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Volumn 109, Issue 49, 2005, Pages 11144-11154

Electron spin polarization of functionalized fullerenes. Reversed quartet mechanism

Author keywords

[No Author keywords available]

Indexed keywords

CHARGE TRANSFER; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRON TRANSPORT PROPERTIES; GROUND STATE; PARAMAGNETIC RESONANCE; POLARIZATION;

EID: 30544450211     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp0540104     Document Type: Article
Times cited : (57)

References (72)
  • 14
    • 30544452563 scopus 로고    scopus 로고
    • note
    • 60 was calculated by HyperChem software.
  • 20
    • 0002312013 scopus 로고
    • Dolphin, D., Ed.; Academic Press: New York
    • Gouterman, M. In The Pophyrins; Dolphin, D., Ed.; Academic Press: New York, 1978; Vol. 3; p 1.
    • (1978) The Pophyrins , vol.3 , pp. 1
    • Gouterman, M.1
  • 23
    • 30544433820 scopus 로고    scopus 로고
    • note
    • 69 Evidently, that there are a noticeable number of molecular pairs in cluster with intermolecular distances shorter than 25 Å. The dipolar interaction between them should induce spin-lattice relaxation, which broadens the TREPR spectrum of TEMPO in glassy environment.
  • 27
    • 30544450519 scopus 로고    scopus 로고
    • note
    • B from the central one, are mainly due to the +1/2 ↔ +3/2 and -3/2 ↔ -1/2 transitions and include predominantly the contributions from the molecules, which rotational axis is oriented perpendicular with respect to the magnetic field.
  • 38
    • 30544451789 scopus 로고    scopus 로고
    • note
    • 31
  • 49
    • 0004344770 scopus 로고
    • Benjamin/Cummings Publishing Co., Inc.: Menlo Park, NJ
    • Turro, N. J. Modern Molecular Photochemistry; Benjamin/Cummings Publishing Co., Inc.: Menlo Park, NJ, 1978.
    • (1978) Modern Molecular Photochemistry
    • Turro, N.J.1
  • 58
    • 30544445132 scopus 로고    scopus 로고
    • note
    • For modeling a signal filter we have utilized in some simulations a specific filter function (a highpass Butterworth function with a cutoff frequency of 100 Hz). The result was close to that obtained by a simple subtraction of the equilibrium population difference.
  • 59
    • 30544440787 scopus 로고    scopus 로고
    • note
    • For 1 at T ≥ 300 K, absorptive ESP lasts longer than theory predicts (cf. Figure 2 (part a1)). The presence of weakly interacting associated species can be invoked to explain long-lasting polarization in solution.
  • 60
    • 30544440640 scopus 로고    scopus 로고
    • note
    • CT, etc) obtained for the equally populated sublevels.
  • 65
    • 30544447466 scopus 로고    scopus 로고
    • note
    • 60, and found that upon lowering the temperature the outer lines broaden beyond detection.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.