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Volumn 61, Issue 22, 1996, Pages 7911-7917

Reactions of bis(p-methoxyphenyl)trisulfane and its oxides with dimethyldioxirane and (trifluoromethyl)methyldioxirane

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EID: 0001744815     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo960995x     Document Type: Article
Times cited : (21)

References (42)
  • 16
    • 85088542474 scopus 로고    scopus 로고
    • note
    • 15
  • 25
    • 77956787912 scopus 로고
    • Gold, V., Bethell, D., Ed.; Academic Press: London
    • Kice, J. L. In Advances in Physical Organic Chemistry; Gold, V., Bethell, D., Ed.; Academic Press: London, 1980; Vol. 17; pp 65-181.
    • (1980) Advances in Physical Organic Chemistry , vol.17 , pp. 65-181
    • Kice, J.L.1
  • 27
    • 0011790730 scopus 로고
    • The disulfane 1,1-dioxide/tetrasulfane ratio was not 1/1 as anticipated from decomposition of the trisulfane 1-oxide; however, Harpp has pointed out that trisulfane 1,1-dioxides spontaneously extrude sulfur to form disulfane 1,1-dioxides: Harpp, D. N.; Ash, D. K.; Smith, R. A. J. Org. Chem. 1979, 44, 4135-4140.
    • (1979) J. Org. Chem. , vol.44 , pp. 4135-4140
    • Harpp, D.N.1    Ash, D.K.2    Smith, R.A.3
  • 29
    • 0029975048 scopus 로고    scopus 로고
    • (Trifluoromethyl )methyldioxirane (TFD) has a tendency to give more sulfone than observed in reactions of dimethyldioxirane (DMD). A mechanism to explain the excess sulfone formation that invokes a sulfurane intermediate has been suggested. Asensio, G.; Mello, R.; González-Núñez, M. E. Tetrahedron Lett. 1996, 37, 2299-2302. Consequently, it is conceivable that TFD reacts via a different mechanism than DMD. However, we consider this unlikely because at room temperature where the two reagents can be compared directly the oxidations of the trisulfane 2-oxide gave identical product mixtures.
    • (1996) Tetrahedron Lett. , vol.37 , pp. 2299-2302
    • Asensio, G.1    Mello, R.2    González-Núñez, M.E.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.