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note
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1/n (CSD refcode MEPXEK) appears to be erroneous, so this crystal structure was redetermined. Reflections were solved and refined in the orthorhombic space group Pbca (R-factor 4.2%). See Table 1 for crystallographic data.
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Intramolecular C-F⋯O=C repulsion could be yet another reason to avoid the planar conformation and hence the urea tape motif.
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