Novel 1,4-palladium migration in organopalladium intermediates derived from o-lodobiaryls

Journal of the American Chemical Society

Volumn 124, Issue 48, 2002, Pages 14326-14327

  Campo, Marino A ^a   Larock, Richard C ^a  

^a IOWA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

IODINE DERIVATIVE; ORGANIC COMPOUND; PALLADIUM;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; HECK REACTION; REACTION ANALYSIS;

EID: 0037021524     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja027548l     Document Type: Article

References (12)

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3. (c) Overman, L. E. Pure Appl. Chem. 1994, 66, 1423.
4. (d) Shibasaki, M.; Boden, C. D. J.; Kojima, A. Tetrahedron 1997, 22, 7371.
5. (e) Cabri, W.; Candiani, I. Acc. Chem. Res. 1995, 28, 2.
6. (a) Diaz-Ortiz, A.; Prieto, P.; Vazquez, E. Synlett 1997, 269.
7. (b) Heck, R. F. Org. React. 1982, 27, 345.
8. Minor amounts of similar migration products have recently been reported in bromoarylpyridine systems, see: Karig, G.; Moon Maria-Teresa; Thasana, N.; Gallagher, T. Org. Lett. 2002, 4, 3115.
9. Larock, R. C.; Tian, Q. J. Org. Chem. 2001, 66, 7372.
10. Jeffrey, T. J. Chem. Soc., Chem. Commun. 1984, 1287.
11. Larock, R. C.; Doty, M. J.; Tian, Q.; Zenner, J. M. J. Org. Chem. 1997, 62, 7536.
12. For similar pallada(II)cycle reactions with alkynes, see: Portscheller, J. L.; Malinakova, H. C. Org. Lett. 2002, 4, 3679 and references therein.