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5
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0038157006
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(i) Dimerization of terminal alkynes: (a) Bassetti, M.; Marini, S.; Tortorella, F.; Cadierno, V.; Diez, J.; Gamasa, M. P.; Gimeno, J. J. Organomet. Chem. 2000, 593-594, 292. (b) Bassetti, M.; Marini, S.; Diez, J.; Gamasa, M. P.; Gimeno, J.; Rodríguez-Alvarez, Y.; García-Granda, S. Organometallics 2002, 21, 4815.
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0035921548
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0035955796
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2]: Unpublished results.
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6], in which a coordinatively unsaturated intermediate is required. However, no theoretical calculations have been performed with this system.
-
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18
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0010017040
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Similar dynamic proceses have been described for other metal complexes: (a) Clark, P. W.; Hanisch, P.; Jones, A. J. Inorg. Chem. 1979, 18, 2067. (b) Clark, P. W.; Jones, A. J. J. Organomet. Chem. 1978, 122, C41. See also ref 8c.
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See also ref 8c
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Similar dynamic proceses have been described for other metal complexes: (a) Clark, P. W.; Hanisch, P.; Jones, A. J. Inorg. Chem. 1979, 18, 2067. (b) Clark, P. W.; Jones, A. J. J. Organomet. Chem. 1978, 122, C41. See also ref 8c.
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4) which proceeds also without alkene dissociation involving a carbon-hydrogen σ-bond. However, no theoretical calculations have been performed. Peng, T.-S.; Gladysz, J. A. J. Am. Chem. Soc. 1992, 114, 4174.
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The stereochemistry of the chiral centers is identical qualitatively and practically identical quantitatively in the two molecules of a given asymmetric unit; for example, the chiral volumes calculated for the chiral carbon atoms C41 and C87 are equal in sign and nearly equal in magnitude.
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1, under the same experimental conditions of solvent and temperature. Alvarez, P.; Bassetti, M.; Gimeno, J.; Lastra, E. Unpublished results.
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35
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3042663367
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9 Although no kinetic studies have been carried out for this reaction, a dissociative pathway has been proposed.
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Beurskens, P.T.1
Beurskens, G.2
Bosman, W.P.3
De Gelder, R.4
Garcia-Granda, S.5
Gould, R.O.6
Israel, R.7
Smits, J.M.M.8
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