Synthesis and properties of a dithiirane trans-1,2-dioxide, a three-membered vic-disulfoxide

Organic Letters

Volumn 8, Issue 1, 2006, Pages 91-94

  Ishii, Akihiko ^a   Ohishi, Masayuki ^a   Matsumoto, Kimiyo ^a   Takayanagi, Toshiyuki ^a  

^a SAITAMA UNIVERSITY   (Japan)

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[No Author keywords available]

Indexed keywords

EID: 30944451605     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol052570f     Document Type: Article

References (41)

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26. -1, R1 = 0.0968, wR2 = 0.2410, GOF = 1.035. Relevant bond length (Å) and angle (deg) data: molecule A (left), S1A-O1A 1.476(5), S1A-C1A 1.855(6), S1A-S2A 2.241(2), S2A-O2A 1.469(5), S2A-C1A 1.860(6), C1A-C12A 1.578(8), C1A-C2A 1.580-(7), O1A-S1A-C1A 115.6(3), O1A-S1A-S2A 113.6(2), C1A-S1A-S2A 52.99(19), O2A-S2A-C1A 116.6(3), O2A-S2A-S1A 115.0(2), C1A-S2A-S1A 52.79(18), C12A-C1A-C2A 123.3(5), C12A-C1A-S1A 110.2(4), C2A-C1A-S1A 114.8(4), C12A-C1A-S2A 113.8(4), C2A-C1A-S2A 110.2(4), S1A-C1A-S2A 74.2(2); molecule B (right), S1B-O1B 1.468(5), S1B-C1B 1.863(6), S1B-S2B 2.243(2), S2B-O2B 1.471(5), S2B-C1B 1.875(6), C1B-C12B 1.573(8), C1B-C2B 1.579(7), O1B-S1B-C1B 116.1(3), O1B-S1B-S2B 113.1(2), C1B-S1B-S2B 53.37(18), O2B-S2B-C1B 115.3(3), O2B-S2B-S1B 114.5(2), C1B-S2B-S1B 52.89(18), C12B-C1B-C2B 123.5(5), C12B-C1B-S1B 109.7-(4), C2B-C1B-S1B 114.5(4), C12B-C1B-S2B 114.4(4), C2B-C1B-S2B 110.4(4), S1B-C1B-S2B 73.7(2).
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