Synthesis of new half-sandwich ruthenium(II) complexes bearing alkenyl- and alkynylphosphane ligands

European Journal of Inorganic Chemistry

Volumn , Issue 1, 2006, Pages 78-87

  Díez, Josefina ^a   Gamasa, M Pilar ^a   Gimeno, José ^a   Lastra, Elena ^a   Villar, Amparo ^a  

^a UNIVERSITY OF OVIEDO   (Spain)

Author keywords

Indenyl complexes; Phosphane ligands; Ruthenium; Sandwich complexes

Indexed keywords

CESIUM COMPOUNDS; CHELATION; CHLORINE COMPOUNDS; FLUORINE COMPOUNDS; LIGANDS; RUTHENIUM COMPOUNDS; SILVER COMPOUNDS; SODIUM COMPOUNDS; SYNTHESIS (CHEMICAL); X RAY CRYSTALLOGRAPHY;

ABSTRACTORS; ALKENYL; CATIONICS; HALF-SANDWICH; INDENYL COMPLEXES; PHOSPHANE LIGANDS; PHOSPHANES; REFLUXING; SANDWICH COMPLEXES; [CARBONYL;

ANTIMONY COMPOUNDS;

EID: 30644474615     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200500569     Document Type: Article

References (67)

1. 2, see the following: [M] = [Cr] and [Mo] a) P. G. Edwards, J. S. Fleming, S. S. Liyanage, S. J. Coles, M. B. Hursthouse, J. Chem. Soc., Dalton Trans. 1996, 1801-1807;
2. [Os]: b) M. Baya, M. L. Buil, M. A. Esteruelas, E. Oñate, Organometallics 2005, 24, 2030-2038;
3. c) M. A. Esteruelas, A. I. González, A. M. López, E. Oñate, Organometallics 2004, 23, 4858-4869;
4. [Rh]: d) L. P. Barthel-Rosa, V. J. Catalano, K. Maitra, J. H. Nelson, Organometallics 1996, 15, 3924-3934.
5. [1a]; [W]: e) X. Morise, M. L. H. Green, P. C. McGowan, S. J. Simpson, J. Chem. Soc., Dalton Trans. 1994, 571-578;
6. [Pd]: f) S. J. Coles, P. Faulds, M. B. Hursthouse, D. G. Kelly, G. C. Ranger, A. J. Toner, N. M. Walker, J. Organomet. Chem. 1999, 586, 234-240.
7. 2, see the following: [M] = [Ni]: g) K. Issleib, M. Haftendorn, Z. Anorg. Allg. Chem. 1967, 351, 9-17;
8. [Rh] and [Ir]: h) D. V. Krupenya, S. I. Selivanov, S. P. Tunik, M. Haukka, T. A. Pakkanen, Dalton Trans. 2004, 2541-2549;
9. i) P. W. Clark, G. E. Hartwell, J. Organomet. Chem. 1975, 102, 387-396.
10. For representative examples of alkynylphosphane complexes, see the following: [M] = [Fe]: a) E. Louattani, J. Suades, A. Álvarez-Larena, J. F. Piniella, G. Germain, J. Organomet. Chem. 1996, 506, 121-127;
11. [Mo]: b) E. Louattani, J. Suades, J. Organomet. Chem. 2000, 604, 234-240;
12. [Rh], [Ir], and [Pt]: c) J. R. Berenguer, M. Bernechea, J. Forniés, A. García, E. Lalinde, M. T. Moreno, Inorg. Chem. 2004, 43, 8185-8198;
13. d) J. Forniés, A. García, B. Gil, E. Lalinde, M. T. Moreno, Dalton Trans. 2004, 3854-3863;
14. e) J. Forniés, A. García, J. Gómez, E. Lalinde, M. T. Moreno, Organometallics 2002, 21, 3733-3743;
15. [Au]: f) M. Bardaji, A. Laguna, P. G. Jones, Organometallics 2001, 20, 3906-3912.
16. For recent examples of ruthenium complexes with DCVP see: a) D. Dorota, J. H. Nelson, Dalton Trans. 2005, 92-103;
17. b) K. Y. Ghebreyessus, J. H. Nelson, Synth. React. Inorg. Met.-Org. Chem. 2003, 33, 1329-1349.
18. For recent examples of ruthenium complexes with DPVP see: a) D. C. Wilson, J. H. Nelson, J. Organomet. Chem. 2003, 682, 272-289;
19. b) H. D. Hansen, J. H. Nelson, Inorg. Chim. Acta 2003, 352, 4-8;
20. c) G. Kesete, J. H. Nelson, Inorg. Chem. Commun. 2003, 6, 1044-1047;
21. d) D. Dorota, J. H. Nelson, Dalton Trans. 2003, 449-457;
22. e) G. Kesete, J. H. Nelson, Organometallics 2000, 19, 3387-3392;
23. f) H. Heather, J. H. Nelson, Organometallics 2000, 19, 4740-4755.
24. For recent examples of ruthenium complexes with ADPP see: a) D. Cuervo, M. P. Gamasa, J. Gimeno, Chem. Eur. J. 2004, 10, 425-432;
25. b) K. D. Redwine, J. H. Nelson, J. Organomet. Chem. 2000, 613, 177-199;
26. c) L. P. Barthel-Rosa, K. Maitra, J. Fischer, J. H. Nelson, Inorg. Chem. 1998, 37, 633-639.
27. C. Slugovc, K. Mereiter, R. Schmid, K. Kirchner, Organometallics 1999, 18, 1011-1017.
28. a) J. R. Berenguer, M. Bernechea, J. Forniés, A. García, E. Lalinde, Organometallics 2004, 23, 4288-4300;
29. b) J. R. Berenguer, M. Bernechea, J. Forniés, J. Gómez, E. Lalinde, Organometallics 2002, 21, 2314-2324;
30. c) C. J. Adams, M. I. Bruce, B. W. Skelton, A. H. White, Inorg. Chem. 1992, 31, 3336-3338;
31. d) G. Mohamed, B. Demerseman, P. H. Dixneuf, J. Organomet. Chem. 1992, 424, 65-70.
32. a) F. Hong, Y. Ho, Y. Chang, Y. Lai, Tetrahedron 2004, 60, 2639-2645;
33. b) T. Baumgartner, K. Huynth, S. Schleidt, A. J. Lough, I. Manners, Chem. Eur. J. 2002, 8, 4622-4632;
34. c) T. De Simone, R. S. Dickson, B. W. Skelton, A. W. White, Inorg. Chim. Acta 1995, 240, 323-333;
35. d) I. Moldes, J. Ros, Inorg. Chim. Acta 1995, 232, 75-81.
36. J. E. Davies, M. J. Mays, P. R. Raithby, K. Sarveswaran, G. A. Solan, J. Chem. Soc., Dalton Trans. 2001, 1269-1277.
37. I. Ara, J. Forniés, A. García, J. Gómez, E. Lalinde, M. T. Moreno, Chem. Eur. J. 2002, 8, 3698-3716.
38. P. Álvarez, E. Lastra, J. Gimeno, P. Braña, J. A. Sordo, J. Gómez, L. R. Falvello, M. Bassetti, Organometallics 2004, 23, 2956-2966.
39. P. Álvarez, E. Lastra, J. Gimeno, M. Bassetti, L. R. Falvello, J. Am. Chem. Soc. 2003, 125, 2386-2387.
40. J. Díez, M. P. Gamasa, J. Gimeno, E. Lastra, A. Villar, Organometallics 2005, 24, 1410-1418.
41. M. Bassetti, P. Álvarez, J. Gimeno, E. Lastra, Organometallics 2004, 23, 5127-5134.
42. C* represents the centroid of atoms C(1), C2), C(3), C(4), and C(5); C** represents the centroid of atoms C(4), C(5), C(6), C(7), C(8), and C(9).
43. S. García-Granda, M. Pérez-Priede, J. F. Van der Maelen, personal communication.
44. M. P. Gamasa, J. Gimeno, C. González-Bernardo, J. Borge, S. García-Granda, Organometallics 1997, 16, 2483-2485.
45. P. Garrou, Chem. Rev. 1981, 81, 229-266.
46. a) J. Okuda, K. H. Zimmermann, Chem. Ber. 1989, 122, 1645-1647;
47. b) J. W. Faller, B. V. Johnson, J. Organomet. Chem. 1975, 88, 101-113;
48. c) J. A. Miguel-García, H. Adams, P. M. Maitlis, J. Organomet. Chem. 1991, 413, 427-444.
49. Significant distance differences are only found in the cases of the coordination of the olefin to the ruthenium center, probably due to steric requirements. 3a: Ru-C(10) 2.276(11) and 2.289(13); Ru-C(11) 2.230(11) and 2.263(11); C(10)-C(11) 1.389(17) and 1.395(16). 4b: Ru-C(10) 2.228(7) and 2.253(8); Ru-C(11) 2.245(9) and 2.235(8); C(10)-C(11) 1.363(11) and 1.363(10).
50. Complex 5b is unstable in solution at room temperature and the NMR spectra were therefore recorded at low temperature (-50°C).
51. J. A. Gladysz, B. I. Boone, Angew. Chem. Int. Ed. Engl. 1997, 36, 550-583.
52. L. A. Oro, M. A. Ciriano, M. Campo, C. Foces-Foces, F. H. Cano, J. Organomet. Chem. 1985, 289, 117-131.
53. M. S. Loonat, L. Carlton, J. C. A. Boeyens, N. J. Coville, J. Chem. Soc., Dalton Trans. 1989, 2407-2414.
54. P. Clark, J. L. S. Curtis, P. E. Garrou, G. E. Hartwell, Can. J. Chem. 1974, 52, 1714-1720.
55. R. S. Dickson, T. De Simona, E. M. Campi, W. R. Jackson, Inorg. Chim. Acta 1994, 220, 187-192.
56. E. Louattani, J. Suades, R. Mathieu, J. Organomet. Chem. 1991, 421, 335-340.
57. SAINT version 6.02 Bruker Analytical X-ray Systems, Madison, WI, 2000.
58. G. M. Sheldrick, SADABS empirical absorption program, University of Göttingen, 1996.
59. Collect, Nonius BV, Delft, The Netherlands, 1997-2000.
60. Z. Otwinowski, W. Minor, Methods Enzymol. 1997, 276, 307-326.
61. R. H. Blessing, Acta Crystallogr., Sect. A 1995, 51, 33-38.
62. L. J. Farrugia, J. Appl. Crystallogr. 1999, 32, 837.
63. P. T. Beurskens, G. Admiraal, G. Beurskens, W. P. Bosman, S. García-Granda, R. O. Gould, J. M. M. Smits, C. Smykalla, The DIRDIF Program System, Technical Report of the Crystallographic Laboratory, University of Nijmegen, Nijmegen, The Netherlands, 1999.
64. G. M. Sheldrick, SHELXL97: Program for the Refinement of Crystal Structures; University of Göttingen, Göttingen, Germany, 1997.
65. Tables for X-ray Crystallography, Kynoch Press, Birminghan, U. K., 1974, vol. IV (present distributor: Kluwer Academic Publishers, Dordrecht, The Netherlands).
66. M. Nardelli, Comput. Chem. 1983, 7, 95-98.
67. A. L. Spek, PLATON: A Multipurpose Crystallographic Tool, University of Utrecht, The Netherlands, 2005.