Oxidation of amino diols mediated by homogeneous and heterogeneous TEMPO

Advanced Synthesis and Catalysis

Volumn 346, Issue 6, 2004, Pages 655-660

  Testa, Maria Luisa ^a   Ciriminna, Rosaria ^a   Hajji, Chakib ^b   Garcia, Elena Zaballos ^b   Ciclosi, Marco ^b   Sepulveda Arques, Jose ^b   Pagliaro, Mario ^a  

^a CNR   (Italy)

^b UNIVERSITY OF VALENCIA   (Spain)

Author keywords

Amino alcohols; Chloramphenicol; Heterogeneous catalysis; Ormosil; Oxidation; Sol gel; TEMPO

Indexed keywords

2,2,6,6 TETRAMETHYLPIPERIDINE 1 OXYL; ANTIBIOTIC AGENT; BENZOIC ACID; CHLORAMPHENICOL; PIPERIDINE DERIVATIVE; SILICON DIOXIDE; UNCLASSIFIED DRUG;

ARTICLE; CATALYST; GEL; OXIDATION KINETICS; SYNTHESIS;

EID: 3042839781     PISSN: 16154150     EISSN: None     Source Type: Journal    
DOI: 10.1002/adsc.200303239     Document Type: Article

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25. Silica gels functionalized with TEMPO for alcohol oxidations produced by the Canadian company Silicycle Inc. are commercialized by the chemical supplier Aldrich (see: ChemFiles 2002, Vol. 2, no. 6). Silica gels offer several technical advantages over well-known gel-type resins being solvent-independent (rigid porous structure and no swelling), no non-specific binding (high yield) and with a high density of functional groups (small volume of gel required). See also: http://www.silicycle.com/html/english/products/produit detail.php?pro id=177.
26. Silica gels functionalized with TEMPO for alcohol oxidations produced by the Canadian company Silicycle Inc. are commercialized by the chemical supplier Aldrich (see: ChemFiles 2002, Vol. 2, no. 6). Silica gels offer several technical advantages over well-known gel-type resins being solvent-independent (rigid porous structure and no swelling), no non-specific binding (high yield) and with a high density of functional groups (small volume of gel required). See also: http://www.silicycle.com/html/english/products/produit detail.php?pro id=177.