetter, R ^c  

^a NOAA EARTH SYSTEM RESEARCH LABORATORY   (United States)

^b UNIVERSITY OF COLORADO   (United States)

^c NATIONAL CENTER FOR ATMOSPHERIC RESEARCH   (United States)

^d GEORGIA INSTITUTE OF TECHNOLOGY   (United States)

^e Phillips Academy   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001357693     PISSN: 01480227     EISSN: None     Source Type: Journal    
DOI: 10.1029/96jd03322     Document Type: Article

References (63)

1. x, J. Geophys. Res., 95, 18,539-18,546, 1990.
2. Arey, J., A. M. Winer, R. Atkinson, S. M. Aschmann, W. D. Long, C. L. Morrison, and D. M. Olszyk, Terpenes emitted from agricultural species found in California's Central Valley, J. Geophys. Res., 96, 9329-9336, 1991.
3. 2 photooxidations suitable for inclusion in atmospheric simulation models, Atmos. Environ., 16, 1341-1355, 1982.
4. Atkinson, R., Gas-phase tropospheric chemistry of organic compounds, J. Phys. Chem. Ref. Data Monogr., 2, 1-216, 1994.
5. Baumann, K., E. J. Williams, J. A. Olson, J. W. Harder, and F. C. Fehsenfeld, Meteorological characteristics and spatial extent of upslope events during the 1993 Tropospheric OH Photochemistry Experiment, J. Geophys. Res., this issue.
6. x measurements in clean continental air and analysis of the contributing meteorology, J. Geophys. Res., 89, 9623-9631, 1984.
7. Cantrell, C. A., et al., Peroxy radicals as measured in ROSE and estimated from photostationary state deviations, J. Geophys. Res., 98, 18,355-18,366, 1993.
8. Cantrell, C. A., R. E. Shetter, J. G. Calvert, F. L. Eisele, E. Williams, K. Baumann, W. H. Brune, P. S. Stevens, and J. H. Mather, Peroxy radicals from photostationary state deviations and steady state calculations during the Tropospheric OH Photochemistry Experiment at Idaho Hill, Colorado 1993, J. Geophys. Res., this issue.
9. Carter, W. P., A detailed mechanism for the gas-phase atmospheric reactions of organic compounds, Atmos. Environ., 24A, 481-518, 1990.
10. 2-NO system based on airborne observations from the Western and Central North Pacific, J. Geophys. Res., 101, 2053-2072, 1996.
11. Crosley, D. R., The 1993 OH Tropospheric Photochemistry Experiment: A summary and perspective, J. Geophys. Res., this issue.
12. DeMore, W. B., M. J. Molina, S. P. Sander, D. M. Golden, R. F. Hampson, M. J. Kurylo, C. J. Howard, and A. R. Ravishankara, Chemical kinetics and photochemical data for use in stratospheric modeling, in Evaluation 10, JPL Publ. 92-20, 185 pp., Jet Propul. Lab., Pasadena, Calif., 1992.
13. Dunker, A. M., The decoupled direct method for calculating sensitivity coefficients in chemical kinetics, J. Chem. Phys., 81, 2385-2393, 1984. Eisele, F. L., G. H. Mount, F. C. Fehsenfeld, J. Harder, E. Marovich, D. D. Parrish, J. Roberts, M. Trainer, and D. Tanner, Intercomparison of tropospheric OH and ancillary trace gas measurements at Fritz Peak Observatory, Colorado, J. Geophys. Res., 99, 18,605-18,626, 1994.
14. Dunker, A. M., The decoupled direct method for calculating sensitivity coefficients in chemical kinetics, J. Chem. Phys., 81, 2385-2393, 1984. Eisele, F. L., G. H. Mount, F. C. Fehsenfeld, J. Harder, E. Marovich, D. D. Parrish, J. Roberts, M. Trainer, and D. Tanner, Intercomparison of tropospheric OH and ancillary trace gas measurements at Fritz Peak Observatory, Colorado, J. Geophys. Res., 99, 18,605-18,626, 1994.
15. Eisele, F. L., D. J. Tanner, C. A. Cantrell and J. G. Calvert, Measurements and steady state calculations of OH at Mauna Loa Observatory, J. Geophys. Res., 101, 14,665-14,680, 1996.
16. Fried, A., et al., Photochemistry of formaldehyde during the 1993 Tropospheric OH Photochemistry Experiment, J. Geophys. Res., this issue.
17. Gao, D., W. R. Stockwell, and J. B. Milford, First-order sensitivity and uncertainty analysis for a regional-scale gas-phase chemical mechanism, J. Geophys. Res., 100, 23,153-23,166, 1995.
18. 5 alcohol emission in a North American pine forest, Geophys. Res. Lett., 20, 1039-1042, 1993.
19. Goldan, P. D., W. C. Kuster and F. C. Fehsenfeld, Nonmethane hydrocarbon measurements during the Tropospheric OH Photochemistry Experiment, J. Geophys. Res., this issue.
20. Greenberg, J. P. and P. R. Zimmerman, Nonmethane hydrocarbons in remote tropical, continental, and marine atmospheres, J. Geophys. Res., 89, 4767-4778, 1984.
21. Guenther, A., P. Zimmerman, and M. Wildermuth, Natural volatile organic compound emission rate estimates for U.S. woodland landscapes, Atmos. Environ., 28, 1197-1210, 1994.
22. 3 with a series of monoterpenes, J. Atmos. Chem., 18, 75-102, 1994.
23. Harder, J. W., A. Fried, S. Sewell and B. Henry, Comparison of tunable diode laser and long-path ultraviolet/visible spectroscopic measurements of ambient formaldehyde concentrations during the 1993 Tropospheric OH Photochemistry Experiment, J. Geophys. Res., this issue (a).
24. 3 measured by long-path and in situ techniques during the 1993 Tropospheric OH Photochemistry Experiment, J. Geophys. Res., this issue (b).
25. Hatakeyama, S., K. Izumi, T. Fukuyama, H. Akimoto, and N. Washida, Reactions of OH with α-pinene and β-pinene in air: Estimate of global CO production from atmospheric oxidation of terpenes, J. Geophys. Res., 96, 947-958, 1991.
26. Heikes, B., Formaldehyde and hydroperoxides at Mauna Loa Observatory, J. Geophys. Res., 97, 18,001-18,014, 1992.
27. Helmig, D., and J. Arey, Organic chemicals in the air at Whitaker's Forest/Sierra Nevada Mountains, California, Sci. Total Environ., 112, 233-250, 1992.
28. Isidorov, V. A., I. G. Zenkevich, and B. V. Ioffe, Volatile organic compounds in the atmosphere of forests, Atmos. Environ., 19, 1-8, 1985.
29. Kleinman, L. I., Photochemical formation of peroxides in the boundary layer, J. Geophys. Res., 91, 5121-5136, 1986.
30. Lee, J. H., D. F. Leahy, I. N. Tang, and L. Newman, Measurement and speciation of gas phase peroxides in the atmosphere, J. Geophys. Res., 98, 2911-2915, 1993.
31. Lin, X., M. Trainer, and S.C. Liu, On the nonlinearity of tropspheric ozone production, J. Geophys. Res., 93, 15,879-15,888, 1988.
32. Lloyd, A. C., R. Atkinson, F. W. Lurmann, and B. Nitta, Modeling potential ozone impacts from natural hydrocarbons, 1, Developement and testing of a chemical mechanism for the NOx-air photooxidations of isoprene and α-pinene under ambient conditions, Atmos. Environ., 17, 1931-1950, 1983.
33. Logan, J. A., M. J. Prather, S. C. Wofsy, and M. B. McElroy, Tropospheric chemistry: A global perspective, J. Geophys. Res., 86, 7210-7254, 1981.
34. Lurmann, F. W., A. C. Lloyd, and R. Atkinson, A chemical mechanism for use in long-range transport/acid deposition computer modeling, J. Geophys. Res., 91, 10,905-10,936, 1986.
35. McKeen, S. A., E.-Y. Hsie, M. Trainer, R. Tallamraju, and S. C. Liu, A study of the dependence of rural ozone on ozone precursors in the eastern United States, J. Geophys. Res., 96, 15,377-15,394, 1991.
36. 2 by matrix isolation and electron spin resonance, J. Atmos . Chem., 3, 341-361, 1985.
37. Montzka, S. A., M. Trainer, P. D. Goldan, W. C. Kuster, and F. C. Fehsenfeld, Isoprene and its oxidation products, methyl vinyl ketone and methacrolein, in the rural troposphere, J. Geophys. Res., 98, 1101-1111, 1993.
38. Montzka, S. A., M. Trainer, W. M. Angevine and F. C. Fehsenfeld, Measurements of 3-methyl furan, methyl vinyl ketone, and methacrolein, in the southeastern United States, J. Geophys. Res., 100, 11,393-11,401, 1995.
39. Mount, G.H., and F. L. Eisele, An intercomparison of tropospheric OH measurements at Fritz Peak Observatory, Colorado, Science, 256, 1187-1190, 1992.
40. Mount, G. H., and E. Wiliams, An overview of the Tropospheric OH Photochemistry Experiment, Fritz Peak/Idaho Hill, Colorado, fall 1993, J. Geophys. Res., this issue.
41. Mount, G. H., F. L. Eisele, D. J. Tanner, J. W. Brault, P. V. Johnston, J. W. Harder, E. .J. Williams, A. Fried, and R. Shetter, An intercomparison of spectroscopic laser long-path and ion-assisted in situ measurements of hydroxyl conentrations during the Tropospheric OH Photochemistry Experiment, fall 1993, J. Geophys. Res., this issue.
42. Murphy, D. M., D. S. Thomson, M. Kaluzhny, J. Marti, and R. L. Weber, Aerosol characteristics at Idaho Hill during the Tropospheric OH Photochemistry Experiment, J. Geophys. Res., this issue.
43. Nondek, L., D. R. Rodier, and J. W. Birks, Measurements of sub-ppbv concentrations of aldehydes in a forest atmosphere using a new HPLC technique, Environ. Sci. Technol., 26, 1174-1178, 1992.
44. Olson, J. A., K. Baumann, C. J. Volpe, J. Harder, E. J. Williams, and G. Mount, Meteorological overview of the 1993 OH Photochemistry Experiment, J. Geophys. Res., this issue.
45. Pandis, S. N., S. E. Paulson, J. H. Seinfeld, and R. C. Flagan, Aerosol formation in the photooxidation of isoprene and β-pinene, Atmos. Environ., 25A, 997-1008, 1991.
46. 3 photostationary state at Niwot Ridge, Colorado, J. Geophys. Res., 91, 5361-5370, 1986.
47. 2) at Niwot Ridge, Colorado, J. Geophys. Res., 95 , 1817-1836, 1990.
48. Perner, D., et al., Measurements of tropospheric OH concentraions: A comparison of field data with model predictions, J. Atmos. Chem., 5, 185-216, 1987.
49. Poppe, D., M. Wallasch, and J. Zimmerman, The dependence of the concentration of OH on its precursors under moderately polluted conditions: A model study, J. Atmos. Chem., 16, 61-78, 1993.
50. Poppe, D., M., et al., Comparison of measured OH concentrations with model calculations, J. Geophys. Res., 99, 16,633-16,642, 1994.
51. Roberts, J. M., S. B. Bertman, D. Parrish, J. Holloway, and F. C. Fehsenfeld, Measurement of total nonmethane hydrocarbon (Cy) at Chebogue Point, Nova Scotia, during the 1993 NARE campaign, J. Geophys. Res., in press, 1996.
52. Rudich, Y., R. Talukdar, J .B. Burkholder, and A. R. Ravishankara, The reaction of methyl butenol with the OH radical: Mechanism and atmospheric implications, J. Phys. Chem., 99, 12,188-12,194, 1995.
53. Shu, Y., and R. Atkinson, Atmospheric lifetimes and fates of a series of sesquiterpenes, J. Geophys. Res., 100, 7275-7281, 1995.
54. Sillman, S., J. A. Logan, and S. C. Wofsy, The sensitivity of ozone to nitrogen oxides and hydrocarbons in regional ozone episodes, J. Geophys. Res., 95, 1837-1851, 1990.
55. 2 ratios during the Tropospheric OH Photochemistry Experiment: Measurement and theory, J. Geophys. Res., this issue.
56. Tanner, D., F.L. Eisele, and A. Jefferson, Ion-assisted OH instrument, J. Geophys. Res, this issue.
57. Thompson, A. M., and R. W. Stewart, The effect of kinetics imprecisions on constituents calculated in a tropospheric photochemical model, J. Geophys. Res., 96, 13,089-13,109, 1991.
58. Trainer, M., E.-Y. Hsie, S. A. McKeen, R. Tallamraju, D. D. Parrish, F. C. Fehsenfeld, and S. C. Liu, Impact of natural hydrocarbons on hydroxyl and peroxy radicals at a remote site, J. Geophys. Res., 92, 11,879-11,894, 1987.
59. Trainer, M., et. al., Observations and modeling of the reactive nitrogen photochemistry at a rural site, J. Geophys. Res., 96, 3045-3063, 1991.
60. 2 + NO reaction using chemical iionization mass spectrometry, J. Phys. Chem., 99, 12,829-12,838, 1995.
61. Watkins, B.A., D.D. Parrish, M. Trainer, R.B. Norton, J.E. Yee, F.C. Fehsenfeld, and B. G. Heikes, Factors influencing the concentration of gas-phase hydrogen peroxide during the summer at Niwot Ridge, Colorado, J. Geophys. Res., 100, 22,831-22,840, 1995.
62. Williams, E. J., J. M. Roberts, K. Baumann, S. B. Bertmann, S. Buhr, R. B. Norton, and F. C. Fehsenfeld, Variations in NOy composition at Idaho Hill, Colorado, J. Geophys. Res., this issue.
63. Yokouchi, Y., H. Mukai, K. Nakajima, and Y. Ambe, Semi-volatile aldehydes as predominant organic gases in remote areas, Atmos. Environ., 24A, 439-442, 1990.